Showing 43 results for KHademi
M. H. Salehi, H. Khademi, M. Karimian Eghbal,
Volume 7, Issue 1 (spring 2003)
Abstract
Clay minerals have considerable effects on physico-chemical properties of soils. Using different techniques, mineralogy of silicate clays and their formation were investigated in selected soils from Chaharmahal and Bakhtiari Province. The study area is about 1300 ha and its soil moisture and temperature regimes are xeric and mesic, respectively. Geomorphologically, the area consists of different landforms including pediments, outwash, hills and piedmont plain. After field and laboratory studies, five representative pedons were selected in previously determined mapping units and samples were taken for the analyses required. Clay particles from two surrounding rock formations and selected soil samples were separated and examined by electron microscopy (SEM and TEM), X-ray diffraction and infrared techniques.
Illite, smectite, chlorite, palygorskite and kaolinite were present in all the soils. Considering the fact that palygorskite was not observed in nearby rock formations, this mineral is probably formed by pedogenic processes. Smectite, on the other hand, has been inherited from parent materials and also transformed from palygorskite. Other minerals had been probably inherited from parent materials. Infrared spectra confirm the X-ray diffraction and submicroscopic results.
M. Sheklabadi, H. Khademi, A. H. Charkhabi,
Volume 7, Issue 2 (summer 2003)
Abstract
Soil erodibility in arid regions, particularly in less developed soils, greatly depends on parent material. The objectives of this study included comparison of the potential of runoff and sediment production in soils with different parent materials and identification of the highly sensitive parent materials in Golabad watershed, 60 km northeast of Isfahan, with about 160 mm of annual precipitation and various geological formations, as one of the highly erodible watersheds in Iran. Soils formed on twelve different parent materials were selected. Rainfall simulator was run for 80 minutes on three replicates of each soil. To have an idea about the rate of runoff and sediment generation with time, runoff loaded with sediment was collected every 10 minutes using plastic containers. After measuring the volume of each runoff sample, it was dried and the amount of sediment was measured. The mechanical parameters of the applied rain were: intensity about 40 mm/hr, rain drop average diameter: 6.56 mm plot size: 1 m2 and kinetic energy of 13.7-17.2 J/m2.mm. Based on the rainfall simulation experiments, soils formed on green andesite and slightly dissected alluvium derived from both sedimentary and igneous rocks created the highest amount of runoff. They also created runoff much more rapidly as compared to other soils. In contrast, soils developed on granodiorite and moderately undulating alluvium produced the least volume of runoff. Furthermore, maximum quantity of sediment was produced from the soils occurring on green andesite and shale. The least sediment yield was observed in soils developed on granodirite and moderately undulating alluvium. Soils formed on shale created the highest sediment concentration and no significant differences were observed among other soils. Based on the results obtained, soils were ranked according to sensitivity to erosion. It is concluded that soil parent materials have a high influence on the production of runoff and sediment yield in Golabad watershed.
M. H. Farpour, M. K. Eghbal, H. Khademi,
Volume 7, Issue 3 (fall 2003)
Abstract
Gypsiferous Aridisols are of great importance and extent in arid and semi-arid environments. There is a close relationship between soil genesis and landscape positions. This study aimed to determine the genesis and classification of gypsiferous soils and to investigate the relationship between micro-and macro-morphology of gypsum crystals and geomorphic positions in Rafsanjan area. The study area is located in Nough, 30 km north of Rafsanjan with a mean annual precipitation of 60 mm. Seven representative pedons were selected on different geomorphic positions. Physico-chemical, micromorphological, XRD, and SEM observations were performed on soil samples. Rock pediment geomorphic surfaces, that are in fact peripheries of old closed water bodies in central Iran, are the source of gypsum in the area. Large gypsum pendants and microforms of lenticular, vermiform, platy, and interlocked gypsum plates are found in rock pediment. The amount of gypsum and the size of pendants decrease moving down the slope. Lenticular and interlocked gypsum plates are found in a transition of pediment and playa. Puffy ground is observed on the saline surface of playa. Lenticular and vermiform gypsum crystals increase down the slope, but alabastrine gypsum is the most dominant form of gypsum in the playa surface. Large amounts of soft gypsum nodules are found on the rock pediment surface (western slope). In addition, spindle form of gypsum and palycrete bundles are observed in this position. Wind action played a significant role in the genesis and development of soil in rock pediment. A close relationship was found between morphology of gypsum crystals and geomorphic positions.
