R. Bagheri and M.a. Golozar,
Volume 25, Issue 2 (1-2007)
Abstract
Using Electrostatic Spray Coating Technique, Polypropylene Powder (EPD 60R) was applied on carbon steel substrates at room temperature. In order to obtain a uniform coating, steel substrates with powder coatings were heated in a vacuum oven at various temperatures up to 250° C for various periods of time up to 45 min and a pressure of 200 mb. The coatings produced had thicknesses of around 470 microns. In order to modify the chemical structure of this polymer, the powder coatings containing various weight percentages of maleic (anhydride (MA) and a peroxide (TBHP or DCP) were also applied onto the steel substrates under the above conditions. Adhesion strength, wear resistance, and ductility of polymer coatings produced were assessed using ASTM standard methods. Results obtained revealed that the polymer coating containing 5 wt%. MA and 0.1 wt% TBHP had the best mechanical properties. Adhesive strength and wear resistance of this coating were 14.3 kgf and 250.3 cm, at 6 kgf, respectively, under the applied load of 6kg. Results obtained from DSC thermographs and IR Spectroscopy also proved the chemical bond formation (grafting) between the polymer and MA. The mechanical properties of coatings on steel substrate stem from such graftings.
M. Bahrami, G.h. Borhani, S.r. Bakhshi, A. Ghasemi,
Volume 35, Issue 3 (12-2016)
Abstract
Organic–inorganic hybrid coatings were prepared by sol–gel method and deposited on aluminum alloy 6061. Attenuated Total Reflectance-Fourier Transform Infrared (ATR-FTIR) spectroscopy and Scanning Electron Microscopy (SEM) were used for structural study of the hybrid coatings. Adhesive strength of sol–gel coatings to the substrate was evaluated quantitatively and qualitatively. Corrosion behavior of the samples was studied by cyclic potentiodynamic and linear polarization tests. Results showed that adhesion strength of the coatings to the substrates was increased with increasing tetrapropoxide of zirconium (TPOZ) and cerium content. Corrosion tests showed that corrosion current density of coated samples were decreased three to seven orders of magnitude in comparison with uncoated aluminum alloy 6061. Decreasing in corrosion current density and increasing in polarization resistance was observed by increasing zirconia and cerium content. Unlike the uncoated aluminum alloy 6061, the crack-free coatings did not show pitting tendency.
M. Falsafein, F. Ashrafizadeh,
Volume 37, Issue 2 (9-2018)
Abstract
Nitride coatings with excellent hardness and wear resistance have been deposited by physical vapor deposition (PVD) in recent years. For most applications, the load bearing and adhesion of coatings are very important and can determine the life and performance of the final components. In this study, CrN/CrAlN nanostructured coatings with different thicknesses and numberes of layers were deposited on the stainless steel AISI 420 and hot-work tool steel by cathodic arc evaporation. Nanoindentation, X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) were used for the structural characterization and estimation of stress in the coatings. Adhesion of coatings was evaluated by scratch adhesion and VDI 3198 Rockwell tests. The results revealed the high values of compressive residual stress in the physical vapor deposited coatings, in the range of 500 to 1800 MPa, with a detrimental effect on coating adhesion. Load bearing capacity was observed to be dependent on the thickness and adhesion of coating, reaching the maximum at an optimum thickness. Overall, the results proved that the type of steel substrate could have a significant influence on the coating adhesion.
