JWSS - Journal of Water and Soil Science

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Environment pollution is an important problem in the world. In agriculture irrigation, drainage and fertilization activities cause water resource and environmental pollution by effecting on solute, nutrient and sediment transport. Combined methods of water and nutrient management could consider in pollution transport controlling that reducing runoff and deep percolation, providing opportunity for solute infiltration, reducing sediment transport even economic and easy usage. In this research, affect of two different management in irrigation (cutback and continues) and fertilization (solid and fertigation) on nutrient loss was evaluated. Comparing nitrate, phosphor and potassium loss in different management explicate cutback flow with no uniform solid distribution of fertilizer is more useful to prevent nutrient loss. Because of similar results, increasing in fertilizer distribution in furrow length and easy usage between nitrate losses in six managements, show cutback flow with three proceeding solid, fertigation and fertigation (with 1/4, 1/2 and 1/4 ratio) fertilization was recommended replacement of cutback flow with three proceeding solid fertilization.

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Side weirs as flow diversion devices are usually used as emergency weirs in large hydraulic structures like dams and irrigation and drainage networks, because of their importance they require delicate design. As a result application of numerical and simulation models play an important role in design of these hydraulic structures. In this research, the flow pattern and shear stress distribution on broad crested side weirs with different widths and entrances along with different discharges were studied by numerical solution under two and three dimensional conditions and then the results were compared with laboratory findings. These experiments were conducted in a rectangular channel with one side weir and a length of 70 cm. Experiments were done considering rounded and sharp entrances with different rounded radii and one constant discharge with intake proportions of 40 and 60 in main and branch channels, respectively. Comparison of numerical solution and experimental results show that side weirs with rounded entrance had a noticeable shear stress reduction (arrived in the bed and sides) and non-effective spinal flow, resulting in increased intake efficiency.

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Phytoremediation is a new, in-situ and emerging remediation technology for contaminated soils. This technology, compared to other methods, is a sustainable, natural, relatively cheap and applicable to large scale area. Modeling phytoremediation provides quantitative insight for the governing process as well as for managers to assess the remediated sites. The objective of this study was to introduce a macroscopic phytoremediation model for Ni and Cd- polluted soils. The proposed model assumes that relative transpiration reduction function can resemble total soilNi and Cd concentrations. Combining the related functions of soil and plant responses to soil Ni and Cd concentrations, the phytoremediation rate of Ni and Cd was predicted. In order to test the proposed model, large quantities of soil were thoroughly polluted with Ni and Cd. Upland Cress (Lepidum sativum) and Ornamental Kale (Brassica olerace var. Viridis) seeds were then germinated in the contaminated soils. The experimental pots were irrigated with fresh water to reach field capacity. Upland Cress and Ornamental Kale were harvested three and four times, respectively. At each harvest, relative transpiration, Ni and Cd contents of soil samples and plants were measured. Comparison of the maximum error, root mean square error, coefficient of determination, modeling efficiency and coefficient of residual mass indicated that the non-threshold non-linear model provide high efficiency to predict relative transpiration for Upland Cress and Ornamental Kale, respectively. The results also indicated that the proposed macroscopic model can well predict the phytoemediation rate of the Ni and Cd by Upland Cress (R2>0.83) and Ni by Ornamental Kale (R2=0.78).

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  In this study, chemical quality of Zayandehrud river between Zayandehrud Regulating Dam and Nekouabad Diversion Dam, three discharging drains and one Fehlman well were measured using HPLC with determine the pollution concentration of diazinon insecticide from July 2006 to March 2007. Also, Zayandehrud’s assimilative capacity was determined. The results showed that river water and drains were not polluted to diazinon. Physical, chemical and biological factors effective in the diazinon detection were assessed. Diazinon was detected in the groundwater sample in October with concentration of 32.1 ng/L. This level was lower than the maximum permissible level for drinking water. Also, the NO^-₃ concentration in this month was 24 mg/L that is 2.4 times the standard level (10 mg/L). Due to the increased discharge of different wastewaters to Zayandehrud, its assimilative capacity decreased from upstream to downstream. So, prevention of use of pesticides and pre-treatment of wastewaters that are discharged to this river need more attention.

