JWSS - Journal of Water and Soil Science

---

A two-year study (1996-97) was conducted to verify tillage effects on several soil properties and corn yield. The soil (fine loamy, Thermic, typic Haplargids) was treated by conventional (CT) and no-till (NT) systems. Soil organic matter (OM), mean weight diameter (MWD), penetration resistance (Cl), bulk density (BD), total nitrogen (TN) and aggregate size distribution at depths of 0-20 and 20-40 cm were measured.

No-till system caused the OM to be twice as much as that in the conventional tillage system. Total nitrogen in the NT and at depths of 0-20 and 20-40 cm were higher by 30% and 20%, respectively. No differences obtained in bulk density and penetration resistance, but MWD in the NT was 20% and 10% higher than CT in the 0-20 and 20-40 cm depths, respectively. Mean weight diameter of the aggregates in the CT was smaller than that in NT. Aggregates of less than 0.25 mm at 0-20 cm depths were almost 25% higher in CT compared to NT system. The yield in the NT system was significantly lower than CT. Although reduced cultivation could bring a better soil physical condition, low initial organic matter, weak structure and heavy-textured soil produced unsuitable conditions for the crop roots and, consequently, resulted in low yield. Therefore, no-till system in this region would not be recommended.

---

Soil structure maintenance and stability is an important index indicating sustainable soil management. In this regard, components such as soil moisture and organic matter affect soil compactibility during farm machinery trafficking. Soils in Central Iran are commonly very low in organic matter (OM) and thus susceptible to compaction. This study was conducted to measure the effects of soil moisture content and manure application on soil compactibility. A randomized complete block design with four blocks (replicates) with the treatments nested (split-block) into the blocks was used in the soil (Typic Haplargids), located in Isfahan University of Technology Research Farm (Lavark). One-year aged manure treatments 0, 50, and 100 t ha^-1 were incorporated into soil up to the tillage depth (20 cm) by a heavy disc. After five months (July-November), a two-wheel-drive tractor Universal Model U-650 was passed through the field at soil moisture contents of plastic limit (PL), 80% PL (0.8PL), and 60% PL (0.6L), either once (P1) or twice (P2). Bulk density (BD), cone index (CI), and soil sinkage (S) were measured as indices of soil compactibility and trafficability. Adding manure countered the effects of load and wetness on BD and CI, significantly. There was a significant difference between the effects of 50 and 100 t ha^-1 of manure on BD but not on CI. Manure application reduced soil sinkage at high moisture contents (PL) but increased it at low moisture contents (0.6PL). Adding manure also reduced the BD and CI of subsoil. Repeating the passage of tractor (P2) increased compaction significantly. The significant increase in BD and CI did no occur at 0.6PL. When no manure was applied even at 0.6PL, there were limitations for trafficability, whereas this limit for 50 t ha^-1 treatment was reached at 0.8PL. Results from this study indicate that the manure application at a rate of 50 t ha^-1 reduces soil compactibility and increases soil moisture trafficability range.

---

Due to physiography and weak structure, the pasture soils in Boroojen are potentially degradable. Converting pastures to agricultural land accelerates the degradation processes. A study was conducted in 1999 to show the effects of almost 20 years of farming on originally pasture land on soil physical properties, fertility, and tilth index of pastures in Boroojen region in Chahar Mahal and Bakhtiari Province (central Zagrous). Soil texture, clay content, bulk density, organic matter, saturation moisture percent, cone index, plasticity index, mean weight diameter and aggregate size and distribution, nitrogen, phosphorus, and potassium were measured.

After 20 years of cultivation, bulk density increased about 20% while organic matter decreased by 30%. Cone index was lower in the undisturbed pasture but nitrogen and phosphorus contents were higher compared to the disturbed pasture. The undisturbed pasture contained more larger (> 1 mm) aggregates, while the disturbed pasture had more smaller aggregates. Sustainable use of natural resources will lead to their long term workability, while negligence of conservational practices including appropriate farming management practices will result in the destruction of these resources.

