Journal of Advanced Materials in Engineering (Esteghlal)

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In some applications such as morphing technology, high strain and anisotropic behavior are considered a good advantage. The corrugated composite sheets due to their special geometries have a potential of high deflection under axial loading. In this research, to investigate the strain and anisotropic behavior of corrugated composite sheets some glass/epoxy samples with Quasi-sinusoidal, trapezoidal, rectangular and triangular geometries were manufactured and put to tension and flexural tests in the longitudinal and transverse directions of corrugation. Then, in order to determine anisotropic behavior of corrugated sheets two concepts were introduced: tensile anisotropic and flexural anisotropic criteria based on which anisotropic magnitude was investigated theoretically and experimentally. This research used Yokozeki’s theoretical model for quasi-sinusoidal geometry and his model for trapezoidal, rectangular and triangular geometries. Experimental results showed that corrugated sheets have a strain more than 90%. In the corrugated samples, the strain magnitude was dependent on amplitude and pitch of elements in other words, it was dependent on the number of elements per length unit. Generally, the Quasi-sinusoidal corrugated sheets have a high strain (more than 50%). Experimental results of trapezoidal sheets showed that amplitude of the elements is one of the most important parameters in the ultimate strain. Generally, increasing the amplitude leads to the growth of the ultimate strain

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In this study, the effect of different amounts of Y2O3 on the properties of mullite-zirconia composites was investigated. For this purpose, these composites were fabricated by reaction-sintering of alumina and zircon as raw materials. Besides, the slip casting method was used for forming these composites, and sintering process was carried out at 1600 °C. Then, the physical and mechanical properties, phase composition and the microstructure of these composites were investigated. The results showed that yittria addition up to 0.5 wt.% has no effect on the properties of these composites. Besides, addition of more than 0.5 wt.% yittria formed solid solution with zirconia grains and led to stabilization of tetragonal zirconia phase and increasing of its amount. Hence, yittria addition increases the hardness and bending strength of composite by stabilizing tetragonal zirconia phase and then, decreasing the micro-crack formation during zirconia phase transformation. As results show, addition of 0.75 wt.% yittria leads to a considerable increase in the bending strength.

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Due to their superior properties such as high specific strength, high creep resistance and high strength at elevated temperatures, aluminum composites reinforced with alumina nano particles are widely used for advanced purposes such as aerospace and auto industries. Lack of an appropriate welding process limits their applications. Transient liquid phase (TLP) bonding is one of the state-of-the-art joining processes. It is used for welding composites and advanced materials. Microstructure and mechanical properties of TLP bonding depend on the bonding time and temperature. In the current study, the effect of bonding time on the microstructure and bonding strength of the TLP diffusion bonded of Al2O3p/Al nanocomposite was investigated. A thin layer of copper deposited by electroplating was used as an interlayer. The bonding times of 20 and 40 min were not sufficient for completing the isothermal solidification, and the bonding strengths were not satisfactory. By increasing the bonding time to 60 min at constant bonding temperature of 580 ºC, the isothermal solidification was completed and the final joint microstructure consisted of soft α-Al phase with dispersed CuAl2 precipitated particles. Decreasing the amount of brittle eutectic structures in the joint seam by increasing the bonding time was the main reason for improvement of the joint shear strength. The maximum joint shear strength was achieved at 580 ºC for 60 min which was about 85% of the shear strength of the base material.

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Employing direct and alternative electric currents at the time of casting and solidification modified grains of Al and Si. The highest wear resistance was obtained in the direct current, and for alternative current the wear resistance corresponded to the electric current. The change of polarity in the pure Al did not influence the wear resistance, but for the Al-Si alloy the highest wear resistance was obtained when the mold was connected to the positive and the molten metal to the negative pole. Direct current used in the Al-Si alloy brought about three different microstructures including the stretched clusters of Si in the electrons' direction near the negative pole, fine clusters of Si in the intermediate zones that surrounded the oval shape of α-Al, and broken Si clusters near the positive pole.

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In this paper, the effect of MgCl2 addition on the kinetics of MA spinel formation was investigated. For this purpose, the stoichiometric mixture of MgCO3 and calcined aluminum was calcined at 1100 °C for 1 hr. Then, the calcined composition was wet-milled and after addition of 6% MgCl2 the compositions were pressed and fired at 1300 and 1500 °C for different times. Spinel phase content was determined using semi-quantitative phase analysis. With regard to Jander's equation, the rate constant was calculated, and the activation energy was obtained from Arrhenius equation. The results showed that the addition of MgCl2 leads to the acceleration of the spinel formation reaction. Besides, 55.71 Kcal/mol as the activation energy was calculated for the composition containing 6 wt.% MgCl2 compared with 93.06 Kcal/mol for the composition without MgCl2.

