Showing 238 results for Gh
M. Judaki, M. Seifollahi, S. M. Abbasi, S. M. Ghazi Mir Saeed,
Volume 40, Issue 1 (Journal of Advanced Materials-Spring 2021)
Abstract
In this article, the effects of Pr and Nd were investigated on the microstructure and absorption/desorption characteristics of MmNi5 hydrogen storage alloy. The alloys were prepared in Vacuum induction furnace and the microstructures and phases were analyzed using scanning electron microscopy (SEM) equipped with energy dispersive X-ray analysis (EDS) and X-ray diffraction (XRD). Hydrogen absorption/desorption characteristics was performed on Sievert apparatus. The results showed that the microstructure of the alloys consist of matrix, second phase as a result of Al segregation, porosities and cracks. The amount of second phases and Al in this phase in Mm(Pr,Nd)Ni4.7Al0.3 is less than MmNi4.7Al0.3. Al in Mm(Pr,Nd)Ni4.7Al0.3 were more homogenized. Pressure-Composition Isotherms of hydrogen absorption/desorption at 25˚C showed that for MmNi4.7Al0.3 and Mm(Nd,Pr)Ni4.7Al0.3, absorption pressures were 14.52 and 9.90 bar, desorption pressures were 5.53 and 5.49 bar, hydrogen storage capacities were 1.37 and 1.33 wt. % and hysteresis were 0.73 and 0.58, respectively. These results are useful in industrial applications, because of inconsiderable decrease in hydrogen storage capacity and the other positive variation in absorption/desorption characteristics, especially the hysteresis and absorption pressure.
H. R. Karimi, H. Mansouri, M. R. Loghman Estarki, M. Tavoosi , H. Jamali,
Volume 40, Issue 1 (Journal of Advanced Materials-Spring 2021)
Abstract
This study aimed to compare the phase changes and morphology of yttria-stabilized zirconium oxide powders (YSZ) synthesized by co-precipitation and molten salt methods. Ammonia precipitating agent was used for the synthesis of YSZ powder by co-precipitation method and a mixture of sodium carbonate and potassium carbonate salts was used as a molten salt in the molten salt method. Samples were characterized by X-Ray Diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Fourier Transform Infrared Spectroscopy (FTIR), Thermal Gravimetric Analysis (TGA), and Differential Scanning Calorimetry (DSC) analysis. The results showed that only the sample prepared with zirconium oxychloride and yttrium nitrate by co-precipitation method had a single phase of yttria-stabilized zirconium oxide with tetragonal crystal lattice and particle size distribution in the range of 30 to 55 nm. The powder synthesized by the molten salt method contained a mixture of zirconia with monoclinic crystal lattice and yttria stabilized zirconia with tetragonal crystal lattice and particle size of 200 nm.
M. Shayestefar, A. R. Mashreghi, S. Hasani ,
Volume 40, Issue 1 (Journal of Advanced Materials-Spring 2021)
Abstract
Mn0.8Zn0.2Fe2-xDyxO4 (where x= 0, 0.025, 0.05, 0.075, 0.1) ferrite nanoparticles were synthesized by auto- combustion sol-gel method for the first time in this study. The effect of Dy-doping on the structural and magnetic properties of the produced specimens was examined using the X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), vibrating sample magnetometery (VSM), and field emission scanning electron microscope (FE-SEM). The results showed that a cubic spinel structure was formed in all of the synthesized specimens. It was also found that the addition of Dy increased the lattice parameter while decreased the average of crystallites size. Furthermore, the FE-SEM micrographs showed that Dy not only plays an effective role in reducing the agglomeration of nanoparticles and their distribution, but also reduces the average of particle size. It was also observed that the addition of Dy had no effect on the morphology of the synthesized nanoparticles. Investigation of the magnetic properties revealed a clear decrease in the saturation magnetization and coercivity by the Dy addition. So that the saturation magnetization of the samples decreased from 66.3 to 58.4 emu/g and the coercivity decreased from 78.5 to 71.9 Oe.