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The growth and fluorescence parameters of chlorophyll in four corn hybrids including two sweet (K.S.C. 403 and K.S.C. 404) and two grain hybrids (S.C. 500 and S.C. 700) were evaluated in response to Fe and Zn nutrition in a nutrient solution culture. This study was conducted in a randomized complete block design with a factorial arrangement with three replications at the Soilless Culture Research Center (SCRC). Corn hybrids were exposed to two Fe levels (5 and 50 µM Fe in the form of FeEDTA) and two Zn levels (0 and 2 µM Zn in the form of ZnSO4). Increasing Fe concentration in the nutrient solution increased F0, Fm, and Fv/Fm values by 48, 96, and 123%, respectively. The fluorescence parameters of chlorophyll were affected by corn hybrid and there were significant differences in F0 and Fv/Fm at 1% level and Fm at 5% probability level among the studied hybrids. Iron deficiency significantly (P<0.05) reduced the root dry weight of all the studied hybrids. Zinc deficiency resulted in a significant decrease in the root dry weight of H403 and H500 hybrids while no significant decrease was found in the root dry weight of the H404 and H700 hybrids under Zn condition. The results showed that corn hybrids varied significantly in their tolerance to Fe and Zn deficiency. Based on the results of plant growth and fluorescence parameters of chlorophyll, the studied grain corn hybrids were more tolerant to Fe and Zn deficiency conditions in comparison with sweet corn hybrids. It seems fluorescence parameters of chlorophyll might be suitable parameters to screen corn hybrids in their tolerance to Zn and particularly Fe deficiency condition.

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Among the environmental pollutants, heavy metals according to their irresolvable and physiological effects on living organisms at low concentrations, are of special importance These elements due to low mobility are gradually accumulated in soil Being accumulated in soil, they eventually enter the food chains and threaten human health and other creatures Therefore, studying concentration distribution of heavy metals for soil pollution monitoring and maintaining environmental quality is essential In this study we investigated the effect of agricultural land use and geology on the concentration of heavy metals contamination of soil and spatial distribution map, using collected data, GIS and GeostatisticsUsing systematic stratified random sampling, 135 surface soil samples( 0-20 cm) from an area of 7262 sq km area and we measured total concentration of elements Nickel, Chromium and Cobalt and soil characteristics including pH, organic matter and texture. The mean value of elements concentrations turned out to be Cr: 88.9+22.7 Co: 17.6+3.5 Ni 63.1+17.7 mg per kg and the mean acidity is 7.8 which in the area is an indication …… property. Formetal concentrations interpolation procedures, Geostatistics was used. By the aid of spatial correlation analysis, appropriate interpolation method using functions mean absolute error and bias average error were selected. Interpolation map concentrations of heavy metals Chromium, Cobalt and Nickel with ordinary kriging method and the exponential model were developed Interpolation map analysis of heavy metals by the aid of geological and land use maps show that the distribution of the elements Chromium, Cobalt and Nickel are consistent with the geology classes However, they did not match the agriculture pattern Findings of this study in the area give us appropriate information about the concentration distribution of heavy metals Chromium, Cobalt and Nickel which can be used in monitoring and evaluation processes of heavy metals pollution in agricultural lands area. But on the other hand sampling in the areas far away from human effects, showed that the heavy metals concentration is naturally high.

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Waste tire rubbers are considered one of the environment pollutants. Increased production of these pollutants has led to more serious consideration of ways to reduce the harms caused by their accumulation in the environment. Therefore, the effects of incorporation of waste rubber crushed particles in two sizes of 1-2 and 3-5 mm and the amounts of 0, 5, 10 and 20 Mg ha-1 in a calcareous soil (0-30 cm depth) on some chemical properties of soil was investigated in Isfahan University of Technology research field (Lavark). This experiment was performed using seven treatments along with a non amended control treatment in a randomized complete block design with three replications in 1387. Eight months after incorporation, soil samples were collected for laboratory analyses. Results of ANOVA tables show that soil pH, electrical conductivity, percentage of total nitrogen and DTPA-extractable concentrations of cadmium, lead, copper and iron were not significantly affected by application of rubber particles. Incorporation of rubber particles into the soil significantly increased soil organic carbon and carbon to nitrogen. Increases in the DTPA-extractable Zn in soils treated with 10 and 20 Mg ha rubber particles in fine and coarse sizes were significant in comparison with the control soil. DTPA-extractable Zn content in the soil treated with 10 and 20 Mg ha 3-5 mm waste tire rubbers particles was about two and three times higher than that in the control treatment, respectively. The results of this study showed that in short-time, incorporation of crushed tire rubbers particles had no significant effect on most chemical properties of the soil but increased the available Zn content. In this regard, further studies to monitor the effects of adding waste rubber crushed particles on organic matter mineralization, plant toxicity and physical properties of soil in long-term are recommended.