---

Soil tilth is crucial to seedling emergence, plant growth, and crop yield. Soil tilth of unstable soil is very susceptible to change. Internal forces originating from matric suction can change soil physical properties. A laboratory study was conducted on pots of a surface silty clay loam soil of Khomeinishahr series (fine-loamy, mixed, thermic Typic Haplargids, USDA), located in Research Farm of Isfahan University of Technology. Soil surface subsidence, bulk density, cone index, and tensile strength were measured after first flood irrigation. Results showed that the seedbed (0-20 cm) with a bulk density of 1.2 Mg.m^-3 will be changed to a massive soil with high values of bulk density, cone index, and tensile strength after soil wetting. Slaking, slumping and coalescence of the soil caused soil surface to subside about 1.5 cm in 20 cm soil layer. After irrigation, cone index and tensile strength increased abruptly with decreasing of moisture content. It is shown that the dominant source of strength (cone index and tensile strength) gain during drying is the effective stress due to matric suction. In the absence of external loads, physical state (tilth) of the soil returned back to the original state. Therefore, soil slaking and slumping and rearrangement of particles along with the internal forces are the factors leading to soil hardness.

---

Potato (Solanum tuberosum L.) has relatively weak root system and requires high nitrogen fertilizer which is costly and may pose environmental pollution. This study was conducted to compare root morphological characteristics and nitrogen uptake of some potato cultivars growing in Iran. A greenhouse experiment using a completely randomized design with 3 replications and 8 potato cultivars including: Arinda, Agria, Premiere, Diamant, Concord, Marfona, Marodana and Nevita was conducted at Isfahan University of Technology, Isfahan. Virus-free seed tubers were planted and grown up to flowering stage. The plants were then harvested and their root length (RL), root average diameter (RAD) and root surface area (RSA) were determined using a Delta-T Scan image analysis system and Windias software. Root length density (RLD), root length and shoot weight ratio (R/S) were also calculated. Dry mater production and nitrogen accumulation (total nitrogen uptake) (PNA) were also determined. Soil inorganic nitrogen was measured before planting and after harvest. All measured parameters, except RAD, were significantly (p<0.05) affected by cultivar. Large differences observed between cultivars for all traits indicated genetic diversity among the studied potato cultivars. The highest and the lowest values of RL, RLD, RSA, R/S, RDW and PNA were found in Marfona and Nevita respectively. Based on cluster analysis, cultivars were divided into four different groups. Under the condition of this study, Marfona was superior whereas Arinda, Nevita, Marodana and Agria were inferior. Due to the high differences in root morphological characteristics and nitrogen uptake among potato cultivars, plant breeders may produce cultivars with larger root volumes and high nitrogen uptake.

---

The objective of this study was to evaluate effects of cow manure on soil hydraulic properties and bromide leaching in a sandy loam soil (coarse loamy mixed, Typic Torrifluvents). Manure was applied at 0, 30, and 60 tha^-1 at three replications in a completely random design. Three months after manure application potassium bromide (KBr) at rate of 300 Kg ha^-1 Br was uniformly applied on the surface. Soil bulk density, porosity, organic matter, and soil moisture at18 levels of matric potentials were determined. Soil samples to the depth of 105 cm at 15-cm increments were collected after 100, 200 and 400 mm of irrigation. Soil bulk density, porosity, organic matter content, and soil moisture at different levels of matric potential increased significantly with manure application. Manure application also significantly affected the hydraulic parameters. Bromide leaching was significantly lower in plots with manure application and the greatest leaching occurred at the zero manure application treatment. The center of mass evaluation indicated a relatively similar result with measured values.

