Journal of Advanced Materials in Engineering (Esteghlal)

In this study, the composition of magnesium aluminate spinle and the converter mud were used as raw materials to in-situ formation of hercynite phase in magnesite-hercynite refractory bricks. The pressed samples were sintered at 1400 and 1500℃ and then, the phase composition of bricks was evaluated after firing at 1400℃. Besides, the effect of nano-magnesia particles addition on the properties of magnesia-hercynite refractory bricks was examined. Hence, the physical peroperties, thermal shock resistance and microstructure of refractory bricks were evaluated. The phase composition results showed that hercynite is well-formed in the refractory matrix, which leads to bonding formation and its increase between magnesia particles. The evaluation of results indicated that the addition of nano-magnesia particles can reduce the porosity of brick via increasing particles packing. In this relation, 1 wt. % nano-magnesia addition was determined as optimum content. Further addition of nano-magnesia leads to increasing of porosity via agglomeration of particles. Due to the high surface area of used nano-magnesia particles, the adequate sintering of refractory brick containing nano-magnesia take places at 1400℃. This leads to increasing of particles bonding and then, increasing mechanical strength, but it can not affect the thermal shock resistance of refractory bricks. The microstructural evaluations showed the lower porosity and further particles bonding with addition of nano-magnesia optimum content.
 

In this paper, Ni-doped lead hexaferrites (PbFe12-xNixO19) nanoparticles with x = 0.2 were prepared by sol- gel method. Then, the effect of annealing temperature on its structural, magnetic and dielectric properties was studied. First, the dryed gel was evaluated by Thermogravimetry-Differential Thermal Analysis (TG/DTA) and then, the structural morphology, magnetic and dielectric properties of samples have been characterized by Fourier Transform Infrared (FT-IR) spectroscopy, X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM), Vibrating Sample Magnetometer (VSM) and LCR meter. The results of x-ray diffraction patterns show that by increasing annealing temperature up to 800 °C, PbFe11.8Ni0.2O19 phase percentage in the samples increases. Also, by increasing annealing temperature, the magnetization increases because the unwanted phases disappear and pure and single-phase lead hexaferrite are formed. By increasing frequency, first the AC electrical conductivity of the samples decreases and then increases. These variations have been explained by Maxwell- Wanger model. The result measurements show that the best sample is PbFe11.8Ni0.2O19 with annealing temperature of 800 °C for 3 h.
 

In this research, the effect of standoff distance and explosive material thickness on metallurgical features of explosive welding connection of copper to 304 stainless steel has been investigated. Experimental analysis were performed using optical microscopy, scanning electron microscopy, microhardness test and tensile shear strength test. The results indicated that due to severe plastic deformation in welding, both grain elongation and refinement occurred near the connection. Also, increasing of welding parameters led to an increase in the locally melted zones. The results showed that chemical composition of the melted zone consisted of elements of both flyer and base plates. By decreasing the explosive material thickness and standoff distance, the hardness of copper interface zone decreased from 103.4 HV to 99.8 HV. Moreover, increasing the temperature in stainless steel connection led to decreased hardness. As such, the maximum tensile shear strength of 244 MPa was observed  in the sample with 79 mm explosive thickness and 3 mm standoff and the minimum tensile shear strength of about 208 MPa in the sample with 46 mm explosive thickness and 3 mm standoff. By decreasing explosive thickness and standoff, the bond strength decreased, too.
 

In this study, iron powder (~45 μm) with the  minimum purity of 99% was insulated by the 1 to 4 wt% sodium silicate insulator (SiO₂.3Na₂O solution in 40 wt% water) and the 0.5 wt% zinc stearate. Insulated powders were pressed in a die with  a toroidal shape at the pressure of 320 MPa. The effects of insulator percentage and annealing temperature on the magnetic permeability, core loss tangent, and the total loss were investigated. The results indicated that the sodium silicate insulator could be suitable for insulating iron powders used in iron powder cores for high frequencies up to 1000 kHz. Also, this insulator could be stable against heat up to 450 °C.

In this study, the synthesis of nano-porous calcium magnesium silicate was performed and studied to improve drug properties and drug release. This synthesis was carried out by using the tetraethyl ortho silicate precursor (TEOS) and the Cetyltrimethyl ammonium bromide surfactant (CTAB) in a sol-gel alkaline environment; and the product was heat treated at 600° C and 800° C temperatures. The purpose of this study is to investigate the effect of the calcination temperature on the potential for ibuprofen release by the production produced compound. The product was studied using X-ray diffraction patterns (XRD), Nitrogen adsorption / desorption, Fourier-transform infrared spectroscopy (FTIR), ultraviolet spectroscopy (UV) and Transmission electron microscopy (TEM), and field emission scanning electron microscopy (FE-SEM). The results of Nitrogen absorption-desorption assay showed a surface area of 42-140 m² /g The drug release after 240 hours showed that the calcite sample had a lower release at 600 ° C, temperature that which was is due to the smaller size of the cavities and the more surface area, as compared tothan the other specimens. Also, calcium and magnesium elements increased  the loading capacity, and createcreating a suitable substrate for for the slower drug release. Overall, This this study showed that nano-porous magnesium silicate calcium has had  the ability to load and release the ibuprofen and can could be, therefore, used as a modern drug delivery system in the bone tissue engineering field.
 

In the present study, the mechanical alloying process was used to produce the Ni-Nb-Si amorphous alloy. X-ray diffraction (XRD)analysis and high-resolution transmission electron microscopy (HRTEM) were used to approve the amorphous phase formation after 12 hours of mechanical alloying. The results obtained from the SEM morphological images of powder particles during mechanical alloying showed that increasing the milling time caused the reduction  of the powder particles size and uniformity in the shape of the particles. Enhancing the embrittlement and fracturing rate caused brittleness and the  increase in the  failure rate; these were followed by a decrease in the powder particle size to 1-5μm. Cold welding and flattening of the pure elemental powders after mechanical alloying for 2 hours formed a lamellar structure of the alternative layers of different elements lying over each other. SEM image of cross-section of powder particles showed that by increasing the milling time, the interlamellar spacing was decreased, the elements were distributed more uniformly, and finally, a uniform structure of theamorphous phase was completed.