H. R. Karimzadeh, A. Jalalian, H. Khademi,
Volume 8, Issue 1 (spring 2004)
Abstract
Clay minerals deserve special attention as they play a crucial role in many soils. The clay mineralogy of five gypsiferous soils from different landforms in eastern Isfahan was investigated using X-ray diffraction (XRD). In addition, soil aggregates and wind-deposited sediments were examined by scanning electron microscope (SEM) and analyzed by energy dispersive X-ray analyzer (EDX).
The results indicate the presence of palygorskite, mica, kaolinite, chlorite, and quartz with a trace amount of vermiculite and randomly interstratified layers in all soils. Smectite occurs in soils of both the piedmont plain and old river terrace, but not in the alluvial fan soils. Mica, chlorite, quartz, and kaolinite were probably inherited from the parent material. Palygorskite seems to increase with depth in the alluvial fan, whereas, in the old terrace soils, this clay mineral decreases with depth. Palygorskite present in alluvial fan soil appears to have been formed authigenically when the basin was covered with shallow hyper-saline lagoons toward the end of the Tertiary. Palygorskite in the old terrace seems to be mostly detrital and an eolian origin of palygorskite is likely because a large amount of palygorskite is present in upper soil horizons. A higher proportion of smectite in deep soils of the old terrace, as compared with palygorskite, suggests the possibility of authigenic formation of smectite from palygorskite.
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H. Khademi, H. Khayyer,
Volume 8, Issue 2 (summer 2004)
Abstract
Understanding the variability of pedological properties as well as the soil quality attributes on different landscape positions in hummocky terrains would result in a better land management in such areas. Despite the importance of such studies, no research has been couducted on the landscape-scale variability of soil quality indices in Iran and most researchers have so far focussed on pedological aspects of soil variability. The objective of this study was to understand the variability of selected soil quality indices at different landscape positions. A systematic grid including 120 points (12x10) with a distance of 30m was laid out in a hummocky rangeland around the city of Semirom. Surface soil samples were taken from 120 points on grid nodes and their organic carbon, microbial respiration rate, phosphatase activity, pH and EC were measured. Also, the thickness of A horizon and the soil moisture content were measured on grid nodes in the field.
The results indicated that the lower slope positions including footslope and toeslope had the highest amount of phosphatase activity, microbial respiration, A horizon thickness, organic carbon, and EC. In contrast, soils occuring on shoulder had the least amount of the above-mentioned properties. Soils on summit and backslope seem to have been moderately degraded. Soil pH showed the opposite trend, as compared to other properties studied. The presence of a great variability in soil quality attributes at the landscape scale can be attributed to differenes in effective moisture that various landscape positions receive, as well as the differenes in soil erosion and deposition rates. This can also be an indication of a severe land degradion due to poor management practices. Since applying different management practices on different landscape positions are practically impossible, to be on the safe side, it is highly recommended to plan conservation practices based on soil quality of the most degraded landscape positions.
J. Mohammadi, H. Khademi, M. Nael,
Volume 9, Issue 3 (fall 2005)
Abstract
In order to achieve a sustainable management of land resources and to improve land quality, quantitative assessment of effective factors and soil quality indicators are required. The aim of this study was to evaluate variability of selected soil quality attributes in central Zagros affected by such factors as region, land use and management practices. Twelve sites were selected in three provinces including Chahar Mahal va Backtiari (Sabzku, Broujen), Isfahan (Semirum), and Kohkeloyeh va Boyerahmad (Yasodje). Different management practices were considered such as: protected pasture, intensive grazing, controlled grazing, dryland farming, irrigated wheat cultivation, legume-farming practice, protected forest, and degraded forest. Systematic sampling with taking 50 samples of surface soil in each site was carried out. The results of univariate and multivariate analysis revealed that all factors significantly influenced the spatial variability of selected soil quality attributes namely phosphatase activity, microbial respiration, soil organic matter, and total nitrogen. The results obtained from discriminant analysis indicated that all selected soil quality parameters could significantly be used as soil quality indicators in order to recognize and discriminate sustainable agricultural and forestry ecosystems and/or optimal management practices.