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Fe-Co alloys have unique magnetic applications. Fe50Co50 alloy has the highest saturation magnetization value among Fe-Co alloys. Moreover, the introduction of Si into Fe can result in a decrease of magnetic anisotropy. In this study, in order to utilize combined advantages of Si and Co, the effect of adding 10 and 20 at.% Si on the microstructural and magnetic properties of Fe65Co35 alloy was investigated. For this purpose, initial powder mixtures with specific compositions were milled by means of planetary ball mill for different milling times. Microstructural properties and morphology of the obtained powders were analyzed by X-ray diffraction analysis (XRD) and scanning electron microscope (SEM). Also, magnetic properties of the samples were determined by means of vibration sample magnetometer (VSM). The results showed that the crystallite size was finer and more uniform and lattice strain was decreased slightly for longer milling times. Observations indicated that the addition of Si to the alloys leads to finer particles. The results also showed that increasing the Si content increases the reduction rate of lattice parameter and coercivity.

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In this research according to unique properties of fused silica and Its numerous applications fused silica parts with 77% by weight solid loading formed by gel casting. Rheological behavior of the slurry and sintering conditions were optimized. Sample sintered at optimum conditions has bulk density of 1.71 g/cm3, open porosity of 18.13%, water absorption of 10.60%, linear shrinkage after firing of 3.5%, closed porosity of 1.09% and relative density of 78.80%. Its thermal expansion coefficient in range of room temperature to 1000 ◦C has been measured 0.4432×10-6 1/ . Results showed that With increasing temperature and time In addition to the increased vscous flow, Crystallization also extend. Finally sintered at high temperature and short time for an instance with the lowest overall high crystallinity and density, were found suitable

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In this study, Al/Steel multilayer composite was produced by accumulative roll bonding (ARB) process using Al-1100 and St-12 strips. Microstructure, mechanical properties and corrosion behavior of the composite were studied by scanning electron microscopy (SEM), tensile test, Vickers microhardness tests, cyclic polarization and electrochemical impedance spectroscopy (EIS) measurement in 3.5 wt% NaCl solution. After one ARB cycle (2 roll-bonding cycles), the multilayer composite of 4 layers of Al and 2 layers of steel was produced. The tensile strength of the Al/steel multilayer composite reached 390.57 MPa after the first ARB cycle, which was 1.29 times larger than that of the starting steel while composite density was almost half the density of the steel. Corrosion behavior of the composite revealed a considerable improvement in the main electrochemical parameters, as a result of enhancing influence of cold rolling. The results indicated that strength and corrosion resistance of Al/steel composite generally decreases and elongation increases after annealing.

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In this study, mixed metal oxides Al2O3/MgO/TiO2 coatings with Al/Mg/Ti ratios of 5:1:3 and 2.5:3:4 were coated on AA1100 aluminum by sol-gel method. The surface morphology, phase analysis and the corrosion behavior of the Al2O3/MgO/TiO2 coatings were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), and electrochemical impedance spectroscopy measurements (EIS) in 3.5 wt.% NaCl solution. The thermal behaviors, the bonds configuration, and functional groups of the coated samples were studied by thermo-gravimetric and differential thermal analysis (TG-DTA) and Fourier transform infrared spectroscopy (FTIR), respectively. The results demonstrated that heat treatment at 450 °C caused an increase in porosity and coating cracking, finally leading to the decrease of corrosion resistance. The best corrosion resistance was achieved for the sample with Al/Mg/Ti molar ratio of 5:1:3 without any heat treatment. The structure of this sample was amorphous, and heat treatment resulted in crystallization and decrease of the corrosion resistance.

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This research aimed at producing microcellular foams (with cell size of 1-10 μm and cell density above 10 9 cell/cm3) from PC/EPDM in order to use in medical devices. Due to the weak nucleation behavior of microcellular polycarbonate foams, it is difficult to prepare them. This research provides valuable information regarding the possibility of making microcellular foams from this polymer by using multiwalled carbon nanotubes (MWNT,s) as nucleating agents (the value of 1-3 phr). The nanocomposite samples were prepared in an internal mixer and foamed via a batch processing method using supercritical carbon dioxide as the foaming agent. The results showed that the addition of nanoparticles up to 3 phr improves the foamability of PC/EPDM blend. Furthermore, as nanoparticle content increased a decrease in cell size and hence an increase in cell density were observed. Another finding showed that cell size distribution is directly related to uniform dispersion of carbon nanotubes.