---

  Adopting proper agricultural management and conserving soil organic matter are important components of sustainable agriculture. Soil organic matter content is a key attribute in soil quality. Labile organic matter pools can be considered as suitable indicators of soil quality that are very sensitive to changes in soil management practices. This research was carried out to investigate some organic carbon labile pools as an indicator evaluating the effects of different managements on some quality parameters of two calcareous soils. The study was conducted in 2 locations: 1- plots that receiving 0 (C1), 25 (C2), 50 (C3) and 100 (C4) Mg/ha of manure for five years successively with a cropping rotation of wheat –corn every year and plots under three cropping rotations (C5, C6 and C7) at Lavark experimental farm and 2- inquiry research station of Fozveh at different plots with three different cropping rotations (C8, C9 and C10) with a given cropping history recorded for the last 5 years. Soil samples were taken from the center of each plot and the depths of 0-5 cm and 5-15 cm. Their organic carbon, hot water soluble carbohydrate, particulate organic matter (POM), organic carbon and hot water soluble carbohydrate of POM, mean weight diameter of water stable aggregates were determined. Different managements consisting of different levels of manure and types of cropping rotation had significant effects on the soil characteristics measured. The greateast amount of carbohydrate and aggregate stability was obtained in the plots of 100 Mg/ha of manure in Lavak and in alfalfa plots in Fozveh station. Also, the results showed that aggregate stability has a better correlation with hot water soluble carbohydrate in comparison with other soil organic pools. Therefore, the carbohydrate extracted by hot water may be used as an index to assess the impacts of different agricultural management systems on soil quality.

---

  Tillage is one of the important managing factors that can destroy or improve soil structure. Soil structure is affected by the machines and shape of the wheels. Field experiments were conducted at Hamadan Agricultural Research Station on a coarse loamy mixed mesic Calcixerolic Xerocrepts soil to measure and evaluate the effects of tillage and wheel-induced compaction on selected soil physical properties. Treatments included tillage methods (Moldboard Plow and Chisel Plow, (MP, CP)) performed using three customary tractors in Iran [John Deer (J), Romany (R) and Massey Ferguson ( MF) ]. Traffic zone and non traffic zone were other treatments. A split-plot design with three replications was used in a completely randomized arrangement of treatments. Soil samples were taken at the end of wheat growth season in traffic and non- traffic zone and from four layers and compared for bulk density (BD), cone index (CI), and mean weight diameter (MWD). The influence of both tillage methods on BD in most soil depths was not significant, meanwhile, BD was higher in the deeper layers. Wheel traffic did not affect BD significantly, but its effect decreased by increasing the depth. Commonly, conservation tillage increased structural stability as evaluated by MWD. Cone index illustrated the same trend as for BD, with some variation because of it higher sensitivity, so it was significantly was increased in CP rather than in MP for the traffic zone. Such a difference was not observed in non-traffic zone. The CI was also significantly increased in traffic zone compared with non-traffic zone. J significantly increased CI in two first layer in comparing with MF, but there was not significant difference between J and R. The MWD was increased by chisel plow in non-traffic zone and this increment was significant in fourth soil layer (22.5- 30 cm). Wheel traffic caused the increase of MWD in the second layer and significant difference was not observed in other layers. Overall, R caused less destruction in soil structure and tillage methods changed some of soil physical properties.

---

  Applying of intensive cultivation especially in marginal and sensitive regions, after conversion of rangelands to cropland farms, commonly causes reduction in soil quality, and thus an increase in soil degradation, erosion and runoff. This study was conducted to evaluate the land use change effects on some soil physical and chemical properties such as mean weight diameter (MWD), soil organic matter (SOM), bulk density (BD) and saturated electrical conductivity (ECe). For the experiment, soil samples were collected from 8 regions (rangeland and cultivated range) from west and southwest of Isfahan. Samples were taken from two soil layers 0-15 and 15-30 cm. Results showed that after conversion of range to cultivated lands, in some regions, SOM content was increased about 39% but in some regions decreased about 26%. This is due to the initial conditions of the regions. The ECe also increased by 41% due to this conversion. However, no changes were observed to the MWD, BD and pH in different treatments. Although there were little change to the physical and chemical properties of soil as a result of this conversion, those properties which were changed, could have a degradation effect and lower the soil quality.

