Journal of Advanced Materials in Engineering (Esteghlal)

---

---

In dynamic analysis of floating structures, the designer needs to know the wave forces due to incident and scattered waves on the structure. In this work, the flow field around the body is solved based on the potential theory with considering the free surface and sea bed effects. Using this theory, the wave forces exerted on two typical sea buoys with spherical and disc-type bodies are determined. Comparison of these results with the one obtained using Haskind method shows good accuracy of the present method.

---

Sponge iron (DRI) due to the high surface area, often shows a high tendency to re-oxidation and at some cases spontaneous combustion (autoignition). In this work, re-oxidation behavior and autoignition of sponge iron, produced from different types of iron ore has been investigated. Isothermal and non-isothermal re-oxidation experiments were carried out on each type of DRI and their autoignition temperature was determined. Microscopic examination and porosimetric measurements also were used to elucidate the relationship between the DRI specification and its re-oxidation behavior. The type and chemical analysis of the iron ore, used for the production of DRI, had a strong influence on the microstructure of sponge iron and, in turn, on its sensitivity to re-oxidation and autoignition.

---

In this paper, the oscillating two-dimensional laminar flow about a cylinder and the oscillation of a cylinder in still water are studied. A finite volume method is applied to solve the Navier Stokes equations using SIMPLEC algorithm on a body fitted co-located O-type grid. In this study, the non-dimensional flow numbers, Keulegan-Carpenter and Stokes’ numbers are chosen over a range where different laminar flow regimes are normally three-dimensional. The results of this simulation and comparison with numerical and experimental works indicate the good capability of this two-dimensional model in showing the various regimes of flow patterns and vortex shedding. Considering the forces exerted on the cylinder, this study shows that in cases where the flow is of a regular type, there is a good match between longitudinal force presented by this work and the one calculated through Morrison’s equation. But for irregular flows where the flow pattern changes in each cycle, there is less overlap and the accuracy of Morrison’s equation is reduced. Studying the time variation of the transversal force gives accurate information about the vortex shedding and its frequency in each cycle and mode changing. Since the flow mode changes continuously with time, the average of transversal and longitudinal forces on consecutive cycles is not a good representation of the force exerted on the cylinder. On the other hand, the model has satisfactorily reproduced the time variation of the tranversal and longitudinal forces of a pure mode, matching the experimental results. Keywords: Oscillating flow, Laminar flow about a cylinder, Numerical solution

---

Titanium carbide is used as an attractive reinforcement to produce particulate metal matrix composites. One of the problems to use this carbide as a reinforcement in copper-based composites is the lack of wetability in Cu-TiC system. This property improves as the C/Ti ratio in carbide decreases. Problems to use this carbide as a reinforcement in copper-based composites is the lack of wetabiity in Cu-TiC system. This property improves as the C/Ti ratio in carbide decreases. A practical method is presented in this paper to improve the dispersion of titanium carbide into liquid copper and emphasis is placed on the C/Ti ratio in the carbide. It was observed that the C/Ti ratio in a raw mixture containing only Ti and C was equal to C/Ti ratio in the carbide after synthesis but when copper powder was added to the raw materials, this ratio was higher than the starting value. Regarding the relationship between the titanium carbide lattice parameter and the C/Ti ratio in the carbide and this ratio in the raw mixture, a graph was drawn that related the C/Ti=1, a network of agglomerated TiC particles with the same C/Ti ratio is formed which cannot be dispersed into liquid copper. When this ratio is decreased to 0.3, particulate titanium carbide with C/Ti=0.5 can be easily dispersed into liquid copper. Keywords: SHS reaction, titanium carbide

