Journal of Welding Science

This study investigated the effects of pulsed current and constant current on the microstructure and mechanical properties of Hastelloy X superalloy welds produced by Gas Tungsten Arc Welding (GTAW), using ERNiCrMo-2 filler metal. Key microstructural parameters, such as elemental segregation, dendrite refinement, and weld metal uniformity, along with changes in weld strength and hardness, were examined and compared between the two welding modes. Microstructural evaluations were conducted using optical microscopy, Field Emission Scanning Electron Microscopy (FESEM), Energy Dispersive Spectroscopy (EDS), and X-ray Diffraction (XRD) for phase identification. Pulsed current welding resulted in a finer microstructure with more equiaxed dendrites, reduced elemental segregation, and a more uniform distribution of M₆C carbides. Furthermore, this process led to significant improvements in hardness, impact toughness, and tensile strength of the weld metal compared to constant current welding. Fracture analysis confirmed ductile fracture behavior in all specimens, consistent with the microstructural and mechanical findings. The results of this research highlight the importance of using pulsed current in GTAW as an effective method for controlling the microstructure and enhancing the mechanical properties of Hastelloy X alloy joints. 

In this study, the effects of diffusion-bonding temperature and time on the microstructure and corrosion behavior of Al₀.₅CoCrFeMnTi₀.₅ high-entropy alloy coatings applied on A283 plain carbon steel were investigated. The coatings were produced by diffusion bonding using the spark plasma sintering method, in which high-entropy alloy powders were bonded to the substrate at temperatures of 850, 950, and 1050°C for holding times of 10, 15, and 20 minutes. Microstructural characterization performed by field-emission scanning electron microscopy (FESEM) revealed that increasing the diffusion-bonding temperature and time led to reduced porosity and enhanced coating densification. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization tests conducted in a 3.5 wt.% NaCl solution demonstrated that increasing the bonding temperature and time resulted in higher charge transfer resistance (Rct) and corrosion potential (Ecorr values, along with a decrease in corrosion current density (icorr). The coating produced at 1050°C with a holding time of 20 minutes exhibited the highest corrosion resistance. The improvement in corrosion performance was attributed to the formation of a uniform and adherent oxide film, which effectively inhibited the penetration of corrosive ions into the steel substrate.