---

Total petroleum hydrocarbon (TPH) contaminations in soils may be toxic to human, plants and cause groundwater contamination. To achieve maximum TpH- reduction and to establish successfull stable vegetation cover in phytoremediation method, various criteria must be considered to choose the plants carefully. In this study, germination and subsequent growth of seven plants were tested in three soils with different petroleum contamination levels. Contamination treatments consisted of C₀ (uncontaminated soil), C₁ (1:1 w/w, uncontaminated: contaminated soil) and C₂ (1:3 w/w, uncontaminated: contaminated soil). The experimental design was completely randomized split plots with three replications per treatment. The results showed that the presence of TPH in the soil had no effect on seed germination of agropyron, white clover, sunflower and safflower although canola seedlings were sensitive to these compounds and failed to produce dry matter yield (DMY) at the end of trial period. In contrast, seed germination of canola, puccenillia and tall fescue decreased in the petroleum contaminated soils. No reduction was found in DMY of puccenillia in contaminated soils (C₁ and C₂ treatments) compared to control however, the presence of TPH proportional to the contamination levels, decreased dry weight of sunflower and safflower. This reduction in growth and dry weight for tall fescue and agropyron was also observed in C₂ compared to C₁ treatment. Therefore, it seems that though agropyron, white clover, sunflower and safflower germinated well and the presence of TPHs in the soil treatments had no effect on their seed germination, they grew poorly. In contrast, grasses had poor seed germination but their subsequent growth and establishment in the contaminated soils was acceptable for subsequent phytoremediation trials.

---

Determination of carbohydrates in soil requires prior extraction and numerous extraction methods were suggested for this purpose. Three methods and five extractants were applied in order to extract carbohydrate fraction in three soil types forest, clayey and saline soils. The extraction methods were: 1) shaken in a plane rotary shaking machine for 16 h 2) heated in steam-bath for 2.5 h and 3) heated in oven for 24 h and extractants included 1) 0.5 M HCL, (2) 0.25 M H2SO4, 3) 0.5 M H2SO4, 4) 0.5 M K2SO4 and 5) distilled water. Carbohydrate content in soil was measured by phenol-sulphuric acid method. The addition of phenol to the extracted solution of HCl caused to milky precipitation. Therefore, this extractant can not be used for carbohydrate extraction in the phenol-sulphuric acid spectroscopic method. The results showed that in all soils and in the shaker extraction method, carbohydrate content was lower than in the oven and steam-bath extraction methods. In the forest and saline soils, the extracted carbohydrate content was not significantly different among the oven and steam-bath methods. For the clayey soil, the carbohydrate content was higher in the oven method than that of the steam-bath method. In all soils, the extracted carbohydrate by 0.5 M H2SO4 extractant was greater than those of other extractants. In the forest and saline soils, the extracted carbohydrate by distilled water was lower than those of other extractants. Using steam-bath method (for the forest and saline soils) and oven method (for the clayey soil) with 0.5 M H2SO4 extracted the highest amount of carbohydrates.