M. Amini, M. Afyuni, H. Khademi,
Volume 10, Issue 4 (winter 2007)
Abstract
Heavy metals including cadmium (Cd) and lead (Pb) are entering agricultural soils from different routes and mainly due to human activities. Accumulated Cd and Pb in the soil would eventually enter the human and animal food chains and pose threat to their health. Therefore, evaluating heavy metal accumulation is necessary to prevent soil and environmental pollutions and should be considered by researchers as well as policy makers. This study was conducted to model the accumulation rates of Cd and Pb in the agro-ecosystems of Isfahan, Mobarakeh, Lenjan, Borkhar, Najafabad, Khomeinishahr and Felavarjan. Cadmium and lead accumulation rates in the agro-ecosystems were computed using a stochastic mass balance model which uses Latin Hypercube sampling in combination with Monte-Carlo simulation procedure. Agricultural information including crop types, crop area and yield, the type and the number of livestock, application rate of mineral fertilizers, compost and sewage sludge and also metal concentration in plant and amendments were used to quantify Cd and Pb accumulation rates. Modeling Cd and Pb accumulation rates indicated that the metals are accumulating in the agricultural lands in the studied townships. The largest Cd (18 g ha-1 yr-1) and Pb (260 g ha-1 yr-1) accumulation rates were found in the township of Isfahan but the minimum accumulation rates were found in township of Lenjan for Cd (3 g ha-1 yr-1) and Mobarakeh for Pb (10 g ha-1 yr-1). The major input route to agricultural soils is phosphate fertilizers for Cd but for Pb is manure on the regional scale. High application rates of sewage sludge and compost in agricultural lands in the township of Isfahan could result in considerable amounts of Cd and Pb entering the soils of this region.
M. Yousefifard, A. Jalalian, H. Khademi,
Volume 11, Issue 40 (summer 2007)
Abstract
Improper use of natural resources, especially soil, causes its degradation and severe soil erosion. Water erosion is an important factor causing soil degradation. Land use change of pasture would result in severe soil erosion mainly due to the reduction of vegetation cover and also surface soil disturbance. The objectives of this study were to estimate the amount of sediment, runoff and nutrient loss in four different land uses including a pasture with good vegetation cover (> 20%), a pasture with poor vegetation cover (< 10%), a currently being used dryland farm and a degraded dryland farm which is not used. Soil samples were taken from the depth of 0–10 cm in a completely randomized design with four replications. A rainfall simulator was run for two hours to estimate the amount of sediment, runoff and nutrient loss. Organic matter, total N, available P and distribution of particles size in soil and sediment were measured. The results showed that a very high degradation has occurred in the area mostly due to water erosion created as a result of overgrazing in pasture, susceptibility of geological formations and more importantly, the change of land use pasture to inefficient dryland farming. Maximum and minimum runoff was observed in the abandoned dry landfarm and pasture with good vegetation cover, respectively. Maximum sediment content was observed in dryland farm. Sediment content in dryland farm, abandoned dry landfarm and pasture with poor vegetation cover were 54.5, 21 and 10.4 times more than that in the pasture with good vegetation cover, respectively. Enrichment ratio (ER) of soil particles in sediment was highest for fine silt (2-5µm), followed by clay. A minimum of ER was obtained for sand fraction. Percentages of organic matter, total N and available P in sediment were higher in the first hour as compared to the second one. This is mainly due to the fact that fine particles are removed at the beginnings of the rainfall event. Total removal of these chemical factors was highest in dryland, intermediate in pasture with poor vegetation cover and abandoned dryland and lowest in pasture with good vegetation cover. In general, cultivation and disturbance of the pasture in the area land have caused a great decrease in soil quality and made the surface very sensitive to erosion.
