JWSS - Journal of Water and Soil Science

Gypsiferous soils, as the most characteristic soil in arid and semi-arid regions, are widespread in Isfahan Province. The north-west region of Isfahan is a closed basin and is surrounded by geologic formations. This area is a part of Zayandehrood watershed. The origin of gypsum in this area was investigated in this study. Considering the geologic distribution of gypsum, twenty-two locations, suspected to have been affected by gypsum, were selected for sampling. Natural and artificial excavations were used to discover their relationships. To distinguish the differences between fresh and weathered shales, some fresh samples were taken from the depth of Shemshak formations (a lead mine).

Field observations showed that in Shemshak and Nayband formations, gypsic crystals were present within the layers of weathered shales, and pyrite was observed only in the mine shales. In weathered red conglomerates (Lower Cretaceous), considerable amounts of gypsum had accumulated. In the hydrothermal veins of Shemshak and Nayband formations, gypsic crystals were found in matrix or between rock layers. In some parts, the Qom formation (Evaporate sediments) contained plenty of gypsum.

From field observations and analytical data, such as mineralogy of untreated and floated rock powders, determination of residual sulfides in shales, and the examination of thin and polished sections of rocks, we conclude that the origin and main resources of gypsum in our study area are as follows:

1. Gypsum being released from Cretaceous limes particularly from red conglomerates

2. Oxidation of pyrite and any sulfidic minerals existing in shales

3. Gypsum being released from evaporates (Qom formation and Oligomiocenic Marls)

4. Gypsum formed through hydrothermal reactions during late Tertiary.