M. Khosravi , M. Mansouri, A. Gholami, Y. Yaghoubinezhad,
Volume 40, Issue 1 (Journal of Advanced Materials-Spring 2021)
Abstract
In this research, the effect of graphene oxide (GO) and reduced graphene oxide (RGO) nanosheets on the mechanical and microstructural properties of AISI 304 stainless steel welded joints produced by the flux-cored arc welding (FCAW) method was investigated. Light microscope, field emission scanning electron microscope (FE-SEM) equipped with energy-dispersive X-ray spectroscopy (EDS), X-ray diffraction analysis (XRD), Raman spectroscopy, and tensile strength test were used to characterize the samples. GO was synthesized by modified Hummers’ method and reduced by hydrazine. Accordingly, the pastes of GO and RGO in different concentrations of 1, 3, and 10 mg/ml were applied in the groove. The results demonstrated that increasing the RGO concentration up to 10 mg/ml improves the tensile strength and hardness values of welded joints up to 23% and 43%, respectively. It seems that RGO nanosheets have a significant effect on the mechanical properties of the welded joints by pinning of dislocations.
S. Shahzamani, M. R. Toroghinejad, A. Asharfi,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
In this study, Al/Al2O3 composite was produced by accumulative roll bonding (ARB) process coupled with the plasma electrolytic oxidation (PEO) process. The alumina was grown on Al sheets by electrolyte technique with three different thicknesses (10, 20, and 40 µm). The results showed that incorporation of alumina up to 3.22 vol.% in aluminum matrix enhanced the yield and tensile strength of the composite, whereas increasing the amount of alumina up to 6.25 vol.% deteriorated the tensile properties. In the last part, a serial sectioning process was employed to develop a three-dimensional (3D) representation of the microstructure of Al2O3 particles reinforced Al composite for visualization and finite-element modeling (FEM).
S. Sarafrazian, M. Tavoosi, A. Ghasemi ,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
The aim of this study was optimization of the annealing process in melt spun Nd2Fe14B intermetallic magnetic alloy. In this regard, the melt spinning process was done at wheel speed of 40 m.s-1. In order to achieving the desired microstructure, the as-spun ribbons were subsequently annealed at temperature range of 500 to 700 ºC for different periods of time. Structural and magnetic characterization of produced samples were performed by X-ray diffraction (XRD), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). The results showed that the structure of as-spun ribbons at wheel speed of 40m.s-1 was composed of Fe-α, Nd2Fe14B and amorphous phases with the coercivity and saturation of magnetization in the range of 0.14 kOe and 120 emu/g, respectively. By annealing the produced ribbons and crystallization of the amorphous phase, the percentage of Fe-α and Nd2Fe14B was decreased and increased, respectively. The optimum annealing conditions for achieving the highest value of coercivity (about 9.2 kOe) was 600°C for 6h.
H. Fallah-Arani, S. Baghshahi, A. Sedghi, F. Shahbaz Tehrani,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
In this research, the influence of titanium dioxide nanoparticles on the structural and magnetic properties of high-temperature superconductor Bi1.6Pb0.4Sr2Ca2Cu3O10+θ (Bi-2223) from the Bi-based ceramic system (BSCCO) was studied. In order to investigate the synthesized samples, X-ray diffractometry and magnetic measurements were performed. Based on the magnetic measurements, the superconductivity transition temperature declined with the increase in the nanoparticles' content. The addition of nanoparticles affected on the hysteresis loop width. Accordingly, the compound containing 0.2 wt.% nanoparticles had the maximum magnetization, hysteresis loop width, and critical current density.
F. Delshad, M. Maghrebi, M. Baniadam,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
Carbon nanotubes contain impurities and deamorphization is one of the methods of their purification. In this study, for the first time, a solution of piranha with a ratio of 3:1 (30 ml sulfuric acid + 10 ml hydrogen peroxide) as well as microwave irradiation with processing time of 30 minutes were used to remove amorphous carbon from the nanotube arrays. Ultrasonication was performed to disperse pristine and purified carbon nanotubes in water and centrifugation was performed to separate large particles. To assess the removal of amorphous carbon, new characterization methods such as dispersed percent and floating percent were used. It was observed that with increase in the ultrasonication time (from 0 to 50 minutes), the dispersed percentage of treated arrays was increased (about 47%), while the floating percentage of pure array decreased (about 20%). These results are ascribed to the removal of amorphous carbon. The results of the thermo gravimetric analysis (TGA) were in good agreement with the results obtained from the newly proposed characterization methods.