M. Sheklabadi, H. Khademi, M. Karimian Eghbal, F. Nourbaksh,
Volume 11, Issue 41 (fall 2007)
Abstract
The effect of overgrazing on vegetation changes in central Zagros has been studied by a few scientists, but there is no detailed information on the impact of such practices on soil properties. The objective of this study was to assess the effect of climate and grazing management on selected soil biochemical properties. Fourteen experimental range sites protected against grazing as well as their adjacent overgrazed sites in Chadegan, Pishkuh and Poshtkuh were selected. In each site, samples were collected from the depths 0-5 and 5-15 cm. Soil organic C (OC), microbial biomass C (MBC), total nitrogen (TN), organic C to total N ratio (C/N), microbial biomass C to organic C ratio (Cmic/Coc) and metabolic quotient (qCO2) were measured and/or calculated. The results showed that the lowest SOC, MBC, TN and Cmic/Coc occur in Chadegan due to low fresh materials input. The above parameters in Pishkuh and Poshtkuh regions are 2.5 to 3 times greater than those in Chadegan area. Grazing intensity in Pishkuh is less than that in Poshtkuh region and there is no significant difference between grazed and protected sites in Pishkuh. But, there is a significant difference between grazed and protected plots in Poshtkuh due to a higher grazing intensity. Higher Cmic/Coc and lower qCO2 suggest that the quality of organic matter is better in Poshtkuh and Pishkuh. In conclusion, highly degraded rangelands in Pishkuh and Poshtkuh seem to be able to recover very quickly with proper management, while Chadegan region needs a much longer period of time to restore.
F. Kiani, A. Jalalian, A. Pashaee, H. Khademi,
Volume 11, Issue 41 (fall 2007)
Abstract
To investigate the degree of forest degradation and the effect of land use change on selected soil quality attributes in loess-derived landforms, samples were taken from different land uses including forest, rangeland, degradated rangeland and farmland in Pasang watershed located in the Galikesh area of Golestan province (37°16'N, 55°30'E). The annual average temperature and mean precipitation of study area were 15°C and 730 mm respectively. Organic matter, pH, EC, CaCO3 and nutrients (N, P, K) as chemical indicators, hydraulic conductivity, bulk density and porosity as physical indicators and soil respiration as biological indicator were measured. The results showed that the amount of organic matter decreased three percent when it was turned from forest to farmland, and increased two percent from farmland to rangeland. The amount of CaCO3 in surface layer of deforested area was more than in the forest soils. The amount of soil N in forest and soil P and K in rangeland were higher than in other land uses. Bulk density and porosity in forest and MWD in rangeland were higher than in other land uses because of the decrease in organic matter due to farming activities. Soil respiration in forest was highest as compared to in other land uses. Difference of enzymes activities (L-asparaginase and Dehydrogenase) compared to microbial respiration indicates that enzymes activity is related to specific biological processes while soil microbial respiration basically depends on the general activity of soil microbial population. It could be concluded that amount of organic matter, soil N, bulk density, porosity, MWD, soil respiration and enzymes activities are suitable indicators for soil quality evaluation in this area.
R. Dehghan, H. Shariatmadari, H. Khademi,
Volume 11, Issue 42 (winter 2008)
Abstract
Studying soil phosphorus fractions is useful in understanding soil pedogenesis as well as soil fertility. In this reseach, 20 soil samples were taken from different depths of 0-30 and 30-60 cm of upper-slope, mid-slope and lower-slope positions of four toposequences in arid (Jei and Ziar in Isfahan) and semiarid (Farokhshahr and Shahrekord) regions. In each toposequence, the soil depth was relatively low at the upper-slope position and increased toward the lower-slope. The soils in upper-slope and mid-slope were under scarce native vegetation where the soil in lower-slope was under farming activities. Soil phosphorus (P) fractionation was carried out using sequential extraction. The total soil phosphorus was in the range of 302-1135 with an average of 715 mg/kg. About 65-89% of total phosphorus were inorganic, and 11-35% organic. The amount of inorganic and organic P in the soil samples was in the range of 204-897 with an average of 571, and 70-238 with an average of 114 mg/kg, respectively. The amount of total, inorganic and organic P increased from upper-slope toward the arable lands and decreased from topsoil to subsoil in all toposequences. In the studied soils, apatite ( Ca10-P ), aluminum phosphates(Al-P), octacalcium phosphates( Ca8-P ), iron phosphates (Fe-P), iron oxides occluded phosphates( OC-P ) and dicalcium phosphates( Ca2-P ) were the major constituents of the soil inorganic phosphates, respectively.
