Journal of Welding Science

In this study, the effects of diffusion-bonding temperature and time on the microstructure and corrosion behavior of Al₀.₅CoCrFeMnTi₀.₅ high-entropy alloy coatings applied on A283 plain carbon steel were investigated. The coatings were produced by diffusion bonding using the spark plasma sintering method, in which high-entropy alloy powders were bonded to the substrate at temperatures of 850, 950, and 1050°C for holding times of 10, 15, and 20 minutes. Microstructural characterization performed by field-emission scanning electron microscopy (FESEM) revealed that increasing the diffusion-bonding temperature and time led to reduced porosity and enhanced coating densification. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization tests conducted in a 3.5 wt.% NaCl solution demonstrated that increasing the bonding temperature and time resulted in higher charge transfer resistance (Rct) and corrosion potential (Ecorr values, along with a decrease in corrosion current density (icorr). The coating produced at 1050°C with a holding time of 20 minutes exhibited the highest corrosion resistance. The improvement in corrosion performance was attributed to the formation of a uniform and adherent oxide film, which effectively inhibited the penetration of corrosive ions into the steel substrate.