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Mechanical property of porous nickel-titanium alloy produced by volumetric combustion synthesis (VCS) for bone surgery applications is reported in this paper. Stress-strain behavior of the alloy is determined by uniaxial tension test. Superelastic diagram of the porous alloy is compared with that of the solid material cooled from austenite stability temperature. Due to movements of the dislocations, growth of the nucleation sites and thinning of the martensite plates during cooling, plastic deformation and necking behavior of these materials are principally different from that of the ordinary materials. Elastic modulus and yield stress of the material have nonlinear relationship with porosity percentage and obey the following correlations  and The stress-strain curves of the alloy show more than 6 percent elongation before rupture, even with 30 percent porosity. A comparison of the cleavage surfaces of the combustion synthesis samples with those of the powder metallurgical ones indicate great influence of production process on fracture mechanism.

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In recent years, much research has been performed in the field of nanomaterials synthesis using mechanochemical process. In this research, TixAly/Al2O3 ceramic matrix nanocomposite was produced by the mechanochemical method. Aluminum and inexpensive titanium oxide powders were used as raw materials, and milling was performed under N2 atmosphere. The results showed that reduction of TiO2 by Al is the first step of synthesis process, and then Ti reacts with residual Al. The synthesis after 10 hours of milling resulted in titanium aluminide and aluminium oxide. With the increase of milling time to 80 hours, titanium aluminide quantity was increased. Also, the results showed that the heating of samples containing titanium aluminide in the argon and nitrogen atmospheres does not lead to complete decomposition of aluminides.

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In this study, ZrB2-HfB2 composite was produced by pressureless sintering method. MoSi2 B4C and SiC particles were used as reinforcement. ZrB2 powder was milled in planetary ball mill apparatus and then reinforcement particles were added to the milled powder. The composite powders were then CIPed and sintered at 2100oC and 2150oC. Scanning electron microscopy (SEM) with an energy dispersive X-ray spectrometer (EDS), flexural test, and resonance frequency method were used to compare the added particle effects on mechanical properties and pressureless sintering behavior of ZrB2-HfB2 composite. The analysis showed that the ZrB2-HfB2-MoSi2-SiCnano composite displays the largest gain in flexural strength. Furthermore, increasing the sintering temperature leads to an increase in flexural strength of samples.

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In the present study, pure Aluminum powder with 5%wt Titanium Dioxide was mechanically milled at different times. Using phase analysis through X-ray diffraction (XRD), it was found that increasing of the milling times over 10 hours causes the reduction of Titanium by Aluminum and formation of Al2O3 in the structure. Also, it was shown that if the process persists, Aluminum reacts with Titanium and causes the formation of Al3Ti in the composition. The reactions were studied through the thermodynamic relations. Furthermore, after distribution of reinforcement particles in the matrix, using X-ray diffraction peak broadening, according to Williamson-Hall equation, the mean crystallite size and lattice strain were determined, and by scanning electron microscopy (SEM), the structure and morphology of the powder particles were studied.

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In this study, the effect of different amounts of Y2O3 on the properties of mullite-zirconia composites was investigated. For this purpose, these composites were fabricated by reaction-sintering of alumina and zircon as raw materials. Besides, the slip casting method was used for forming these composites, and sintering process was carried out at 1600 °C. Then, the physical and mechanical properties, phase composition and the microstructure of these composites were investigated. The results showed that yittria addition up to 0.5 wt.% has no effect on the properties of these composites. Besides, addition of more than 0.5 wt.% yittria formed solid solution with zirconia grains and led to stabilization of tetragonal zirconia phase and increasing of its amount. Hence, yittria addition increases the hardness and bending strength of composite by stabilizing tetragonal zirconia phase and then, decreasing the micro-crack formation during zirconia phase transformation. As results show, addition of 0.75 wt.% yittria leads to a considerable increase in the bending strength