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Silver toxicity and its fate in the environment are currently being debated and are important as challenging research topics. Even though there are several studies on its total content in soils, fractionation of Ag especially in calcareous soils has not been investigated. Therefore, to provide fundamental information on the chemical behavior of Ag in calcareous and noncalcareous soils, we studied 8-step chemical fractions of Ag (i.e., EXCH, CARB, Me-Org, re-MeOx, H2O2-Org, am-MeOx, cr-FeOx, and RES) after 30 and 60 days of incubation in soils amended with Ag (0 and 15 mg kg-1), sewage sludge (0 and 20 t ha-1) and EDTA (0 and 0.5%). Experimental results showed that redistribution of Ag in spiked noncalcareous soils was EXCH (34%), H2O2-Org (33%) and RES (17%). In calcareous soils, after 30 days, EXCH- and RES-Ag increased but at the end of 60 days H2O2-Org-Ag increased. Based on our data, we could conclude that addition of Ag results in an increase of Ag mobility in soils but incubation and sewage sludge may have adverse effect on its mobility. In contrast to noncalcareous soil, EDTA in calcareous soil resulted in higher Ag mobility. This may have environmental implications in Ag polluted calcareous soils.

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This research was carried out to determine spatial distribution of heavy metals concentration in soil particle size classes using Landsat ETM+ reflectance in Southern Isfahan city in the vicinity of Bama mine. To fulfill this goal, 100 compound soil surface samples were collected randomly from the area. The samples were air dried and soil particle size classes 250-500, 125-250, 75-125, 50-75 and <50 μm were determined using appropriate sieves after dispersion of the bulk samples of soil using ultrasonic apparatus. Total Zn, Pb and Cd concentrations were measured using Atomic Absorption Spectrophotometer after wet digestion of samples in acid nitric. The results indicated significant negative correlation coefficients between heavy metals concentrations of soil particle size classes and soil spectral reflectance in the visible, near infrared and panchromatic bands of Landsat ETM+ satellite. Stepwise multiple regression models were used for estimating heavy metals concentration in soil particle classes through satellite data. Furthermore, spatial distributions of heavy metals were mapped using stepwise multiple regression equations. Results also showed heavy metals concentrations in all soil particle size classes were maximum close to the mines and decreased by increasing the distance from these sources.

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Iron chlorosis is an important disorder of plane trees (Plantanus orintalis L.) in green space of Isfahan city. Before using reclamation methods for correcting Fe chlorosis, it is necessary to find a suitable index for evaluating plant Fe status. Therefore, activity of glutathione peroxidase (GP) enzyme and concentration of carotenoids and chlorophyll a and b pigments, as physiological indices of active Fe, were compared to total Fe concentration in leaves to evaluate Fe status in plane trees. For this purpose, severity of chlorosis of plane trees at different regions of Isfahan city was recorded. Then, 73 trees with different severity of chlorosis symptoms were selected and their leaves were sampled on July 2009 and 2010. Concentration of Fe, chlorophyll a and b and carotenoids in leaves as well as activity of GP enzyme were measured. Results showed large variation in leaf Fe concentration between young and old leaves and also between leaves with different chlorosis severity symptoms. No correlation was found between leaf Fe chlorophyll concentration and severity of chlorosis symptoms. Also, concentrations of chlorophyll a in young and old leaves with very severe chlorosis symptoms were 44 and 37% smaller than that in young and old leaves with slight chlorosis symptoms, respectively. Concentration of chlorophyll b in young and old leaves with very severe chlorosis symptoms were 40 and 37% smaller than that in young and old leaves with slight chlorosis symptoms, respectively. Concentration of carotenoids varied among young and old leaves with different severity of chlorosis symptoms. Activity of GP in young leaves was also reduced by intensifying severity of chlorosis symptoms. According to the result of the present study, activity of GP enzyme and leaf concentration of carotenoids and chlorophyll a, as suitable physiological indices of active Fe, had close correlation with severity of Fe chlorosis in plane trees. Also, deficiency of active Fe in leaves is a probable reason of chlorosis symptoms in plane trees.