---

The 25Cr-35Ni heat resistant steel has been widely used when resistance to oxidation and creep rapture at elevated temperatures is required. In this paper, the microstructural effect on the weldability of this alloy is investigated. The results of this study indicate that this steel has a perfect weldability in the as cast condition but does not possess good weldability in the aged condition. The as cast microstructure of 25Cr-35Ni steel consists of austenite matrix and a network of primary carbides, while the aged condition consists of austenite matrix and y primary and secondary carbides. The morphological change of primary carbides and the secondary carbides precipitate formation, reducing the elongation and ductility of aged steel, should have enhanced the steel susceptibility to cracking, particularly in the area of the eutectic carbides, and hence, the reduced weldability of the steel. The cracking observed was of the intergranular type and spread along the eutectic carbides. It was found that the carbides in the as cast steel consisted of NbC and M23C6, whereas that of the aged steel also exhibited Ni16Nb6Si7 and M23C6 carbides

---

A higher bustle temperature in midrex direct reduction process is always desirable due to its positive effect on the productivity and DRI quality. The limit of the bustle temperature is related to the sticking or clustering behaviour of oxide pellets during the reduction in the reactor. It has been well estabilished that coating of oxide pellets by a refractory material decreases its tendency to clustering. In this study, the clustering behaviour of oxide pellets (produced from Golegohar-Chadormalu iron ore) during redution at different temperatures was investigated. The effect of coating with different amounts of hydrated lime on the clustering behaviour was also examined. Microscopic examination of coated pellets shows a porous, non-continious layer of Ca(OH)2 being fromed on the surface of the pellets. The clustering tendency of coated pellets, measured by the standard sticking test at pilot scale, was much lower, compared with normal (uncoated) pellets, while their reducibility was the same.

---

Anatase-to-rutile phase transformation was studied in milled and unmilled samples. Ball milling was carried out in two types of ball mills, planetary and tumbler, with a ball-to-powder ratio of 40:1 over 2-48 hours. First, the unmilled samples were heated in the furnace at various temperatures for different periods of time. The results revealed that the anatase-to-rutile transformation completed at 980 after 48 hours. The rate of transformation in milled samples was greatly higher than that of unmilled ones. Activation energy in unmilled samples was about 440 kj/mol. The rate of transformation in the planetary ball mill was higher than that in tumbler mill. In the former, transformation almost finished after 16 hours of milling while in the lattar, it did not finish even after 48 hours. XRD results revealed that the transformation proceeds through an intermediate srilankite phase in all milled samples. However, srilankite was not observed in the unmilled samples.

---

Production of nickel-silver by mechanical alloying was investigated. Effects of parameters such as milling duration, ball to powder weight ratio, and chemical composition on mechanical alloying process, and alloy's color and microstructure were studied. The milled powders were characterized, using XRD and SEM. Results showed that nickel-silvers could be produced by mechanical alloying in a wide range of compositions. Alloyed powder with a bright silvery contrast and less than 15 nm grain size could be obtained by optimization of milling parameters. Zinc content of the powder mixture had a significant effect on the minimum alloying time. Ball to powder ratio up to 25 also reduced minimum alloying time but it had no significant effect above this value.

---

Stretchable woven chute is a safe device for falling humans from multi-story buildings in emergencies. During the fall, the elastomeric property of the fabric, in the weft direction, causes radial forces towards the human body inside .These radial forces lead to frictional forces between the chute and the body. The falling man can reduce the falling speed by exerting outward forces via stretching and contracting arms or legs. In this research, a model is developed to analyze the different forces involved in the fall based on the so-called thin sheet tank "fall relations". The model is capable of determining body characteristics with respect to the real model. Finally, real-world model predictions have been made in which the effects of body weight and dimensions have been considered of.