---

Tillage systems and organic manures could affect soil physical and mechanical properties. This study was conducted to investigate the impacts of two tillage systems including conventional tillage by moldboard plowing (plowing depth, 30 cm) and reduced tillage by disk plow (plowing depth, 15 cm) and three rates (0, 30 and 60 ton ha-1) of farmyard manure (FYM) on the soil penetration resistance under corn cropping in a split block design with 3 replications. The cone index (CI) decreased with increase of the tillage depth. It is attributable to soil disturbing and loosening of the deeper layers under conventional tillage compared to reduced tillage. This trend, however, was observed only in the first (after treatments’ application and before cropping) and second (the highest rate of vegetative growth) samplings. In the third sampling (after harvest), there were not significant differences between the CI values under two tillage systems in different soil depths. It might be due to soil re-compaction (approaching the pre-tillage state) as well as disappearance of the tillage effects seven month after commencement of the experiment. In fact, the soil mechanical resistance increased with the time indicating soil re-compaction over the growing season. Adding FYM to the surface layer (i.e. 0-10 cm) of ridge soil resulted in significant decrease of soil mechanical resistance compared to control treatment. The CI decreased significantly in the 30 ton ha-1 treatment up to the stage of highest rate of vegetative grow, but the effect on CI was diminished after harvest. However, the decreasing effects of the 60 ton ha-1 treatment on the CI continued to the harvesting time. There were no significant effects of FYM in the soil deeper than 10 cm from the ridge surface and in all of the layers in furrow. The CI did not decrease significantly in the furrow due to negligible effect of manure application for the inter-row position.

---

Presence of petroleum contaminants in soil may be toxic to human and organisms and act as a source of ground water contamination hence, remediation of these compounds from environment is vital. In this study, first the feasibility of remediation of two petroleum-contaminated soil samples around Tehran Oil Refinery (oil refinery landfill and agricultural soils) was assessed using landfarming technique during a four month experimental period. The elimination of total petroleum hydrocarbons (TPHs) from soils treated through landfarming technique was then investigated in the rhizosphere of agropyron and fescue. The results showed that microbial respiration increased due to landfarming processes in both soils. Urease activity in the landfarming treatment for agricultural soil was 21, 45, 26, and 23% higher than the control at the end of first to the 4th months of experiment, respectively. However, no significant differences were observed between the landfarming and control treatments for landfill soil at the end of experiment. Furthermore, about 50 and 57% reduction in TPH-concentration was observed in the landfarming treatment for landfill and agricultural soils at the end of experiment, respectively. In the phytoremediation study, presence of TPHs in both landfarming and control treatments reduced dry matter yield of the studied plants. Urease activity in the rhizosphere of fescue and agropyron was higher than in the unplanted soil. Degradation of petroleum-compounds in the landfill soil under landfarming treatment was more than 20 and 40% in the presence of fescue and agropyron, respectively. The influence of agropyron on TPH-removal from agricultural soil under the landfarming treatment was also higher than fescue.

---

The salt–affected lands in arid regions of central Iran are characterized by low rainfall, low fertility, high evaporation and salinity. The cultivation of salt–affected lands may have a major influence on soil quality. The aim of this study was to determine the response of soil quality indicators to reclamation and cultivation of salt–affected lands occurring in Abarkooh plain, central Iran. Soil quality indicators were evaluated in three land use systems including salt-affected land, wheat, and alfalfa fields. Composite soil samples were collected at 0–10, 10–20, 20–30, and 30–40 cm layers and analyzed for soil organic carbon, total nitrogen, carbohydrate, particulate organic carbon in macro-aggregates (POCmac) and micro-aggregates (POCmic), organic carbon mineralization and wet aggregate stability. The cultivation of salt–affected land caused a significant decrease in electrical conductivity at all layers and increased the amount of soil organic carbon, total nitrogen, carbohydrate, POCmac, POCmic, and organic carbon mineralization. At all layers, the POCmac/POCmic ratio in the alfalfa fields was higher than that in the wheat fields. The cultivation of salt-affected land caused a significant increase in soil aggregate stability (MWD) at all layers. In most cases, the amounts of soil organic matter and MWD were greater in alfalfa than in the wheat fields, reflecting a better soil quality and thus higher potential for increasing soil organic carbon sequestration in the alfalfa fields