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The transport process of chemical-fertilizers, radioactive materials and other solutes in soils and porous media is important to understand the environmental and economic effects of industrial, agricultural and urban waste disposal methods. In unsaturated porous media, large gradient in aqueous osmotic potential derives significant water vapor fluxes towards regions of high solute concentrations. In this research, the effects of osmotic potential (resulting from salinities of 0.5, 1 and 1.5%) on water vapor transport in three soil textures (silty clay loam, loam and sandy loam) were examined by using a physical laboratory model. Then, the experimental results were compared with Kelly and Selker (2001) model for validation of the predicted water vapor transport. The results showed that the rate of water vapor transport reduces significantly as soil texture gets heavier. For example, in salinity of 0.5% and 5th day of experiment, the amount of transported vapor in sandy loam, loam and silty clay loam soils was 0.362, 0.196 and 0.12 kg/m2, respectively. Large osmotic potential near the high solute concentration in soils caused significant vapor movement toward dense solutions. In salinity of 1.5%, transported vapor in these soils was 1.47, 0.723 and 0.38 kg/m2, respectively. Total water vapor movement until the 15th day was more than the 5th day. Comparison of experimental results with Kelly and Selker model results, using Mathcad PLUS 6.0 software, showed a good agreement between the observed and predicted data. Since water vapor delivered from uncontaminated soils to the contaminated soils can result in increased contaminant plume volume, these physical and chemical processes must be included in the predictive models of contaminant transport in the vicinity of concentrated sources

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Copper is considered as one of the most important nutrient elements for plants. If its contents are concentrated higher than the standard value it can be considered as a pollutant element. The content of absorbable copper in the area around Sarcheshmeh copper mine can be significantly high. In this study, samples of soil were collected in summer through a particular sampling method with chimneys of Sarcheshmeh plant as the center of sampling area within a radius of 6km, in three different directions (Rafsanjan, Sarcheshmeh City and Sarcheshmeh mine) and. The total concentration of absorbable copper and some chemical properties of soil (i.e. pH and EC) were measured for 122 surface samples (depth of 0 to 35 cm). There was a significant negative regression between pH and total absorbable copper content, and a significant negative regression was observed between EC and total absorbable copper content. The best fitted model was spherical model, and Ordinary Kriging was applied to map the absorbable copper content. Results showed that most concentration of copper occurred in the Rafsanjan direction. Also, regarding wind orientation which blows towards Rafsanjan, the chimneys probably have a significant effect on increasing copper content in Rafsanjan moreover, the copper content is substantially higher around chimneys than other areas. Also, transition of copper elements from chimneys by wind can be significant up to 4 km from Sarcheshmeh plant.

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Atmospheric dust is an important source of heavy metals, particularly in urban environments. Heavy metals can easily attach to dust particles and be distributed in large areas. The objective of this study was to evaluate the status of major heavy metals in the atmospheric dust of Isfahan and adjacent cities. A total of 144 dust samples were taken during a period from August to December 2010 from Isfahan, Khomeynishahr, Falavarjan, Mobarake and Zarinshahr cities. Dust samples were extracted with HNO3 65% and the total concentration of metals including Pb, Zn, Cd, Cu, Ni, Co, Cr and Mn in the samples was measured by an atomic absorption spectrometer. The mean concentration of these metals was 223.5, 470.3, 3.5, 71.0, 82.0, 26.5, 24.4 and 426.3 mg kg-1, respectively. Results indicated that heavy metals concentration in any area was different depending on the source of pollution and it was much higher than the mean concentration of the corresponding heavy metal in soils. Besides, the highest deposition rate of all the heavy metals in this study was found in November-December period. This could be attributed to an increase in the use of heating systems and also to a temperature inversion event prevailed in the area. Atmospheric deposition seems to be an important pathway of heavy metals addition to soils. For example, it is responsible for 35-91% and 12-47% of Pb and Cd entering the soil in the area, respectively.