O. Khademi, Y. Moustofi, Z. Zamani , M.r. Fatahi Moghaddam,
Volume 12, Issue 43 (spring 2008)
Abstract
In this experiment the response of persimmon fruit, cv. Karaj, to astringency removal by ethanol and the effects of this treatment on some important fruit characteristics were investigated. Fruits were harvested at three different dates and at each date based on the previous results, and then modified treatments were applied. The best ethanol astringency removal treatment in this study was 10 ml of 38% ethanol per kg fruit for 48 hours. The period after ethanol treatments had no effect on the reduction of soluble tannin concentration, although it resulted in the reduction of flesh firmness and increased soluble pectin. Ethanol treatments and also temperature conditions reduced flesh firmness and increased ground color of fruits however, the effect of ethanol treatments was more than temperature conditions. Temperature conditions increased ethylene production, thus reducing the flesh firmness and increasing the ground color index of fruits. Ethanol treatments did not increase the ethylene production, and it seems that its effects on some characteristics are due to ethanol itself or factors other than ethylene.
N. Toomanian, H. Khademi , A. Jalalian,
Volume 12, Issue 44 (summer 2008)
Abstract
Determination of landscape evolution is useful to well understand the physical environment and it also enables us to conduct the soil related studies. The objective of this study was to establish the historic evolution of Zayandeh-rud Valley from late Tertiary to Quaternary. To achieve this objective, the spatial structure of a representative area of Zayandeh-rud Valley in three dimensions was examined. Responsible geologic and geomorphic processes of landscape formation were determined and inherited records and evidences of changes in soil development were investigated. The inherited foot marks and different analyses proved that following the Zayandeh-rud River formation, from Miocene to present time, the following processes and events have occurred during valley formation pathway: 1- formation of old gypsiferous gravelly alluviums, 2- lagoon formation, the change in the river pathway, 3- playa formation, 4- river terrace deposition and 5- starting of wind erosion.
A. Jafari, H. Shariatmadari, H. Khademi, Y. Rezainejad,
Volume 12, Issue 44 (summer 2008)
Abstract
Mineralogy is one of the most influential soil properties that change from upper- to lower slope positions, depending on the climate differences. Such changes affect soil properties such as phosphorus sorption and desorption processes differently. Therefore, this study was carried out to investigate the clay mineralogy of soils in four toposequences from arid (Isfahan) and semiarid (Chaharmahal Bakhtiari) regions and its effect on soil P release. The soils of three points on each toposequence were sampled as the upper-slope mainly containing parent materials the mid-slope, non-arable lands and the lower-slope, arable lands. Some of soil properties such as clay minerals were determined. Also, trend of P release parameters was studied in four toposequences. Results showed that the amount of clay, cation exchange capacity (CEC), electrical conductivity (EC), and pH of the soils increase down the slope in all toposequences. X-ray diffractograms showed that kaolinite and illite in upper slope and smectite and chlorite in lower slope were the predominant clays. Among the kinetic models examined based on their determination coefficient and standard error, the Elovich equation was chosen to describe the P release kinetics in studied soils. The trend of P desorption rate along the arid toposequences was in the following order: upper-slope < mid-slope < lower-slope. Furthermore, the rate of P desorption in soils of the semiarid toposequences was higher than arid toposequences. Regarding the trend of P rate parameters along the toposequences, it could be concluded that P release rate and the soil capacity to supply P for plants increase toward lower slope.
A. Karimi, H. Khademi, A. Jalalian,
Volume 12, Issue 44 (summer 2008)
Abstract
Despite the existence of highly silty soils in southern Mashhad, there is no information about the aeolian and /or in situ formation of these soils. The main objective of this study was to determine the source of silt generation in this area. Granitic hilly lands in southern Mashhad have been covered by silty deposits. Based on the soil origin, four profiles including a residual soil covered by a silty layer, a residual soil with low amount of silt, a highly silty soil and an alluvial soil as well as a deep profile containing a succession of silty and alluvial materials were studied. Cumulative particle size distribution curve (CPSDC), depth distribution curves of silt/sand ratio (Si/S), Folk inclusive graphic standard deviation, Folk inclusive graphic skewness (SKI) and sand grain morphology analyzed by scanning electron microscopy (SEM) were determined and used to identify the source of the silty materials. Based on the results obtained, silty (L), residual-silty (R-L), residual (R), alluvial (A) and alluvial-silty (A-L) horizons were identified. CPSDC of L horizons is sigmoidal in shape and is easily distinguishable from that of the other horizons. In contrast, the CPSDC of alluvial and residual horizons is spherical in shape. CPSDCs for R-L and A-L horizons are neither sigmoidal nor spherical, but something in between. The L horizons have the highest SKI (very skewed to fine particles) and the lowest Folk inclusive graphic standard deviation (very badly sorted). In this regard, alluvial and residual horizons are intermediate. Because of the silt addition to R-L and A-L horizons, these horizons have a nearly zero SKI (symmetrical) and the highest Folk inclusive graphic standard deviation (very badly sorted). Particle size distribution histograms of R-L and A-L horizons are bimodal, a mode for sand and a mode for silt, suggesting two different sources. Depth distribution of Si/S, SKI and Folk inclusive graphic standard deviation of highly silty and other horizonz show a drastic change between L horizons and the other horizons-an indication of lithologic discontinuity and difference in origin. In conclusion, despite the possible contribution of granitic parent rocks to silt generation in the area, loess deposits recognized appear to have mostly been transported by aeolian movement.