---

---

The effects of mechanochemical treatment of monoclinic zirconia in high energy planetary ball mill on its phase transformation were investigated. The mechanical treatment in ball mill reduces the grain size, increases microstrain, and causes phase transition to metastable nanostructured tetragonal and cubic phases. XRD and TEM results show considerable amounts of amorphous phase during ball milling. Surface area measurements by BET method over long milling times reveal that ZrO2 particles are agglomerated with an amorphous phase as a binder. The mechanical treatment increases the reactivity of zirconia in chlorine gas. Annealing of ball milled zirconia in the chlorine atmosphere produces oxygen vacancy in zirconia (ZrO2-x) and causes the amorphous phase to be crystallized and to change into cubic and tetragonal phases. The chlorine atmosphere increases the stability temperatures of cubic and tetragonal phases to 800°C and 1000°C, respectively. In this situation, the energy of grain boundary and oxygen vacancy play important roles in the stability of tetragonal and cubic phases.

---

In recent years, much research in the field of advanced materials synthesis using the mechanochemical process has been performed. In this study, Al2O3-TiN nanocomposite was produced by the mechanochemical method and using inexpensive material TiO2 (instead of pure titanium which is too expensive). Also, aluminum and titanium oxide powders were used as raw materials. Milling under N2 atmosphere with 5 atmospheric pressure was performed and the products were evaluated by the SEM and XRD. Milling results showed that in the first stage of the synthesis process, titanium oxide is reduced by aluminum and the process continues, producing titanium reaction with nitrogen. When the Al/TiO2 ratio molar is equal to 1.2 and 1.3, after 20 hours of milling, TiN peaks in the XRD appears. Moreover, the results showed that milling leads to the formation of fine and spherical particles.

---

Carbothermic reduction of Molybdenite in the presence of Magnesium oxide was thermodynamically studied. The stability diagrams for MoS2-MgO and MoS2-MgO-C Systems was prepared. The reduction of MoS2 with Carbon in the presence of Magnesium oxide proceeded through the direct oxidation of MoS2 by MgO to form intermediate molybdenum oxidized Species, MoO2 and MgMoO4. The results showed that the gaseous phase is mainly composed of CO. Stability diagrams for Mo-O-C (Reduction of MoO2 with carbon) and Mo-Mg-C-S-O (Reduction of MgMoO4 with carbon) were also investigated. The results showed that the Reduction of oxidized species leads to the formation of Mo, Mo2C, MoC or MgO products.

---

In recent years, much research has been performed in the field of nanomaterials synthesis using mechanochemical process. In this research, TixAly/Al2O3 ceramic matrix nanocomposite was produced by the mechanochemical method. Aluminum and inexpensive titanium oxide powders were used as raw materials, and milling was performed under N2 atmosphere. The results showed that reduction of TiO2 by Al is the first step of synthesis process, and then Ti reacts with residual Al. The synthesis after 10 hours of milling resulted in titanium aluminide and aluminium oxide. With the increase of milling time to 80 hours, titanium aluminide quantity was increased. Also, the results showed that the heating of samples containing titanium aluminide in the argon and nitrogen atmospheres does not lead to complete decomposition of aluminides.

---

Nanoparticles of Mg–Co–Ti substituted strontium hexaferrite with nominal composition of SrFe_12-2x(Mg,Co)_0.5x Ti_xO₁₉ (x=0-2.5) were synthesized by a co-precipitation method. The structural, magnetic and electromagnetic properties of samples were studied as a function of x by thermal gravimetric (TG), X-ray diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometer (VSM) and vector network analysis. It was found that the synthesis temperature increases with an increase in Mg–Co–Ti substitution and hence the particle size decreases. The XRD results showed that whole samples had good crystallinity and with an increase incations, the impurity phase of Fe₂O₃ appears. The results of hysteresis loops indicated that the saturation of magnetization of ferrite decreases from 40 emu/g to 19 emu/g with an increase in x. The Mössbauer spectroscopy showed that the cations are substituted in the 12k site of magnetoplumbite structure. Vector network measurements showed that the doped samples had much more effective reflection loss values than those of undoped ferrites. As a result, Mg–Co–Ti doped Sr-hexaferrites with x=2 can be proposed as suitable absorbers for applications in microwave technology with a good deal of consistency.