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Zeolite is widely used for removing heavy metals from aqueous solutions. The objective of this study was to assess three sizes of zeolite in removing lead, nickel and cadmium from wastewater. A splite-plot experimental design was employed with 45 treatments and three replications at Shiraz University Lab in 2011. The treatments were five different concentrations of the pollutant and three sizes of zeolite (0.075, 0.2 and 0.425mm). The concentrations for lead were: 40, 250, 500, 1000 and 1250 mg/l and 4, 6, 15, 20 and 40 mg/l for nickel and cadmium. The results showed that the effect of concentrations of pollutant was significant, and by increasing the concentration of pollutant, absorption of heavy metals by zeolite increases linearly. Maximum lead absorption occurred at 1250 mg/l with 59.97 mg and minimum absorption of lead was related to the concentration of40 mg/l with 1.82 mg for 1 grams of zeolite. Maximum and minimum nickel absorptions were related to the concentration of 40 and 4 mg/l with 1.92 and 0.16 mg for 1 grams of zeolite, respectively. The values were 1.87 and 0.18 mg for 40 and 4 mg/l for cadmium, respectively. The effect of size of zeolite on the pollutant adsorption was not significant.

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In recent years, due to the increased population, urbanization and changes in human consumption patterns, urban, industrial and agricultural soils have been exposed to various pollutants such as heavy metals. The objective of this research was to identify hotspots of Pb by using global and local Moran Indices in urban and suburban soils of Kashafrood catchment. A total of 261 surface soil samples (0-15 cm deep) were taken using irregular girding network method and their total Pb concentrations were measured. The positive Moran index at confidence level of more than 99 percent showed the spatial clusters between observations. On the basis of local Moran index results, 15 samples were introduced as hotspots (high-high value) located southeast of Mashhad plain. Exclusion of extreme values resulted in the addition of high-high cluster (hotspots) leading to the extension of these areas to the West of the Mashhad city. These areas are introduced as hotspots due to the urban land use, the direction of prevailing wind, and the area being close to Mashhad airport.

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Modeling of flow and transport processes in variably saturated porous media requires detailed knowledge of the soil hydraulic properties. The hydraulic properties to be determined by the inverse problem solution are the unsaturated hydraulic conductivity K(h) and the water retention curve &theta;(h). The inverse modeling approach assumes that both &theta;(h) and K(h) as well as transport parameters can be determined simultaneously from transient flow data by numerical inversion of the governing flow and transport equations. In order to find answers to the questions of uniqueness, identifiability and stability of different experimental setups, a new numerical experiment of redistribution was carried out. To study the shape of the objective function near its minimum, response surfaces for the estimated parameters were generated. The sensitivity of model outputs with respect to changes in input parameters was also computed and analyzed. Results of the redistribution experiment suggest that the non-uniqueness increases when the model output variables are not sensitive enough to the optimized parameters. As expected, the estimated values of parameters were sensitive to the magnitude of error in the measured data. In this experiment, the parameter estimation based on the pressure head observations provides unique solution. Due to preferential flow in the sample, tensiometric observations may provide poor results for inverse problem solution. Taking into account information about saturated hydraulic conductivity, Ks improved the likelihood of uniqueness and reduced the errors in parameter estimation of the shape parameters (&alpha;, n). It was found that the sensitivity analysis could be a useful tool to design the optimal time and location distribution of experimental observations.