M Momeni, M Kalbasi, A Jalalian, H Khademi,
Volume 12, Issue 46 (1-2009)
Abstract
The forms and dynamics of soil phosphorus can be greatly affected by land use changes, which often involve changes in vegetation cover, biomass production and nutrient cycling in the ecosystem. Present research evaluates the impact of land use change on the amount of total organic and inorganic P, labile, moderately labile and nonlabile P pools in semiarid soils of central Zagros. Samples were collected from surface soils (0-10 cm) of i) of moderately degraded pasture (20-25% plant cover), ii) highly degraded pasture (5-10 % plant cover), and iii) cultivated field (10 years) in Soolegan sub watershed and i) moderately degraded pasture (25-30 % plant cover) and ii) highly degraded pasture (5-10 % plant cover) in Sadat Abad sub-watershed. Significantly (P<0.05) low amounts of total organic P were found following cultivation (23.9%) and overgrazing (18.2 and 40.8 %) in Soolegan and Sadat Abad, respectively. The largest depletion of labile organic P (NaHCO3-Po) (72.3%) and moderately labile organic P (H2SO4-Po plus NaOH-Pi) (24.3%) were observed in cultivated rainfed land in Soolegan. Overgrazing led to decrease in labile organic P (42.1 and 64.4%), moderately labile organic P (13.9 and 35.7%) and nonlabile organic P (NaOH-Po) including moderately resistant and resistant organic P (12.9 and 44.4%) in Soolegan and Sadat Abad, respectively. Our results showed that degradation of natural plant cover cause to depletion in the soil P pools. Decreasing the amounts of moderately resistant and resistant P pools led to a decline in soil productivity and fertility.
M Noruzi, A Jalalian, Sh Ayoubi, H Khademi,
Volume 12, Issue 46 (1-2009)
Abstract
Crop yield, soil properties and erosion are strongly affected by terrain parameters. Therefore, knowledge about the effects of terrain parameters on strategic crops such as wheat production will help us with sustainable management of landscape. This study was conducted in 900ha, of Ardal district, Charmahal and Bakhtiari Province to develop regression models on wheat yield components vs. terrain parameters. Wheat yield and its components were measured in 100 points. Points were distributed randomly in stratified geomorphic surfaces. Yield components were measured by harvesting of 1 m2 plots. Terrain parameters were calculated by a 3×3 m spacing from digital elevation model. The result of descriptive statistics showed that all variables followed a normal distribution. The highest and lowest coefficient of variance (CV) was related to grain yield (0.36) and thousand seeds weight (0.13), respectively. Multiple regression models were established between yield components and terrain parameters attributes. The predictive models were validated using validation data set (20% of all data). The regression analysis revealed that wetness index and curvature were the most important attributes which explained about 45-78% of total yield components variability within the study area. The overall results indicated that topographic attributes may control a significant variability of rain-fed wheat yield. The result of validation analysis confirmed the above-stated conclusion with low RMSE and ME measures.
