Volume 39, Issue 2 (Journal of Advanced Materials-Summer 2020)
2020, 39(2): 81-101 |
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Kianfar A H, Eskandari N, Arayesh M A. Synthesis, Characterization and Investigation of Magnetic Properties of Co3O4/CoFe2O4 Nanocomposite Prepared by Calcination of [CO(SALEN)(PPH3)(H2O)]4[Fe(CN)6] and [Co(Salophen)(PPH3)(H2O)]4[Fe(CN)6] Binary Complex Salts. Journal of Advanced Materials in Engineering (Esteghlal) 2020; 39 (2) :81-101
URL: http://jame.iut.ac.ir/article-1-1037-en.html
URL: http://jame.iut.ac.ir/article-1-1037-en.html
Department of Chemistry, Isfahan University of Technology. , akianfar@cc.iut.ac.ir
Abstract: (2535 Views)
In this research the synthesis of [Co(Salen)(PPh3)(H2O)]4[Fe(CN)6] and [Co(Salophen)(PPh3)(H2O)]4[Fe(CN)6] schiff base complexes was reported. Co3O4/CoFe2O4 magnetic nanoparticles were prepared by calcination of these complexes at 500, 550 and 600°C. Precursor complexes were identified by FT-IR and UV-Vis spectroscopy and their thermal behavior was studied via TG/DTA. Nanomagnetic samples were characterized by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier Transform Infrared Spectroscopy (FT-IR). Magnetic properties of the synthesized nanoparticles were studied using Vibrating Sample Magnetometer (VSM). Magnetic parameters such as saturation magnetization (Ms), remanent magnetization (Mr), coercive field (Hc) and squareness ratio (SQ = Mr/Ms) were determined at room temperature. Stoichiometry and approximate composition of the prepared samples were studied by Electron Diffraction X-ray spectroscopy (EDX). The prepared nanocomposites could be useful in some practical applications due to their high magnetization, good chemical stability and dispersion.
Type of Study: Research |
Subject:
Nanomaterials
Received: 2019/05/26 | Accepted: 2020/09/9 | Published: 2020/09/21
Received: 2019/05/26 | Accepted: 2020/09/9 | Published: 2020/09/21
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