R. Bagheri, F. Karimzadeh, A. Kermanpur , M. Kharaziha,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
A new method has been presented for the synthesis of copper (Cu)/copper oxide (CuO)-nanoparticles (NPs), based on the process of corrosion and oxidation of Cu-NPs on the surface of the gold electrode by nitric acid. Cu-NPs were deposited on the surface using potentiometric method. The high concentration of Cu-NPs was estimated by Differential Pulse Voltammetry (DPV). The process of growth and distribution of CuO-NPs on the surface of Cu-NPs using structural analysis of Fourier Transform Infrared Spectroscopy (FTIR) and X-ray diffraction (XRD) showed that nitrate was well absorbed and a sharp hydroxyl peak appeared and a phase of CuO NPs formed on the electrode surface. The surface morphology indicated that the average size reduced from about 150 nm to 50 nm in the presence of nitrate. This can be due to the oxidation of Cu nanoparticles on the surface and reduction of particle size compared to the absence of nitric acid. This simple and low-cost method can be used as a surface modification of antibacterial and active catalyst electrodes.
M. Ghorbani, H. Khorsand,
Volume 40, Issue 2 (Journal of Advanced Materials-Summer 2021)
Abstract
Strontium hexaferrite M-type nanoparticles doped with La and Cu (SrFe12-xCuxO19-Sr1-xLaxFe12-xCuxO19) with different mole fractions (x=0.1-0.2-0.3-0.4-0.5) synthesized by self-combustion sol-gel technique. Firstly, a gel of metal nitrates with the above-mentioned mole fractions were fabricated and the obtained powder was cured at 950°C. Microstructural properties and the morphology of the compounds were investigated by employing X-ray diffraction (XRD) and scanning electron microscopy (SEM). Also, in order to investigate the magnetic properties, Vibrating Sample Magnetometer (VSM) was used. SEM images revealed that the particles had an average size of about 100 nm. Cu2+ ions were substituted with Fe3+ ions within the crystalline sites of SrFe12O19 structure. It was shown that the lattice parameter (a) remained approximately unchanged with an increase in Cu-dopped while the lattice parameter (c) decreased with increasing the mole fraction (x). By using VSM hysteresis diagrams, it was observed that the saturated magnetization and coercive force increased with the addition of La; this was attributed to the variation in the distribution of ions and the shape anisotropy of the nanoparticles. These significant changes in the magnetic properties were for the sample with the composition of Sr1-xLaxFe12-xCuxO19 and SrFe12-xCuxO19, for the x=0.1 and x=0.5, respectively.
F. Fareghdeli, M. Karimi, A. Novin, M. Solati-Hashjin,
Volume 40, Issue 3 (Journal of Advanced Materials-Fall 2021)
Abstract
One challenge in preparing polymer/ceramic composites is non-uniform ceramic particles distribution in a polymer matrix. This research evaluated the effect of stirring time and temperature on hydroxyapatite (HA) distribution through (polylactic acid) PLA matrix. Therefore, to mix the ceramic suspension with the polymer solution, three temperatures, namely 25, 37, and 45°C and four times including 6, 12, 24 and, 48 h were examined. Fourier-transform infrared spectroscopy (FTIR) analysis was used to investigate the bonds, which showed physical bond formation such as carboxyl-calcium-carboxyl between HA and polymer matrix, influenced on particles distribution. Scanning electron microscopy (SEM) and Energy-dispersive X-ray spectroscopy (EDS) were used to observe particles distribution and determine samples homogeneity. To fulfill this goal, each obtained photograph representing the calcium presentation was split into nine equal sections, and a method based on the newly defined index called dispersion factor “α” was used to analyze the distribution. Results showed that the sample prepared at 37°C and 48 h had the topmost homogeneity properties.
P. Verdi, S. M. Monirvaghefi, F. Ashrafizadeh,
Volume 40, Issue 3 (Journal of Advanced Materials-Fall 2021)
Abstract
Regarding to the low rate of conventional Ni-P electroless plating method that needs more time to make a coating on the substrate surface, a new technique called “substrate local heating” was introduced based on the temperature parameter modification and its advantages were expressed and compared to the conventional electroless plating technique (temperature=90°C, pH=4.7). In order to provide necessary equipment making this approach practicable, electrical resistance was used as the heating source, and air injection and cooling water circulation were employed to control the solution temperature near the substrate and in the bulk solution, respectively. Considering the heater power (1000 W), the substrate and bulk temperatures were about 190°C and 80°C, respectively. This novel method could enhance the plating rate up to 32 µm/h which was about 60% greater than that of the conventional method, 20 µm/h. Moreover, benefits such as local plating, reduction of production costs, and formation of functionally graded coatings (FGC) can be achieved.