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Nowadays, due to the effective role of nitrogen fertilizer in growth, yield and crop quality, farmers apply large amount of chemical fertilizers. High application of nitrogen fertilizers has caused soil and water pollution and environmental dangers, higher nitrate accumulation in plant, and different disease risks in human and livestock. In order to investigate the effects of nitrogen and cycocel application effects on soil nitrate pollution and agronomic traits of rice, an experiment was arranged in split plot based on a completely randomized block design with three replicates at Sari region (north of Iran) in 2010. The main factor was nitrogen in four levels and cycocel was considered as a sub factor in three levels. Results showed that maximum and minimum plant height and fourth internodes bending moment were obtained in 0 and 150 kg N ha-1, respectively. Higher filled spikelet percentage per panicle, grain yield and harvest index were obtained in 100 kg N ha-1 application. Application of N up to 150 kg N ha-1 increased soil nitrate by 44.7 percent. As cycocel application decreased, the plant height and panicle length were reduced, but tiller number per plant, filled spikelet percentage per panicle, and grain yield were increased.

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One of the major problems associated with petroleum-contaminated soils is water repellency, especially in arid regions of the world. Hence, a variety of methods such as clay addition has been proposed to improve the hydrophobicity of soils. This research was conducted to evaluate the influence of zeolite application on water repellency of an oil-contaminated soil from Khuzestan Province under various treatments including initial soil moisture content (0, 10, 20, and 30 weight %), the amount of applied zeolite (2, 4 and 8 weight %), size (25-53 and <2 μm), and exchangeable cation (Sodium and Calcium). The hydrophobicity of soil sample was determined using Water Drop Penetration Time (WDPT) method. The results showed that by increasing the amount of applied mineral WDPT decreased, where the application of 2 percent of zeolite led to the reduction of WDPT by about 27 percent less than the control. The results also indicated that soils treated with sodium-saturated zeolite had less WDPT than the calcium-treated samples, where the average of WDPT in sodium and calcium treatments decreased by 23% and 5% compared with the control, respectively. The initial moisture content of 30 percent showed the best performance with the decreasing WDPT of about 67 percent. Furthermore, the effect of mineral particle sizes showed a meaningless reduction in WDPT.

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Soil pollution and accumulation of heavy metals in soils and crops are the most important bioenvironmental problems that threaten the life of plants, animals and humans. This study was conducted to explore contamination of heavy metals in soils of Hamadan province. A total of 286 composite surface soil samples (0-20 cm) were collected thoroughout the province. After preparation of the samples, the total contents of Zn, Pb, Cu, and Ni in soil samples were extracted using HNO3. Total contents of heavy metals were measured by ICP. Contamination factor results showed that most samples were moderately polluted and contamination factor for lead was highly polluted. Interpolated distribution map of contamination factors (CF) and pollution load index (PLI) of the heavy metals were prepared using GIS. The overlap of CF and PLI maps with geology and land use maps indicated that the concentrations of Ni, Pb, Zn, and Cu have been controlled by natural factors such as parent material, but agricultural activities according to excessive consumption of animal manure and chemical fertilizers can increase most of these elements in soil.

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The present study was conducted to increase phytoextraction efficiency of Festuca ovina L. in lead contaminated soil in the EDTA-assisted (0, 1.5, 3, 1.5+1.5, 3+3, 6 mmol kg&minus;1), assess the best time of plant harvesting to increase Pb uptake and method of EDTA application to reduce Pb leaching risk. The results revealed that the greatest Pb uptake was observed in 3EDTA treatment. Therefore, 3mmolkg-1 was used in the second step for assessing harvest time for 15, 30 and 45 days. Results showed that the concentration of Pb in plant tissues was increased with the passage of time and the best harvest time to achieve maximum removal of Pb was 60 days of the first harvest. In the third step to reduce leaching of Pb-chelate, 3mmolkg-1 EDTA in five ways of single, double, triple, quadruplet, quintuplet were added to the soil. The results indicated that under quintuplet application, Pb content reached its minimum concentration in the soil and in the plant organs, the Pb concentration was maximum and metal concentration in the plant organs did not vary significantly when triple, quadruplet and quintuplet dosages were added (p<5%). Overall, optimum phytoextraction of F. ovina L. and Pb leaching reduction were achieved when 3mmol kg&minus;1 EDTA was added in quintuplet dosage and the plant was harvested at the end of growth stage.