Showing 9 results for Amorphous
S. Mirzaei , A. Jazayeri Gharehbagh,
Volume 31, Issue 1 (6-2012)
Abstract
The soft magnetic nanocrystalline Fe73.5Si13.5B9Cu1Nb3 alloy (FINEMET®) is produced by heat treatment of amorphous precursor. Determining kinetic parameters of amorphous structure transformation to nanocrystalline allows the control of microstructure (e.g. size and volume fraction of nanocrystalline grains) in order to achieve desired soft magnetic properties by optimizing the heat treatment conditions. In this research, the nanocrystallization kinetics of amorphous FINEMET alloy were studied using isoconversional and isokinetic methods under non-isothermal conditions of various heating rates ranging from 5 to 20˚C/min. The changes in the microstructure and magnetic properties of amorphous ribbon during nanocrystallization process were studied using X-ray diffractometry and hysteresisgraph, respectively.
A. Zare, M. Hadi, A. Ghasemi, H. Karimi , M. Sadeghi,
Volume 34, Issue 2 (7-2015)
Abstract
The aim of this investigation was to produce Ti47Al48Mn5 intermetallic compounds with different microstructures in order to study their oxidation behavior. The reason for selecting manganese as an alloying element was to enhance the toughness of the compound. Ti47Al48Mn5 alloys were obtained through mechanical alloying, cold pressing and heat treatment. XRD results showed that milling of the elemental powder mixture for 30 hours causes the formation of Al and Mn in Ti solid solution, while by increasing milling time up to 50 hours, amorphization of powder mixture occurs. To obtain duplex and fully lamellar microstructures, the mechanically alloyed powders were cold pressed and then heat treated at 1100 °C and 1400 °C in argon atmosphere for 50 hours, respectively. The results of the oxidation test at 1000 °C revealed that the different microstructures of Ti47Al48Mn5 alloy investigated in this study have little effect on the oxidation resistance, and similar oxidation mechanisms existed for the two microstructures.
B. Binesh, A. Jazayerigharehbagh, A. R. Foroghi,
Volume 35, Issue 3 (12-2016)
Abstract
In this research, the TLP bonding of IN-738LC superalloy was investigated using MBF-20 amorphous foil produced by melt spinning process. The bonding process was carried out at 1035-1080°C for 30-60 min under the vacuum atmosphere. Microstructural investigations showed that the eutectic phases formed in non-isothermal solidified zone (ASZ) are consised of secondary phase borieds rich in nickel, chromium and nickel silicides. Nickel silicide fine precipitates are formed within γ solid solution via solid state precipitation during cooling. The centerline eutectic phases decreased with increase of the bonding time and decrease of amorphous foil thickness. It was found that isothermal solidification was completed when bonding was done at 1055°C for 30 min. However, the isothermal solidification rate decreased with increasing of the bonding temperature up to 1080°C. Unexpectedly, isothermal solidification rate decreased by increasing the tempretarure to 1080°C. The shear strength increased by completing isothermal solidification stage and eliminating brittle secondary phase particles in the centerline of bonding zone.
M. Hosseinzadeh, M. Bozorgmehr, M. Askari,
Volume 36, Issue 1 (6-2017)
Abstract
Cobalt-based amorphous alloys attracted the attention of many researchers to carry out fundamental research for their application in electronics, sensors and magnetic memory due to their special magnetic properties including close to zero Magnetostriction, magnetic permeability and high saturation magnetization. The purpose of this study is the formation and evaluation of microstructure and magnetic properties of cobalt-based amorphous alloy produced by melt spinning and mechanical alloying. The final compositions produced by both methods were studied by scanning electron microscopy, X-ray diffraction and vibrating magnetoresistance. The results showed that compound produced by chill block melt spinning has a better magnetic properties.
Gh. Akbari, M. H. Enayati, H. Minouei,
Volume 37, Issue 1 (6-2018)
Abstract
In the present study, the mechanical alloying process was used to produce the Ni-Nb-Si amorphous alloy. X-ray diffraction (XRD)analysis and high-resolution transmission electron microscopy (HRTEM) were used to approve the amorphous phase formation after 12 hours of mechanical alloying. The results obtained from the SEM morphological images of powder particles during mechanical alloying showed that increasing the milling time caused the reduction of the powder particles size and uniformity in the shape of the particles. Enhancing the embrittlement and fracturing rate caused brittleness and the increase in the failure rate; these were followed by a decrease in the powder particle size to 1-5μm. Cold welding and flattening of the pure elemental powders after mechanical alloying for 2 hours formed a lamellar structure of the alternative layers of different elements lying over each other. SEM image of cross-section of powder particles showed that by increasing the milling time, the interlamellar spacing was decreased, the elements were distributed more uniformly, and finally, a uniform structure of theamorphous phase was completed.
