JWSS - Journal of Water and Soil Science

Determining the spatial distribution of different contaminants in soil is essential for the pollution assessment and risk control. Interpolation methods are widely used to estimate the concentrations of the heavy metals in the unstudied sites. In this study, the performances of interpolation methods (inverse distance weighting, local polynomials and ordinary Kriging and radial basis functions) were evaluated to estimate the topsoil contamination with copper and nickel in Golestan Province. 216 surface soil samples were collected from Golestan province, and their Cu and Ni concentrations were measured. Soil contamination was determined using different interpolation methods. Cross validation was applied to compare the methods and estimate their accuracy. The results showed that all the tested interpolation methods have an acceptable prediction accuracy of the mean content for soil heavy metals. RBF-IMQ and IDW1 methods had the lowest RMSE, whereas RBF-TPS method with the largest RMSE estimated a larger size for the polluted area. The greater the weighting power, the larger the polluted area estimated by IDW. Compared with the ‘‘sample ratio over the pollution limits” method, the polluted areas of Cu and Ni were reduced by 8.38% and 6.14%, respectively.

Petroleum pollution is an important environmental issue in most of the countries especially those have an oil industry. This study was conducted to investigate the effect of petroleum pollution on soil water repellency and its relation to soil structural stability in Bakhtiardasht area, Isfahan. Polluted and adjacent non-polluted locations were selected to be representative in the green space around the Isfahan Oil Refinery. Soil water repellency was assessed using water drop penetration time (WDPT) in the polluted locations. Soil sample with least aggregates disturbance were collected and selected soil physical and chemical properties were measured. Soil structural stability was evaluated using the wet-sieving method and mechanically dispersible clay (MDC) structural stability indices of mean weight diameter (MWD) and geometric weight diameter (GMD) of aggregates and MDC were then calculated. Results showed that the positive effect of petroleum pollution on the MWD and GMD become significant. Negative impact of petroleum pollution on MDC was also significant. Increment of total petroleum hydrocarbons (TPHs) increased the soil water repellency. A positive correlation was observed between soil water repellency and GMD. However, TPHs concentrations greater than 6.4% decreased the MWD and GMD presumably due to anionic repulsion between clay particles and hydrocarbon functional groups. Although greater water repellency increased soil structural stability in the polluted locations when compared to control locations, however, diminished water retention of polluted soil has created an unfavorable condition for the green space in the area.

Cadmium (Cd) is a metal with high toxicity and solubility in water, which is a serious environmental threat to human health. Phytoremediation is an environment-friendly method and a promising new and cost effective technology that uses plants to clean organic and inorganic contaminated media. This study was conducted to evaluate the potential of Jatropha curcas for remediation of soils contaminated with Cd. Seedlings were planted in the soil spiked with Cd in amounts of 0, 25, 50, 75, 100 and 150 mg kg^-1 (Cd₀, Cd₂₅, Cd₅₀, Cd₇₅, Cd₁₀₀ and Cd₁₅₀) for a period of five months. Biocentration factor (BCF, metal concentration ratio of plant roots to soil), translocation factor (TF, metal concentration ratio of plant shoots to soil) and removal efficiency (RE, total metal removed by plant biomass to total metal loaded in soil) were determined. Cd concentrations among plant parts were in the following trend: roots>stems>leaves. The highest total Cd concentration (up to 1100 mg kg^-1) and the highest RE were found in Cd₁₅₀ and Cd₂₅, respectively. BCF and TF of the plant were more and less than 1, respectively. Hence, although this species has a potential to be used in phytostabilization of Cd-contaminated soil, more researches in the field condition are needed.

This experiment was conducted to evaluate the effect of vermicompost, pistachio kernel and shrimp shell on the immobilization and availability of Cd, Pb and Zn in corn in polluted soils. Treatments consisted of two levels of pistachio kernel, shrimp shell and vermicompost (5 and 10 % w/w). In control treatment, no amendment was added to the soil. The experiment was carried out as a completely randomized design with 3 replications. Plants grew for two months in the greenhouse. Then, all the plants were harvested and their shoots and roots were separated, washed with distilled water and oven dried at 65 °C to a constant mass. The measured characteristics were dry weight of shoots and roots, leaf area, greenness index, chlorophyll fluorescence, maximal quantum yield of PS  photochemistry (Fv/Fm), performance index (PI), and total concentrations of Cd , Pb and Zn in shoots and roots. Results showed that plant growth parameters (dry weight of shoots and roots, leaf area) and photosynthetic characteristics (chlorophyll fluorescence, Fv/Fm, and PI) were higher in plants grown in vermicompost and pistachio kernel treatments as compared to those grown in control. Plants died in shrimp shell treatment after two weeks. The concentration of Cd, Zn and Pb in shoots and roots of plants grown in vermicompost and pistachio kernel treatments were lower than those grown in control.