---

The petroleum refinery sludge is an important source of environmental pollution. Burning and burying of the sludge may have adverse effects on environment and human health. Thus, other mechanisms for decreasing the toxic effects of hydrocarbon substances in the sludge must be used. In this study, Isfahan refinery sludge was dewatered, air dried and mixed by 0, 10, 20, 30 and 40% w/w ratio with two calcareous soils, viz., Mahmoud Abad (Typic Haplocalcids with clay texture) and Bagh Parandegan (Anthropic Torrifluvents with silty loam texture). Different mixtures of soil and sludge were farmed for 21 days and irrigated on a daily basis to field capacity. Then, 100 seeds of Tallfescue (Festuca arundinacea) and Agropyron were planted in polluted soils with 3 replicates in 3 kg pots for 5 months. Result showed that Tallfescue and Agropyron yields decreased in sludge contaminated treatments. In the 40% sludge treatment, Tallfescue decreased the total petroleum hydrocarbons content by 65 percent. The highest degradation for agropyron was in the 30% sludge treatment which showed about 55% reduction in total petroleum hydrocarbons. The 40% sludge treatment resulted in the minimum yields of root and shoot plants. The highest degradation of TPHs occurred in the Tallfescue rhizospher of 40% sludge. Maximum degradation of TPHs on the Agropyron rhizospher was in 30% sludge mixed with Bage parandegan soil, but maximum yield of plant was in 20% sludge. Our study shows that Tallfescue rhizospher is most effective for decreasing TPHs, and that the phytoremediation in soils with more clay can adsorb and fix the toxic components and then at higher levels of pollutions can let the plants grow.

---

Waste tire rubbers are considered one of the environment pollutants. Increased production of these pollutants has led to more serious consideration of ways to reduce the harms caused by their accumulation in the environment. Therefore, the effects of incorporation of waste rubber crushed particles in two sizes of 1-2 and 3-5 mm and the amounts of 0, 5, 10 and 20 Mg ha-1 in a calcareous soil (0-30 cm depth) on some chemical properties of soil was investigated in Isfahan University of Technology research field (Lavark). This experiment was performed using seven treatments along with a non amended control treatment in a randomized complete block design with three replications in 1387. Eight months after incorporation, soil samples were collected for laboratory analyses. Results of ANOVA tables show that soil pH, electrical conductivity, percentage of total nitrogen and DTPA-extractable concentrations of cadmium, lead, copper and iron were not significantly affected by application of rubber particles. Incorporation of rubber particles into the soil significantly increased soil organic carbon and carbon to nitrogen. Increases in the DTPA-extractable Zn in soils treated with 10 and 20 Mg ha rubber particles in fine and coarse sizes were significant in comparison with the control soil. DTPA-extractable Zn content in the soil treated with 10 and 20 Mg ha 3-5 mm waste tire rubbers particles was about two and three times higher than that in the control treatment, respectively. The results of this study showed that in short-time, incorporation of crushed tire rubbers particles had no significant effect on most chemical properties of the soil but increased the available Zn content. In this regard, further studies to monitor the effects of adding waste rubber crushed particles on organic matter mineralization, plant toxicity and physical properties of soil in long-term are recommended.

---

The task of modern agriculture is to safeguard the production of high quality food, in a sustainable natural environment under the precondition of pollution not exceeding accepted norms. The sustainability of current land use in agro-ecosystems can be assessed with respect to heavy metal accumulation in soils by balancing the input/ output fluxes. The objectives of this study were to model accumulation rate and the associated uncertainty of Zn in the agro-ecosystems of 3 arid and semi-arid provinces (Fars, Isfahan and Qom). Zinc accumulation rates in the agro-ecosystems were computed using a stochastic mass flux assessment (MFA) model with using Latin Hypercube sampling in combination with Monte-Carlo simulation procedures. Agricultural information including crop types, crop area and yield, kind and number of livestock, application rates of mineral fertilizers, compost and sewage sludge and also metal concentration in plants and soil amendments were used to quantify Zn fluxes and Zn accumulation rates. The results indicated that Zn accumulates considerably in agricultural lands of the studied townships especially in Najafabad (3009 g ha-1yr-1). The major Zn input routes to the agricultural soils (and due to agricultural activities) were manure and mineral fertilizers and the major part of the uncertainty in the Zn accumulation rate resulted from manure source.