E. Mohagheghpour, R. Gholamipour, M. Rajabi, M. Mojtahedzadeh Larijani,
Volume 40, Issue 3 (Journal of Advanced Materials-Fall 2021)
Abstract
In this study, the amorphous carbon thin films were deposited by ion beam sputtering deposition method on the glass and Ni–Cu alloy substrates. The structural evolution of amorphous carbon and its correlation with the kinetic energy of carbon atoms during the growth of thin film was investigated. The effect of substrate material, deposition temperature, and ion beam energy on the structural changes were examined. Raman spectroscopy indicated a structural transition from amorphous carbon to diamond-like amorphous carbon (DLC) due to an increase in deposition temperature up to 100°C and ion beam energy from 2 keV to 5 keV. The size of graphite crystallites with sp2 bonds (La) were smaller than 1 nm in the amorphous carbon layers deposited on Ni-Cu alloy. The results of residual stress calculation using X-ray diffractometer (XRD) analysis revealed a decreasing trend in the tensile residual stress values of the amorphous carbon thin films with increasing the ion beam energy.
N. Ghobadi, S. A. Hosseini Moradi, M. Amirzade,
Volume 40, Issue 4 (Journal of Advanced Materials-Winter 2022)
Abstract
In this research, cobalt ferrite powders (CoFe2O4) and cobalt ferrite/reduced graphene oxide composite (CoFe2O4/RGO) were synthesized by the co-precipitation method. The phase structure, morphology, magnetic properties, and microwave absorption properties of the produced samples were investigated through various techniques. X-ray diffraction test indicated the successful formation of pure CoFe2O4 and its composites with RGO. According to the Scanning electron microscopy (SEM) images, most pure and composite samples’ particles were formed in a semi-spherical shape. The VNA test results showed the saturation magnetization of CoFe2O4 and the composite containing 5 wt.% and 10 wt.% of RGO, 71.6, 56, and 37 emu/g, respectively. Also, the network analyzer results demonstrated the maximum reflective losses in the X-band range due to the impact of microwaves on CoFe2O4 te was -5.5 db. This amount reached 21.5 dB with the addition of 10 wt.% RGO. Also, the wave input increased from 41% for the pure CoFe2O4 to 99.5% for the sample containing 10 wt.% RGO.
H. Fallah-Arani, N. Riahi-Noori, S. Baghshahi, A. Sedghi, F. Shahbaz Tehrani,
Volume 40, Issue 4 (Journal of Advanced Materials-Winter 2022)
Abstract
In this research, the effect of addition of silicon carbide (SiC) nanoparticles on the improvement of the structural, superconductivity, magnetic, and flux pinning properties of high-temperature superconductor Bi1.6Pb0.4Sr2Ca2Cu3O10+θ (Bi-2223) was investigated. The Bi-2223 ceramic superconductor was prepared using the sol-gel method, and silicon carbide nanoparticles were modified by Azobisisobutyronitrile (AIBN). The X-ray diffractometry, feild emission scanning electron microscopy, magnetic susceptibility, and hystersis loop measurements were performed to characterize the synthesized compounds. Based on the magnetic measurements, the superconductivity transition temperature dropped with an increase in the content of nanoparticles. Also, the maximum magnetization, hysteresis loop width, critical current density, and magnetic flux pinning force belonged to the sample with 0.4 wt.% SiC nanoparticles.
M. H. Rezvani, M. Yeganeh, S. M. Lari Baghal,
Volume 41, Issue 1 (Journal of Advanced Materials-Spring 2022)
Abstract
In this study, the addition of organic methionine inhibitor (as an eco-friendly inhibitor) to 0.1 M sulfuric acid media on corrosion resistance of 316L austenitic stainless steel (fabricated by rolling method and three-dimensional (3D) printing method) was investigated. Open-circuit potential electrochemical test and impedance, and structural tests such as optical and electron microscopy and x-ray photoelectron spectroscopy were conducted. The results showed that the corrosion resistance in the presence of inhibitor was higher than the sample without inhibitor and the inhibitory efficiency of methionine was increased up to 64% and the resistance to surface transfer between metal oxide and electrolyte was improved up to 2.77 times. The addition of methionine reduced the surface roughness and accumulation of the surface cavities. The chemical and physical adsorption mechanism of the inhibitor (negatively charged side adsorption of the methionine molecule with positively charged anodic regions of the metal surface) occurred at all points on the surface of the sample with the inhibitor. Also, the amount of oxygen in the cavities was reduced and the distribution of sulfur was uniform. The thickness of the passivator oxide layers was calculated more than the sample without inhibition due to the addition of inhibitor.