Technosols are modified soils affected by human activities. This study investigated genesis, classification and physicochemical properties of four pedons of Technosols developed on refused oil refinery materials and compared them with two unpolluted pedons. Mineralogical studies showed smectite as a dominant clay mineral with other clay minerals. These clay minerals adsorb oil compounds in their interlayer spaces and reduce their mobility and decomposition. Different micromorphological features resulting from oil compounds in soils, including depletion zones, types of coatings (quasi and hypocoating) and features due to horizontal and vertical movement of oil compound in soil showed dynamics of oil compounds and their effects on soil forming process. The refused petroleum compounds decrease pH and increase organic carbon, amorphous form of Iron in soils. Taking into account the presence of high amounts of gypsum and carbonate in polluted soil, the studied soils were classified as Typic Calcigypsids in Soil Taxonomy but in WRB system, due to the presence of impermeable geomembrane within 100 cm of soil surface, they were classified as Linic Technosols, showing the more precision of WRB system in their classification. 

Simulation of water and solute transport in soil is very useful for optimum management of water and fertilizer use. In this study, the HYDRUS-1D model was used to simulate water and nitrate transport in furrow irrigation of sugarcane. For this putpose, a large-scale experiment was performed as a split plot design based on the randomized complete blocks with 3 replications in a 25-hectare piece of land in the Dehkhoda Sugarcane Agro-Industry Company from March 2012 to October 2013. The main factor was split application of fertilizer at three levels: two, three and four splits. The sub-main factor was fertilizer amount, applied at three levels (i.e. 350, 280 and 210 kg urea corresponding to 100%, 80% and 60% fertilizer requirements, respectively). Soil hydraulic parameters were estimated through inverse modeling using moisture data collected during more than 4 months of the sugarcane growing season. Solute transport parameters were then estimated using the hydraulic parameters and nitrate concentration data. In this study, statistical criteria including R², RMSE, ME and SSQ were used to compare the observed and simulated values of moisture content and nitrate concentration. The results indicated that R² for simulated moisture content and nitrate concentration in four splits and 60% fertilizer requirement treatment (i.e. calibrated treatment) were 62.7 and 91.2 percent, respectively. Cumulative infiltration depths were about 46 and 58 mm for calibration and validation treatments, respectively. For these treatments, the cumulative evapotranspiration rates were 50 and 60 mm, respectively. Soil moisture content in the surface layer varied from 21 to 45 and 21 to 42 percent, for calibration and validation treatments, respectively while the changes in the deep layer moisture content were 33 to 38 percent, for both treatments.

Soil moisture is one of the main input parameters in many models for monitoring and predicting crop yield. The ability of mathematical models has allowed correct application of brackish water and selection of management options. The purpose of this research was to evaluate the performance of HYDRUS-2D for simulating soil volumetric water content in a heterogeneous heavy soil under field conditions. Three volumes of irrigation water (10, 15 and 20 L) and three salinity levels of irrigation water (1.279, 2.5 and 5 dSm^-1) were exerted in a linear drip irrigation system with three replications. In order to check the amount of soil volumetric water content, soil profiles were drilled to 40 cm depth and vertical wall of drip irrigation line was networked. Soil volumetric water content was measured with a TDR MiniTrase kit 6050X3K1B model. The observed soil moisture values were compared with the simulated ones using statistical indices (i.e. nRMSE and CRM).  The results indicated that mean soil volumetric water content distribution in irrigation water with different levels of salinities was in the range of field capacity. The range of nRMSE values varied from 0.91 to 2.07 percent in different replications. According to calculated nRMSE values, performance of the simulation model, was ranked as excellent for simulation of soil volumetric water content. Range of CRM values was shown to be from -0.0080 to 0.0170 that was really low. Results of these two statistics indicate high ability of the model in simulating soil volumetric water content using estimating hydraulic parameters by inverse solution.

