Showing 4 results for Electroplating
A. Saatchi, H. Yan, and S. J. Harris,
Volume 20, Issue 1 (7-2001)
Abstract
Zinc was electrodeposited from an acidic sulphate solution on commercial steel sheet substrates galvanostatically at 10, 20, and 100 mA/cm2. The steel substrates had an average roughness number of 1.34 microns and a high percentage of its grains had their (111) planes parallel to the plate surface. During electrodeposition at 10 mA/cm2, on some specimens, there was an intense potential fluctuation around –870 mV vs Saturated Calomel Electrode (SCE). During this period zinc hydroxide precipitated on the surface. After a certain time, the potential dropped to –1020 for zinc deposition. Zinc nuclei were seen to precipitate from zinc hydroxide. Increasing current density changed nucleation mode from progressive to instantaneous, and also changed the size, morphology, and texture of zinc deposits.
Keywords: Zinc Electroplating, Current Density, Morphology, Orientation
A. Nasr-Esfahany and M.heydarzadeh Sohi,
Volume 23, Issue 2 (1-2005)
Abstract
Zinc-Nickel electrodeposits have been widely adopted for surface treatment of automobile steel sheet for high corrosion resistance. In this work the effect of pulse parameters on the Zn-Ni alloy electrodeposits was investigated. The hardness, thickness, corrosion resistance and composition of deposits thus produced were investigated. The surface topography of the deposits was also observed in SEM and results are reported. It has been shown that the thickness of the pulse electrodeposits
was almost even. The hardness in the pulse electrodeposits increased by increasing the on-time period and by decreasing the current density. It was also noticed that increasing the on-time period increases the nickel content of the deposit. Pulse electrodposits had fine structure and the structure become finer by reducung the on-time period and pulse frequency. The corrosion dehaviors of the deposits were then investigated. The results showed that the corrosion resistance of the DC electrodeposits improves in their nickel content increases. Pulse electodeposits show the same behavior, but deposits with about 13% nickel show maximum corrosion resistance.
H. Rashtchi, M. Shamanian, K. Raeissi,
Volume 36, Issue 4 (3-2018)
Abstract
Stainless steel bipolar plates are preferred choice for use in Proton Exchange Membrane Fuel Cells (PEMFCs). However, regarding the working temperature of 80 °C and corrosive and acidic environment of PEMFC, it is necessary to apply conductive protective coatings resistant to corrosion on metallic bipolar plate surfaces to enhance its chemical stability and performance. In the present study, by applying Ni-Mo and Ni-Mo-P alloy coatings via electroplating technique, corrosion resistance was improved, oxid layers formation on substrates which led to increased electrical conductivity of the surface was reduced and consequently bipolar plates fuction was enhanced. Evaluation tests included microstructural and phase characterizations for evaluating coating components; cyclic voltammetry test for electrochemical behavior investigations; wettability test for measuring hydrophobicity characterizations of the coatings surfaces; interfacial contact resistance measurements of the coatings for evaluating the composition of applied coatings; and polarization tests of fuel cells for evaluating bipolar plates function in working conditions. Finally, the results showed that the above-mentioned coatings considerably decreased the corrosion and electrical resistance of the stainless steel.
F. Shahriari Nogorani, M. Afari, M. A. Taghipoor, A. Atefi,
Volume 39, Issue 1 (5-2020)
Abstract
Practical applications of thermal barrier coatings with aluminide bond-coats are limited due to oxide scale spallation of the aluminide coating under applied thermal stresses. Considering the positive effects of oxygen-active elements or their oxides on the high temperature oxidation behavior, in this research zirconia was introduced into an aluminide coating. For this purpose, a Watts type bath was used to electroplate a layer of Ni-ZrO2 composite on a Ni-based substrate. Aluminizing was performed using the conventional two-step process at 760 and 1080 °C. Microstructural characterization of coatings in the as-coated conditions and after cyclic oxidation via 5-hour cycles at 1050 °C was performed using electron microscopy, energy dispersive spectroscopy and X-ray diffractometry. The results showed that the general three-zone microstructure of the simple high activity aluminide coatings develops below the pre-deposited nickel-zirconia layer and latter converts to a nearly un-alloyed porous NiAl. In spite of its porous surface layer, the zirconia modified coating has a higher oxidation resistance than the unmodified aluminide coating.
