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Effect of Acidic Biochars on Some Chemical Properties and Nutrient Availabilities of Calcareous Soils
I. Hasanpour, M. Shirvani, M.a. Hajabbasi, M.m. Majidi,
Volume 26, Issue 2 (9-2022)
Abstract
Low organic matter content and alkaline pH of calcareous soils in arid and semi-arid regions are the main reasons for the low nutrient availabilities for plants in these soils. One way to improve the chemical properties and fertility of calcareous soils is the application of organic substances such as biochar produced from pyrolysis of organic wastes. However, biochars have an almost predominant alkaline pH, which exacerbates plant nutrient deficiencies in calcareous soils when used for a long time. Pyrolysis of some organic wastes under controlled temperature conditions can lead to the production of acidic biochar. The effect of acidic biochars on several chemical properties of two calcareous soils in Isfahan province was investigated in the present study. Treatments included two types of biochar (pine cone and rice husk), three levels of biochar addition (one, three, and six percent), two types of soil (a sandy loam (Tiran) and a clay loam (Lavark)), and two incubation periods (one and six months). The results showed that applying biochar could slightly decrease soil pH but raised soil electrical conductivity. In addition, the amount of organic carbon, total nitrogen, and available concentration of manganese in all treatments and the concentrations of available phosphorus, potassium, iron, zinc, and copper in the most of treatments showed a significant increase compared to the control. Amending soil with biochar at a 6% rate caused the most significant changes in the measured parameters in both soil types. In general, the results of this study indicated that acidic biochar produced from pine cones and rice husk can be used as a suitable conditioner to improve the chemical properties and fertility of calcareous soils.

Ammonia Removal from Oily Water by Microalgae Cultivated in an Airlift Photobioreactor
S. Jalinousi, E. Joudaki, A. Moghadassi, M. Mahdieh,
Volume 27, Issue 4 (12-2023)
Abstract
This research presents the application of phytoremediation to remove ammonia from effluent possessing high ammonium content and alkalinity in one of the most complex refineries in Iran. The objective of this research was to find new methods to protect and preserve water resources. At first, the algae distribution was investigated. After purifying the samples, Chlorella Vulgaris was selected as resistant algae in the areas that experienced ammonia shocks. A 10-liter container and an airlift photobioreactor with similar laboratory conditions were developed to control biomass production. Experiments were conducted over 20 days and maximum biomass production occurred in the first 16-17 days. Cell density was expressed as dry cell weight in ammonia concentration from 10 mg/L to 500 mg/L. It was also observed that when the Nitrogen content of the culture medium was less than 50 mg/L, ammonia was completely removed in both methods. At a concentration of 10 mg/L, total ammonia in both methods was removed in the first week. At 50 mg/L to 100 mg/L concentrations, about 94% of ammonia was removed in the glass container and about 95% in the bioreactor. In these concentrations, with high ammonia content, the final cell density, and absorption power were significantly low and this was evident at 500 mg/L. Prevention of water evaporation and biomass settling, better control of some vital parameters including pH, temperature, light, and energy intensity, effective mass and heat transfer, and carbon dioxide concentration led to better efficiency of the airlift photobioreactor. A noteworthy point in this result was the extraordinary performance of Chlorella Vulgaris in removing toxic pollutants such as ammonia and possibly using it in the biological systems of sanitary, refineries, and petrochemicals.

Investigating the interaction Effect of Irrigation Water Quality and Type of Irrigation System on the Soil Physical and Chemical Properties under the Conditions of Using Treated Municipal Wastewater
Y. Choopan, H. Arianpour,
Volume 28, Issue 2 (8-2024)
Abstract
Reducing the effects of the misuse of urban wastewater is to use it in agriculture along with the subsurface irrigation system, which effects on the soil also require extensive investigations. Therefore, the present research was performed in a randomized complete block design with two factors of the type of irrigation source (well water W1 and treated urban wastewater W2) and the type of irrigation system (surface S1 and subsurface drip S2) in three replications (R) for a soil depth of 0-40 centimeter during two crop seasons. The results showed that the potassium, sodium, salinity, and sodium absorption ratio were significant at the 1% probability level in the comparison of system type and irrigation source type, whereas the values of pH, calcium, and magnesium were not significant in the comparison of system type and irrigation source type. The lowest value of calcium, magnesium, sodium cations, chlorine, phosphate, and sulfate anions was obtained in the W1S1 treatment. Also, the highest parameters of salinity, calcium, magnesium, phosphate, potassium, and chlorine were observed for the W2S2 treatment. It can be concluded that irrigation with urban wastewater has improved the chemical properties of the soil, and the type of irrigation system has had minor changes.

Evaluation of the Effect of Soil Fertility Management Scenarios on the Amount of Available Nitrogen, Phosphorus, and Potassium in Soil in Six Consecutive Cultivations
S.a. Ghaffari Nejad, F. Moshiri, S.m. Mousavi,
Volume 29, Issue 2 (7-2025)
Abstract
This study was conducted to evaluate soil fertility management scenarios including separate use of chemical and organic fertilizers (animal manure and municipal waste compost) and their integrated application on changes in the amount of available nitrogen, phosphorus, and potassium in the soil from November 2017 for four years in six consecutive crops at the Agricultural Research Station of the Soil and Water Research Institute. The results showed a depletion of 14 and 44% of soil available nitrogen and phosphorus, and no depletion of available potassium in the treatment without fertilizer in six consecutive cultivations. Annual consumption of 20 t ha-1 of municipal waste compost and 75% of the recommended nitrogen showed the highest amount of soil-available nitrogen. Unlike phosphorus, the amount of soil available nitrogen in municipal waste compost treatments was significantly higher than in cattle manure. The highest available soil phosphorus was in the treatment with 10 t ha-1 of cattle manure before each crop, and the average available phosphorus in six consecutive cultivations was significantly higher than in the other treatments. The use of 10 t ha-1 of cattle manure and municipal waste compost before each crop resulted in the highest accumulation of potassium in the soil, respectively. The available soil potassium in cattle manure treatments was significantly higher than in municipal waste compost. The results of this experiment indicated the importance of using fertilizers containing nitrogen, phosphorus, and potassium in maintaining soil fertility stability in the long term.

Dyeing Wastewater Treatment Using a Batch Electrocoagulation System and Investigating the Effect of Retention Time and Electrode Distance on Removal Efficiency
S. Rezaei, M. Heidarpour, A. Aghakhani,
Volume 29, Issue 2 (7-2025)
Abstract
The growing concern for environmental protection and increasing demand for green approaches to address environmental problems have prompted researchers to explore a sustainable and reliable method for treating dyeing wastewater. One of the sustainable and reliable methods is the electrocoagulation process. In this study, a batch electrocoagulation reactor was designed to evaluate the efficiency of this process in treating dyeing wastewater. The effects of two parameters, electrode distance and retention time, on pollutant removal efficiency were investigated. Electrode distances of 2, 5, and 7 cm were tested, and retention times of 10, 15, 20, 25, and 30 minutes were examined. Results indicated that the optimal electrode distance was 5 cm and the optimal retention time was 20 minutes. Under these conditions, the removal efficiency of BOD, COD, TSS, color, and turbidity reached 83%, 85%, 98%, 98%, and 93%, respectively. The results of this research demonstrate the significant potential of the electrocoagulation system for treating dyeing wastewater.

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