JWSS - Journal of Water and Soil Science

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In this study, the effects of enhancing synthetic chelators (HEDTA, EGTA) and low molecular weight organic acids (LMWOA) such as citric acid were compared on cadmium (Cd) solution in soils that were artificially contaminated. Also Cd phytoextraction capability by radish (Raphanus Sativus L.) was studied. The experiment was laid out in a randomized complete factorial design where each treatment was replicated three times. Concentration treatments of cadmium using CdCl2 were 0(control), 5, 20, 60 and 100 mg Cd kg-1. After complete growth of plants, 6, 20 and 20 mMkg-1 soil HEDTA, EGTA and Citric Acid were added per pot, keeping a control without any chelator application. In order to determine cadmium concentration ten days after adding chelates, samples were taken from the plants and soil of pots. The results showed that in all treatments the concentration of soluble Cd in soil was higher than the control. Also the results showed that synthetic chelators as compared with LMWOA (Citric Acid) have increased the solution remarkably. Among the other chelates, HEDTA had significant effects on Cd solution. In the current study, Cd concentration in shoot and root of (Raphanus Sativus L.) was increased with enhancement of Cd concentration in soil. Cd concentrations in shoots of radish were higher than those in roots. This could refer to higher bioavailability and solubility of Cd. In the current study, in all the treatments with HEDTA Cd concentrations in shoot and root of (Raphanus Sativus L.) were increased as compared with other chelates..

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Soil bulk density measurements are often required as an input parameter for models that predict soil processes. Nonparametric approaches are being used in various fields to estimate continuous variables. One type of the nonparametric lazy learning algorithms, a k-nearest neighbor (k-NN) algorithm was introduced and tested to estimate soil bulk density from other soil properties, including soil textural fractions, EC, pH, SP, OC and TNV. As many as eight nearest neighbors, based on cross validation technique were selected to perform bulk density prediction from the attributes of 136 soil samples. The nonparametric k-NN technique mostly performed equally well using Pearson correlation coefficient (r=0.86), root-mean-squared errors (RMSE=2.5) maximum error (ME=0.15), coefficient of determination (CD=1.3), modeling efficiency (EF=0.75) and coefficient of residual mass (CRM=0.001) statistics. It can be concluded that the k-NN technique is an alternative to other techniques such as pedotransfer functions (PTFs).

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Microbial transport in soil is critical in different ways, especially in groundwater contamination and bioremediation of groundwater or soil. The main objectives of this research were quantitative study of bacterial transport and deposition under saturated conditions in calcareous soils. A series of column leaching experiments were conducted. Breakthrough curves (BTCs) of Pseudomonas fluorescens and Cl- were measured. After leaching experiment the bacteria was measured in difference layers of the soil columns. The HYDRUS-1D one- and two-site kinetic attachment-detachment models were used to fit and predict transport and deposition of bacteria in soil columns experiments. The results indicated that two-site kinetic model leads to better prediction breakthrough curves and bacteria retention in the calcareous soil in comparison with one-site kinetic model. Interaction with kinetic site 1 was characterized by relatively fast attachment and slow detachment, whereas attachment to and detachment from kinetic site 2 was fast. Fast attachment and slow detachment of site 1 was attributed to soil calcium carbonate that has favorable attachment site for bacteria. The detachment rate was less than 0.01 of the attachment rate, indicating irreversible attachment of bacteria. Most of the cells were retained close to the soil column inlet, and the rate of deposition decreased with depth. Microbial reduction rate for the soil was 4.02-4.88 log m-1. High reduction rate of bacteria was also attributed to soil calcium carbonate that has favorable attachment site for bacteria.