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Silicon nitride has attracted a considerable attention because of its excellent properties such as high-temperature strength, good oxidation resistance, high corrosion resistance, good thermal shock resistance, high creep resistance and good thermal and chemical stability. There are several different fabrication methods for synthesizing Si3N4 particles. Such methods are mostly costly and kinetically slow and require lengthy heat treatment. In this study, Si3N4 compounds were synthesized by means of mechanical milling. In the mechanical milling route,Si powder (≤99.0%) was milled under nitrogen gas for 25 h and heated at various temperatures 1100-1200-1300 and 1400 C for 1 h at the nitrogen atmosphere at a rate of 200 ml/min. Silicon powder was also annealed under a similar condition in order to evaluate the impact of milling process on the low temperature synthesizing of Si3N4. Phase identification and microstructural characteristics of products were evaluated by X-ray diffraction, scanning electron microscopy and energy dispersive spectroscopy. The Fourier transform infrared spectroscopy and thermal analysis were used for characterization of the formed bands and thermal treatment of the sample, respectively. The obtained results exhibited that Si3N4 powder was fully formed with two kinds of morphologies including globular particles and wire with a width of 100–300 nm and length of several microns at sintering temperature of 1300 C. This was confirmed by the Si–N absorption bonds in the FTIR trace. Based on XRD results, 25 h milling reduced temperature of reaction remarkably in comparison with direct nitridation of Si powders for 1 h. With an increase in the reaction temperature, the Si3N4 samples had a phase transformation 𝛂→𝛃, and variation of the morphology followed the vapor–liquid -solid mechanism.

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In this study, the chemical composition, thickness and tribocorrosion behavior of oxide films prepared on Ti-6Al-4V alloy by anodising treatment in H2SO4/H3PO4 electrolyte at the potentials higher than the dielectric breakdown voltage were evaluated. The thickness measurement of the oxide layers showed a linear increase of thickness by increasing the anodizing voltage. The EDS analysis of oxide films demonstrated precipitation of sulfur and phosphor elements from electrolyte into the oxide layer. Tribocorrosion results indicated that the tribocorrosion behavior of samples was significantly improved by anodising process. Furthermore, the tribocorrosin performance of thesamples anodised at higher voltages was enhanced. SEM and EDS of worn surfaces indicated that the oxide layer on the samples anodised at lower voltages was totally removed, but for the samples anodised at higher voltages, the oxide layer was only locally removed within the wear track. Moreover, measurement of wear volume of the treated samples exhibited lower values on the samples anodised at higher voltages.

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In this research, ZrC nano particles were synthesized by self-propagating high temperature (SHS) using the mixed powder of ZrO2-C-Mg and NaF or NaCl diluent. The effect of different proportions of raw materials, milling time, composition of the diluent and also pickling on the synthesis of ZrC was investigated. Optimal amounts of magnesium and sodium fluoride for the synthesis of ZrC were 2.8 and 2 mol, respectively. Milling process of 120 minutes decreased the diffusion gap of raw material and increased the combustion reaction progress. XRD and SEM analysis showed that the NaF diluent more than NaCl caused a reduction in the size of the particles of ZrC and increased the progress of the combustion reaction. Synthesized samples were subjected to pickling in order to remove impurities of MgO by 37% HCl, and distilled water was used to wash off NaF and NaCl residues. ZrC particle size of different samples were in the range of 50-90 nm.

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In this study, the effects of different parameters on charpy impact properties of pure and hybrid composite laminates reinforced with basalt and glass filaments were investigated. For this purpose, five types of basalt and glass laminates with quasi-isotropic stacking sequence, namely, a pure basalt, a pure glass, two inter-ply hybrid and one intra-ply hybrid composites were produced. Epoxy resin was used as matrix material. After that, the impact test was performed and the average absorbed energy of each type of specimens was determined. The results indicated that the pure basalt and nylon laminates had the highest and least absorbed energy, respectively. The hybrid laminates had the absorbed energy somewhere between the pure basalt and glass ones. Also, between the hybrid composites, the intra-ply laminate had a better impact performance than the inter-ply ones.

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Nickel ferrite based cermets and their relevant composites have been widely used as inert anodes for aluminum electrolysis due to their good combination of chemical resistance, thermal stability and mechanical properties. In this study, various NiO/NiFe2O4 composites consisting of 5, 10 and 15% NiO in conjunction with Cu/NiFe2O4 cermets containing 0.5, 10 and 15% Cu were prepared by powder metallurgy method. The degradation resistance of the developed inert composites was examined under hot corrosion condition by plunging samples in to the molten electrolyte at 1000ºC. The strength, toughness, hardness, relative density, microstructural observation, phase analysis and electrical resistivity were evaluated by 3-points bending tests, Vickers method, Archimedes method, scanning electron microscope, x-ray diffraction and conventional direct current four-probe techniques, respectively. The experimental results for NiO/NiFe2O4 composites showed that a significant improvement of toughness and degradation resistance continuously occurred with a moderate decrease in strength by increasing NiO content, while the relative density was increased only up to 5%NiO content. By increasing the Cu content in the cermet samples, all the properties such as strength, toughness and electrical conductivity were improved considerably but the degradation resistance decreased.