M. Zarchi, Sh. Ahangarani ,
Volume 39, Issue 1 (5-2020)
Abstract
The structural and optical properties of polycrystalline silicon films obtained on a silicon wafer by electron beam physical vapor deposition (EBPVD), were studied in this paper. These films were initially amorphous and changed to a crystalline solid phase during annealing. Annealing was performed in an inert gas atmosphere tube furnace at different temperatures. Micro-structure of the films was analyzed to know the relationship between the crystalline / amorphous composition, grain size and characteristics of the films. The results showed a decrease in roughness with increasing annealing temperature and structural density. Moreover, results of Micro-Raman spectrum showed formation and increase of silicon nanocrystals in the annealed condition when the thickness of the coating increased due to structural defects.
M. Farhadian, K. Raeissi, M. A. Golozar,
Volume 39, Issue 2 (8-2020)
Abstract
This work is focused on the effect of amorphous SiO2 addition on the phase transformation and microstructural evolution of ZrO2 particles. Considering the structural similarities between the amorphous ZrO2 and its tetragonal structure, XRD results showed initial nucleation of metastable tetragonal ZrO2 from its amorphous matrix upon heat treatment. This metastable phase is unstable in pure ZrO2 sample and transforms to a stable monoclinic phase at around 600 oC. However, addition of amorphous SiO2 to ZrO2 structure causes metastable tetragonal phase to remain stable up to around 1100 oC. The temperature range for stability of metastable tetragonal ZrO2 structure increased from about 150 oC in pure ZrO2 particles to around 500 oC in ZrO2-10 mol.% SiO2 composite powders. A further increase in SiO2 content up to 30 mol.% did not change the stabilization temperature range but the average particle size reduced around 1.6 times compared to pure ZrO2 particles. Stabilization of metastable tetragonal ZrO2 explained by constrained effect of SiO2 layer surrounding zirconia nuclei. The thickness of this SiO2 layer enhanced by increasing SiO2 content which limited the growth of ZrO2 nuclei resulting in finer particle sizes.
F. Delshad, M. Maghrebi, M. Baniadam,
Volume 40, Issue 2 (9-2021)
Abstract
Carbon nanotubes contain impurities and deamorphization is one of the methods of their purification. In this study, for the first time, a solution of piranha with a ratio of 3:1 (30 ml sulfuric acid + 10 ml hydrogen peroxide) as well as microwave irradiation with processing time of 30 minutes were used to remove amorphous carbon from the nanotube arrays. Ultrasonication was performed to disperse pristine and purified carbon nanotubes in water and centrifugation was performed to separate large particles. To assess the removal of amorphous carbon, new characterization methods such as dispersed percent and floating percent were used. It was observed that with increase in the ultrasonication time (from 0 to 50 minutes), the dispersed percentage of treated arrays was increased (about 47%), while the floating percentage of pure array decreased (about 20%). These results are ascribed to the removal of amorphous carbon. The results of the thermo gravimetric analysis (TGA) were in good agreement with the results obtained from the newly proposed characterization methods.
E. Mohagheghpour, R. Gholamipour, M. Rajabi, M. Mojtahedzadeh Larijani,
Volume 40, Issue 3 (11-2021)
Abstract
In this study, the amorphous carbon thin films were deposited by ion beam sputtering deposition method on the glass and Ni–Cu alloy substrates. The structural evolution of amorphous carbon and its correlation with the kinetic energy of carbon atoms during the growth of thin film was investigated. The effect of substrate material, deposition temperature, and ion beam energy on the structural changes were examined. Raman spectroscopy indicated a structural transition from amorphous carbon to diamond-like amorphous carbon (DLC) due to an increase in deposition temperature up to 100°C and ion beam energy from 2 keV to 5 keV. The size of graphite crystallites with sp2 bonds (La) were smaller than 1 nm in the amorphous carbon layers deposited on Ni-Cu alloy. The results of residual stress calculation using X-ray diffractometer (XRD) analysis revealed a decreasing trend in the tensile residual stress values of the amorphous carbon thin films with increasing the ion beam energy.