---

Zinc (Zn) is an essential trace element for plants as well as for animals and humans. There is a significant relationship between soils, plants and humans Zn status in a certain agro-ecosystem. The objectives of this study were to assess Zn status of soils in 3 arid and semiarid provinces of Iran and to model the relationship between wheat grain Zn and agro-ecosystem parameters. About 137 soil and wheat samples were collected randomly from the agricultural soils of Fars, Isfahan and Qom and were analysed in laboratory. Modeling the relationship between wheat grain Zn and agro-ecosystem parameters was done using least square based and robust methods. The results indicated that total Zn concentration of soils (range, 21-149 mg kg-1 mean, 75.2 mg kg-1) was in normal ranges. The DTPA-extractable Zn concentrations were below the critical level (0.8 mg kg-1) in 16% of the surveyed fields. The Zn concentration in 80% of wheat grains was sufficient (more than 24 mg kg-1) with respect to plant nutrition (range, 11.7-64 mg kg-1 mean, 31.6 mg kg-1). However, Zn bioavailability for consumers was generally low in more than 75% of the samples. This is because of high phytic acid to Zn molar ratio (more than 15). Soil DTPA-extractable Zn and available P were entered in to most of regression models significantly. Regression analysis showed that most of models fitted to wheat grain Zn concentration and soil Zn and influenced by agro-ecosystem parameters had a weak prediction power, despite their high determination coefficient. This means that factors other than those considered here have a strong influence on the uptake of Zn by wheat in these soils.

---

The conventional application of nitrogen fertilizers via irrigation is likely to be responsible for the increased nitrate concentration in groundwater of areas dominated by irrigated agriculture. This requires appropriate water and nutrient management to minimize groundwater pollution and to maximize nutrient use efficiency and production. To fulfill these requirements, drip fertigation is an important alternative. Design and operation of drip fertigation system requires understanding of nutrient leaching behavior in cases of shallow rooted crops such as potatoes, which cannot extract nutrient from lower soil depth. This study deals with neuro-fuzzy modeling of nitrate leaching from a potato field under a drip fertigation system. In the first part of the study, a two-dimensional solute transport model (HYDRUS-2D) was used to simulate nitrate leaching from a sandy soil with varying emitter discharge rates and various amounts of fertilizer. The results from the modeling were used to train and validate an adaptive network-based fuzzy inference system (ANFIS) in order to estimate nitrate leaching. Radii of clusters in ANFIS were tuned and optimized by genetic algorithm. Relative mean absolute error percentage (RMAEP) and correlation coefficient (R) between measured and obtained data from HYDRUS were 0.64 and 0.99, respectively. Results showed that ANFIS can accurately predict nitrate leaching in soil. The proposed methodology can be used to reduce the effect of uncertainties in relation to field data.

---

In this work, the effect of raw and modified bentonite and zeolite with trivalent iron on the stabilization of water-soluble and adsorbed arsenic in a calcareous soil was studied. Raw and modified bentonite and zeolite were added to the soil in different weights in a completely randomized block design with three replications and kept to field capacity soil moisture content of 80% for 8 weeks. The concentrations of water-soluble and adsorbed arsenic, water-soluble and absorbed phosphorus in soil and soil pH were measured. Treatments significantly affected the mobility of arsenic and phosphorus in soil. Raw zeolite and bentonite in different levels increased arsenic mobility (about 107 to 325 % and 259 to 350% respectively). Despite the change in surface properties of zeolites modified with iron, this treatment at different levels increased arsenic mobility in soils by about 124 to 246%. Bentonite modified with iron had the greatest effect on reducing arsenic mobility in soil (about 91%). Phosphate mobility was similar to arsenic in different treatments.