M. Ghalambaz, M. Shamanian, A. M. Eslami, M. Abdollahi, E. Abdoulvand,
Volume 41, Issue 1 (Journal of Advanced Materials-Spring 2022)
Abstract
This research investigated the bonding properties of AISI 321 austenitic stainless steel from microstructural, mechanical, and corrosion points of view. To obtain the optimal parameters of pulsed current gas tungsten arc welding (PCGTAW), the Taguchi method was used. A cyclic potentiodynamic polarization test evaluated the corrosion resistance of the welded samples. The optimal conditions were achieved when the background current, the pulse current, the frequency, and the percentage of the pulse on time were 50 amps, 140 amps, 5 Hz, and 50, respectively. On the other hand, the analysis of variance showed that the percentage of pulse on time equal to 36 and the background current equal to 46 amperes were the most influential factors on the surface current density of the austenitic stainless steel 321 connection using the PCGTAW process. The mechanical properties were assessed using punch shear testing. In the optimal condition, the maximum shear force and strength were 3200 N and 612 MPa, respectively. The results showed that the most critical factor affecting the bonding properties of 321 steel was the heat input.
F. Dehghani Firoozabadi, A. Ramazani Saadatabadi, A. Asefnejad,
Volume 41, Issue 1 (Journal of Advanced Materials-Spring 2022)
Abstract
Today, many people need to use bone grafts and implants because of damage to bone tissue. Due to the stimulation of the immune system after implantation, infection at the operation site is very common, which causes swelling and pain in the operation area. The use of zinc oxide nanoparticles reduces infection at the operation site and reduces the patient's need for antibiotics. In the present study, the morphology of the scaffolds was investigated by field emission scanning electron microscope (FE-SEM). The toxicity of the samples was evaluated using MTT assay. The behavior of nanocomposites against Escherichia coli and Staphylococcus aureus was investigated by measuring the diameter of the growth inhibition zone. It was found that modification of scaffolds with nanoparticles caused a growth inhibition in bacterial culture medium. It was also observed that fibroblast cells on the surface of the modified scaffolds had longer survival than polymer scaffolds. This study showed that the addition of oxidizing nanoparticles improves the antibacterial properties of scaffolds and cell viability and reduces scaffold toxicity.
R. Zarei, E. Mohammadsharifi, M. R. Loghman, M. Ramazani, Kh. Zamani,
Volume 41, Issue 1 (Journal of Advanced Materials-Spring 2022)
Abstract
The present research has examined the effect of adding Si3N4 on the mechanical and structural properties of NiCrAlY alloy. The structural and mechanical properties of the manufactured samples were characterized by SEM, XRD, micro-hardness evaluation and pin on disk wear test. Various concentrations of Si3N4 powder (1, 3, and 5 wt.%) were mixed with NiCrAlY powder using a mechanical ball mill. Next, the mixtures were sintered at 1100 °C using the spark plasma sintering (SPS) technique. The XRD patterns indicated that the samples were composed of two phases of solid solution γ-Ni(Cr) and intermetallic compounds β-NiAl. The results of micro-hardness measurements showed that adding 1% Si3N4 to NiCrAlY enhanced the hardness from 418 to 614 HV. However, with an increase in the Si3N4 content from 1 to 5 wt%, the hardness diminished from 614 to 543 HV, and by Adding Si3N4 to the NiCrAlY, its tribological properties were significantly improved.
A. Mehdikhani, H. Fallah-Arani, F. Dabir, A. Ghanbari,
Volume 41, Issue 2 (Journal of Advanced Materials-Summer 2022)
Abstract
In this research, the effect of hydrogen peroxide (H2O2) and benzoyl peroxide (BPO) on the structural properties, porosity, active pores, and surface area of the MOF-5 (Zn4O(BDC)3) metal-organic framework was studied. For this purpose, the metal-organic framework was synthesized by direct mixing and the molar ratios of the precursors to the ligand were modified to minimize the stoichiometric calculation error as well as the washing process to improve the properties of the synthesized MOF-5. In order to characterize the synthesized compounds and to investigate the effect of peroxides and washing process on the properties of the samples, X-ray diffraction (XRD), fourier Transform infrared spectroscopy (FTIR), and thermogravimetric/Differential scanning calorimetry (TG-DSC) analysis were performed. Structure, pore volume (1.212 cm3/g), and specific surface area (2307 m2/g) were compared to the sample synthesized with H2O2. DM-P-03 was selected as the optimal sample and prepared for thermal stability. According to TG-DSC analysis, the remaining zinc compounds in the sample were checked and the thermal stability of MOF-5 structure was confirmed up to 470°C.
