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Showing 87 results for Mohammadi
Systematic Evaluation and Meta-Analysis of Risk, Toxicity Potential, and Carcinogenic and Non-Carcinogenic Risks of Potentially Toxic Elements in Arak City
F. Beigmohammadi, E. Solgi, M. Soleimani, A.a. Besalatpour,
Volume 26, Issue 3 (Fall 2022)
Abstract
The industrial areas are located near residential centers in the city of Arak and potentially toxic elements (PTEs) pollution is a serious threat to human health and living organisms in this area. Meanwhile, soil contamination by PTEs is one of the challenges in this region and various studies have been conducted in this area. Meta-analysis studies provide a comprehensive evaluation of the results of a subject. In the present study, soil contamination data for PTEs in the 11 years (2009 to 2020) were studied through the studies conducted in Arak. In this study, the risk, potential toxicity, and carcinogenic and non-carcinogenic risks of PETs were assessed using indices and mathematical relationships. Based on the results of pollution indices, the soil of Arak city in terms of PETs including Zn, Cd, Cr, Ni, As, Pb, Cu, and Hg were categorized into the polluted and highly polluted classes. The soil of the region in terms of PETs has significant ecological risk and acute toxicity. Cadmium, arsenic, and mercury showed the ecological risk of 49.3%, 23.2%, and 18.3% respectively, and nickel, chromium, and arsenic were responsible for 34.7%, 23.03%, and 22.07% of the toxicity potential of PETs in the soil. Arsenic, nickel, and chromium have the highest carcinogenic risk for children in both the ingestion and inhalation pathways, and chromium, arsenic, and nickel have the highest carcinogenic risk from the inhalation pathway for adults. According to the results, the most considerable PETs in the study area including As, Cd, and Pb, and the most important source of their emission in Arak are anthropogenic resources and industries.

Trend Analysis and Change Points in Stream Flow of Gorganrood Watershed
T. Mohammadi, V. Sheikh, A. Zare,
Volume 26, Issue 4 (Winiter 2022)
Abstract
Trend analysis of stream flow provides practical information for better management of water resources on the eve of climate change. Therefore, the present study investigated river flow variations during three decades as well as projections of future discharge in the Gorganrood watershed. The Man-Kendall method has been used to detect the trend and methods of Pettitt, SNHT, and Buishand to identify points of a sudden change in discharge time series in 8 stations of Aq Qala, Galikesh, Gonbad, Haji Ghoshan, Nodeh, Ramyan, Sadgorgan, and Tamar. The Mann-Kendall trend test showed the existence of a significant negative trend (flow reduction) on a daily and annual scale in all stations. Monthly, the strongest negative trend in Aq Qala, Galikesh, Gonbad, Haji Ghoshan, and Ramyan stations was related to July, but in Nodeh and Tamar stations, it was related to August and February, respectively. A decreasing trend was observed in all stations on a seasonal scale, but this trend was not significant in some seasons. The results of the analysis of change points in discharge showed that the change points in the data used in this study are more of a decreasing and in some cases incremental type and some stations, no change points have been identified at all. Therefore, the number of decreasing changes in the studied hydrometric stations is significantly higher than the incremental changes and is more visible from 1993 to 1997 and 2005-2007 in three and four stations, respectively. Also, the most incremental changes among the stations are related to the Aq Qala station in 2017 with a flow rate of 234 cubic meters per second. Investigation of the flow of the basin in the past decades showed significant monotonic and abrupt changes which are mostly toward decreasing the basin’s discharge. The downward trend in discharge values at different time scales for all hydrometric stations of the Gorganrood watershed, which will be more severe in the future due to global climate change, and increasing the region's water needs for various future use due to population growth and the expansion of industries can also be considered as a serious warning for policymakers, planners, and local managers to prevent a possible water crisis in the region in the future with proper planning.