S.j Hosseinifard, H Khademi, M Kalbasi,
Volume 13, Issue 50 (winter 2010)
Abstract
This study was conducted to determine the effect of 3 extractants on K release from biotite, phlogopite and muscovite. The minerals were grouped to <60 and 60-100 µm size classes. Particles CEC were saturated with calcium. Sequential extraction up to 30 times was carried out using 0.01M HCl, 1M NH4OAc and 0.05M BaCl2 solutions and cumulative concentration of K was calculated for each extractant. There was a difference among the 3 extractants in cumulative K release values from the three minerals. The highest values of cumulative K release were obtained by 0.01M HCl and 1M NH4OAc for less than 60 and 60-100 µm particle sizes, respectively. The amount of K release from muscovite was even higher when 1M NH4OAc and 0.05M BaCl2 solutions were used as extractants. This might indicate that muscovite cannot be considered as an ineffective source of available K in soils. Furthermore, particle size had a great impact on nonexchangeable K release from micaceous minerals. Coarser particles released higher quantity of K as compared to that of finer particles. Therefore, particle size distribution of different micaceous minerals in soils may be a factor that causes a difference in the amount of K release from soils.
M Nael , A Jalalian1 , H Khademi, M Kalbasi, F Sotohian, R Schulin,
Volume 14, Issue 51 (spring 2010)
Abstract
Geologic and pedologic controls are the main factors determining the behavior of elements in natural soil environments. In order to assess the role of these factors on content and distribution of selected major and trace elements in soil, six parent materials including: phyllite, tonalite, periditite, dolerite, shale and limestone were selected in Fuman-Masule region. Soil genesis and development of representive residual pedons were studied for each parent material and the total content of Si, Al, Ca, Mg, Fe, Ti, Mn, Ni, Co, Cr, Cu, Pb, V and Zn were compared among them. Enrichment/depletion patters of trace elements were assessed using Ti as reference element. Generally, Cr, Ni, Co and V are highest in soils derived from peridotite (984, 285, 53 and 204 mg/kg, respectively) and dolerite (1023, 176, 39 and 185 mg/kg, respectively). In the same way, Si and Al exhibit the features of parent materials in the sense that the lowest content was observed in soils developed on peridotite, dolerite and limestone. Zinc and Pb are highest in soils derived from shale (106 and 27 mg/kg, respectively). In a given pedon, different elements exhibited different enrichment/depletion patterns moreover, a given element may behave differently not only in soils with different parent materials but also, in some cases, in soils developed on similar lithology. Lead, Zn, Cu and Mn have been generally enriched in most pedons, except in some acidic and strongly leached soils, whereas Co, Cr, Fe, Ni and V have been leached, especially from Dystrudepts and Eutrudepts. The latter elements, however, showed enrichment trend in Hapludalfs and Argiudolls parallel to the development of illuvial B horizons.
M. Nael , A. Jalalian , H. Khademi , M. Kalbasi , F. Sotohian , R. Schulin ,
Volume 14, Issue 54 (winter 2011)
Abstract
Geologic and pedologic controls are the main factors determining the distribution of elements in natural soil environments. In order to assess the role of these factors in the content and distribution of major elements of soil, six parent materials including phyllite (Ph), tonalite (To), periditite (Pe), dolerite (Do), shale (Sh) and limestone (Li) were selected in Fuman-Masule region. Soil genesis and development of representive residual pedons were studied for each parent material. Total content of Si, Al, Ca, Mg, Fe, Mn, K, Na, Ti and P of soil horizons were measured and compared to the geochemical and mineralogical composition of parent materials. Maximum concentrations of Fe2O3 and MgO were found in the soils derived from Pe and Do however, these soils had low content of SiO2 and Al2O3, which is in conformity with the geochemical composition of the parent rocks. On the contrary, FeCBD content of these soils was lowest, indicating the low degree of soil development and, by the same fact, the importance of inheritance factor in soil Fe concentration. However, comparison of total Fe and FeCBD in Li1, Sh2 and To2 revealed that relative development of these pedons is higher than the others. Silicon depletion in Ph1, To2 and Sh2 pedons, relative to parent rocks, is higher than in Pe and Do pedons. However, this element is enriched in Li pedons. MnO content of Pe and Do pedons is governed by geogenic factors, while in Sh pedons, pedogenic factors, especially redox conditions, play the major role. Exchangeable forms of Ca and Na are determined by soil properties rather than by parent material type. Notwithstanding the redistribution of all major elements throughout pedons due to soil forming processes, the importance of inheritance factor in soil Si, Al, Mg, Fe, K, and Ti is higher than pedogenic factors.