Computational Methods in Engineering

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Titanium carbide is used as an attractive reinforcement to produce particulate metal matrix composites. One of the problems to use this carbide as a reinforcement in copper-based composites is the lack of wetability in Cu-TiC system. This property improves as the C/Ti ratio in carbide decreases. Problems to use this carbide as a reinforcement in copper-based composites is the lack of wetabiity in Cu-TiC system. This property improves as the C/Ti ratio in carbide decreases. A practical method is presented in this paper to improve the dispersion of titanium carbide into liquid copper and emphasis is placed on the C/Ti ratio in the carbide. It was observed that the C/Ti ratio in a raw mixture containing only Ti and C was equal to C/Ti ratio in the carbide after synthesis but when copper powder was added to the raw materials, this ratio was higher than the starting value. Regarding the relationship between the titanium carbide lattice parameter and the C/Ti ratio in the carbide and this ratio in the raw mixture, a graph was drawn that related the C/Ti=1, a network of agglomerated TiC particles with the same C/Ti ratio is formed which cannot be dispersed into liquid copper. When this ratio is decreased to 0.3, particulate titanium carbide with C/Ti=0.5 can be easily dispersed into liquid copper. Keywords: SHS reaction, titanium carbide

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In this paper, shear localization due to strain softening in sidepressed cylinders, is inverstigated. Shear localization causes formation of macroscopic shear bands which can be obsserved in the metallographic cross-section. In this paper, for the first time a method is presented in which a simple two-slice model is used to study the formation of shear bands. The results obtained form this model are in perfect agreement with the results obtatained form experimental works for and micrcrostructures in Ti-6242Si alloy. Keywords: shear Localiation, shear Bands, Two –Slice Model, Titanium Alloy Ti-6242Si

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Titanium is a highly reactive metal so that a thin layer of oxide forms on its surface whenever exposed to the air or other environments containing oxygen. This layer increases the corrosion resistance of titanium. The oxide film is electrochemically formed through anodizing. In this study, anodizing of titanium was performed in phosphate-base solutions such as H3Po4, NaH2Po4, and Na2Hpo4 at 9.75Ma/cm2 and 35ºC under galvanostatic conditions. The Potential-Time curves in the above solutions show that the anodic films formed on titanium are compact and their thickness depends on the solution type and concentration. The SEM and XRD techniques show that these layers are amorphous. In this paper, the effect of electrolyte concentration, composition and resistivity on breakdown voltage have been discussed in terms of Ikonopisov electron avalanche breakdown model. This model shows that the major factor contributing to the decrease in breakdown voltage is the increased electrolyte concentration leading to increased primary electronic current.

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Anatase-to-rutile phase transformation was studied in milled and unmilled samples. Ball milling was carried out in two types of ball mills, planetary and tumbler, with a ball-to-powder ratio of 40:1 over 2-48 hours. First, the unmilled samples were heated in the furnace at various temperatures for different periods of time. The results revealed that the anatase-to-rutile transformation completed at 980 after 48 hours. The rate of transformation in milled samples was greatly higher than that of unmilled ones. Activation energy in unmilled samples was about 440 kj/mol. The rate of transformation in the planetary ball mill was higher than that in tumbler mill. In the former, transformation almost finished after 16 hours of milling while in the lattar, it did not finish even after 48 hours. XRD results revealed that the transformation proceeds through an intermediate srilankite phase in all milled samples. However, srilankite was not observed in the unmilled samples.

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