Assessment of Effective Factors on Soil Pollution by Heavy Metals in a Part of Sirjan Plain, Kerman Province, Iran
M. Naderi Khorasgani, T. Azarbeig, J. Mohammadi,
Volume 27, Issue 3 (Fall 2023)
Abstract
Soil pollution by heavy metals is a significant issue that threatens human health directly and indirectly. The objectives of this research were to map the extension of some heavy metals in soils of a part of Sirjan Plain, Kerman province, to study the role of natural agents on the distribution of heavy metals, and to assess the risk of soil heavy metal concentration for human health. 120 surficial (0-15 cm) compound soil samples were collected during fieldwork. Soil characteristics like soil texture components, pH, electrical conductivity, organic matter, and total soil heavy metal (Fe, Cu, Zn, Cd, and Pb) concentrations were measured using standard protocols. The mapping of soil texture components and heavy metals was done by the usual Kriging method. Results indicated significant correlation coefficients between soil texture components (silt and clay) and total soil Fe and Cu concentrations. Dominant wind direction and spatial distribution of Fe, Cu, and Zn strongly induced the possible dust-born origin of such elements. Results revealed that the sources of Fe, Cu, and Zn were different from those of Cd and Pb. Maximum soil Fe, Cu, and Zn concentrations were in the southern part of the study area, increasing in an upwind direction while for Cd and Pb, maximum soil concentrations were in the northern part of the study area. The Nemerow integrated pollution index revealed that soils were clean for Cd, lowly polluted for Fe, Pb, and Cu, and moderately polluted for Zn.

Trend Analysis and Change Points in Time Series of Water Level of Shallow and Deep Wells in Gorganrood Watershed
T. Mohammadi, V. Sheikh, A. Zare, M. Salarijazi,
Volume 27, Issue 3 (Fall 2023)
Abstract
A quantitative study of groundwater resources and accurate monitoring of changes over time, especially in areas facing limited water resources, is considered essential for proper management and sustainable exploitation of these resources. Golestan province, one of the semi-arid provinces of Iran has faced a drop in the groundwater level and an increase in the salinity of the groundwater due to the excessive withdrawals from the groundwater table and the reduction of atmospheric precipitation in the past few years. Gorgan Plain with an area of about 4727 square kilometers is one of the largest plains in Iran and the most important plain of Golestan province in terms of water supply for agricultural and drinking purposes. In this plain, there is a network of piezometers and observation wells that include continuous monthly measurements for more than 30 years. The objective of this research was to investigate the changes in the groundwater level of shallow (30 years (1989-2018)) and deep (22 years (1997-2018)) wells. The Man-Kendall method was used to reveal the trend and Pettitt, Normal Standard, and Buishand methods were used to identify sudden change points in a time series of groundwater levels in 49 shallow wells and 12 deep wells. The results of this research showed that the groundwater level in most of the studied wells had a significantly decreasing trend at a significant level of 5%. Also, the largest amount of groundwater loss was in the southern and southwestern parts of the plain, which can be attributed to a large amount of water taken from the wells due to their proximity to urban areas and some local conditions such as the proximity of the wells of this area are located in altitudes and at the entrance border of the aquifer. In the same way, as it rises, the fall decreases in the middle of the plain, and the amount of fall decreases in the northern areas and the edge of the Caspian Sea. It can be related to the proximity to the Caspian Sea and the high water table, and as a result, the inappropriate quality of water and land (high salinity and low fertility), which has caused the water withdrawal from this area to be less.

Production of Cyanobacterial Microscale Adsorbent by Hydrothermal Method for Pre-concentration of Cadmium from Water
T. Mohammadi Arian, G. Rahimi, R. Khavari Farid,
Volume 29, Issue 1 (Spring 2025)
Abstract
Heavy metal pollution is considered a serious risk to the environment and human health due to its toxicity and indestructibility. Measuring and monitoring little concentration (even lower than the detection limit of the device) in the case of dangerous and biostable pollutants such as cadmium in natural water samples is a necessity. Solid-phase extraction using carbon adsorbents is the most efficient and common method of pre-concentration of heavy metals from environmental samples. The carbon adsorbent used in solid phase extraction must have favorable physical and chemical characteristics, along with low cost and biocompatibility. In this research, Aphanocapsa cyanobacterial cells were used as a cheap precursor to make a microscale absorbent using the hydrothermal method. The qualitative and absorption characteristics of this adsorbent were evaluated using instrumental analysis tests and chemical tests based on cadmium. The absorbent is made in the form of relatively spherical particles (with a size of less than 10 micrometers) with a rough surface and a specific surface area of 382.02 square meters per gram. The efficiency of cadmium absorption of absorbent was in a wide range of pH (3 to 8) and more than 90% due to the buffering effect. The absorbent surface was rich in oxygen and nitrogen functional groups, such as hydroxyl, isothiocyanate, and carbonyl. The cadmium absorption isotherm was the best fit with the Freundlich nonlinear model, and the cadmium absorption rate was the best fit with the pseudo-second-order nonlinear model. The calculation variables related to the Freundlich model, including the inverse of the absorption intensity, showed that the adsorbent has a great tendency to absorb low concentrations of cadmium. Cadmium had the most and least competition for absorption on the adsorbent with alkali metal cations and heavy metal cations, respectively. The resistance of the adsorbent against the increase of ionic strength and the concentration of competing cations was equal to 4 and 20 mg/liter, respectively. The washing efficiency of the adsorbent loaded in the adsorbent-to-solution ratio (1:1000), at a normal concentration of 0.3 and a volume of 160 microliters of detergent (nitric acid), reached its maximum value. According to the findings of this research, the carbon adsorbent originating from the cyanobacterium Aphanocapsa can be an efficient adsorbent to use in the solid phase extraction of cadmium to reduce environmental pollution due to its unique properties.

Physical Soil Quality Evaluation of a Part of Beheshtabad Sub-basin in Chaharmahal va Bakhtiari Province
M. Naderi Khorasgani, R. Amiri, A. Karimi, J. Mohammadi,
Volume 29, Issue 1 (Spring 2025)
Abstract
The soils of the Shahrekord plain, part of the Beheshtabad watershed subbasin in Shahrekord County, Chaharmahal va Bakhtiari province, have been used for crop production and domestic animal feeding for centuries, yet the soil quality of this plain has been overlooked. Therefore, assessing the quality of Shahrekord plain soil is essential. This research aimed to evaluate the physical soil quality of the plain using soil quality indices such as the Integrated Quality Index (IQI) and Nemoro Quality Index (NQI). A randomized compound sampling strategy was employed, and 106 surficial (0-25 cm) soil samples were collected during intensive fieldwork. Following pretreatments of the soil samples, several key soil characteristics were measured using standard methods, which were compiled into a Total Data Set (TDS) and used to calculate IQITDS and NQITDS. The minimum effective data set (MDS) was selected, and weights for the quality indices were determined using TDS and Principal Component Analysis (PCA). The minimum data set included the soil sand percentage, soil organic matter percentage, mean weighted diameter of aggregates, soil moisture at field capacity, bulk density, soil reaction, and electrical conductivity. The soil quality at each sample site was assessed using the indices and data sets, TDS and MDS. Geostatistical techniques and ordinary kriging methods were utilized to map soil quality. Results indicated that the soil quality of rangelands was significantly higher than that of cultivated soils (irrigated and drylands). Additionally, approximately 71% of the soils were classified as very low, low, and medium quality, highlighting the need for monitoring and managing such soils.

The Role of Soil Water Solutes Type on Changes in Evaporation Intensity from sandy and clayey soils
M.r. Shoaibi Nobariyan, M.h. Mohammadi,
Volume 29, Issue 2 (Summer 2025)
Abstract
The objective of this study is to investigate the effects of solutes and water quality on evaporation amount and rate in two sandy and clayey soils. Soil samples containing aggregates and sand particles with diameters ranging from 0.5 to 1 millimeter were collected. Six columns were prepared during the experiment; three columns were filled with sandy soil and three with aggregated soil, each measuring 60 cm in height and 15.5 cm in inner diameter. One reference column was filled with distilled water. A saturated calcium sulfate solution was added to two columns, a 0.01 molar calcium chloride solution was added to two other columns, and distilled water was added to the remaining two. The amount of water lost through evaporation was recorded every 8 to 12 hours by weighing the columns. After approximately 130 days, the columns were sectioned, allowing for the establishment of moisture and solute concentration profiles for each soil column. The results indicated that the first and second stages of evaporation were distinguishable in sandy soil, whereas in clayey soil (aggregated soil), only the first stage of evaporation occurred due to the gradual transfer of water and the continuous hydraulic connection from the surface to the water table. The presence and type of solutes affected the evaporation rate and moisture profile, reducing evaporation and increasing water retention in deeper soil layers. Hydraulic connectivity (calcium sulfate > calcium chloride > distilled water) and the resulting capillary rise of and supply of evaporated water from higher layers caused a greater evaporation rate in the calcium sulfate compared to the calcium chloride and distilled water treatments in both soil types. Additionally, the formation of a salt crust on the soil surface due to solutes disrupted the hydraulic connection with the surface, resulting in decreased evaporation rates and cumulative evaporation.

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