Heavy metals in dust can directly enter to the human body through ingestion and inhalation. They can pollute the water and soil resources via atmospheric precipitation and accumulate in the plant tissues and then enter human body through water and food. This research aimed to study the heavy metals concentration in dust in Kermanshah province and to identify their sources. 49 samples of dust were collected in the cities of Kermanshah, Songhor, Gilangharb, Ghasre-Shirin, Sahneh, Sarpolzahab, Kangavar, Paveh and Javanrood during the spring 2013. The concentration of Zn, Cu, Ni, Cr, Mn and Fe were determined using an atomic absorption spectrometer following the sample extraction with a mixture of HCL and HNO₃ (3:1 ratio). The average concentrations of Zn, Cu, Ni, Cr, Mn and Fe were 182.3, 48.6, 115.3, 73.9, 428.1 and 23161 mg kg^-1, respectively. Correlation, cluster and principal component analyses were used to identify probable natural and anthropogenic sources of contaminants, and the enrichment factor was used to identify probable effects of human activity on the concentration of heavy metals. The results indicated that metal concentrations, except for Fe and Mn, were higher in comparison with the world soils. Zn, Cu, Ni and Cr are mainly of anthropogenic origin, while Fe and Mn are mainly of natural origin. Zn and Cu are mainly of traffic sources and partly of industrial sources, and Ni and Cr are mainly derived from industrial sources, combustion processes, combined with traffic sources. The analysis of EF revealed moderate enrichment for Mn and Cr, and significant enrichment for Zn, Cu and Ni. Based on the results of this study, more attention should be paid to identifying and controlling the sources of contaminants such as heavy metals in dust in order to prevent their associated pollution.

Water, as a limiting factor, has played a decisive role in shaping and development of Iranian culture and civilization. Water scarcity and a great variety of water users lead to conflicts in rivers' environment. Conflict resolution is conceptualized by the methods and processes involved in peaceful facilitating and ending of the conflict through active communication about their thinking and causes of disagreement as well as persistence in collective negotiations. Currently, the Zayandeh-Rud River basin (ZRR) has been facing severe water scarcity. The aim of this study is to evaluate the methods of water conflict resolution in the ZRR from the viewpoint of farmers and authorities. The statistical population of this study includes all farmers in ZRR and selected staff of Regional Water Authority and Agricultural Organization (Jahad-Keshavarzi) in both Isfahan and Chaharmahal & Bakhtiyari provinces. Data were collected through a sample of 171 farmers and census of authorities through face-to-face interviews based on a comprehensive structured questionnaire. Before the survey, the reliability and validity of the questionnaire was initially evaluated on a pre-test study respectively by using Cronbach’s alpha coefficient and Kaiser-Meyer-Olkin (KMO) criteria. The results showed that the main factors in creating the conflict are drought, increased water use in industry and increased water consumption in other provinces. Furthermore, the most suitable methods of water conflict resolution are the conditions where everybody is able to speak freely, mediation and negotiation. On one hand, in the current situation, farmers prefer violent manners and on the other hand, authorities consider negotiation as the most appropriate solution to the conflict.

Pollutants are considered the disturbing factors of environment, and among them the heavy metals are more important considering their non-degradability and physiological effects on organisms in low concentrations. The goal of this research was to investigate the effect of industrial landuse on Cd and Pb concentrations in surface soils of the southwest Isfahan. According to satellite images and topographic maps (1:50000) of the study area, soil samples (depth: 0–20 cm) were collected using random sampling. A total of 38 surface soil samples were obtained from industrial areas (lowest distance = 1480 m) in the area of 73481 ha. Total concentrations of Cd and Pb in the digested solution were measured by Atomic Absorption Spectrophotometry (AAS). Using Arc GIS, the spatial distribution patterns and Cd and Pb variography of samples were analysed and finally the best models of spatial distribution of heavy metals were achieved. The primary results showed that the mean concentrations of Cd, and Pb of surface soil samples in industrial areas were 1.8 to 31.5 mg Kg^-1 higher than the world’s mean values, respectively. Although the mean concentrations of Cd and Pb were respectively 8 to 700 mg Kg^-1 lower than the standard of Iranian Department of Environment for industrial landuse.

Constant use of treated wastewater (TWW) for irrigation over long periods may cause buildup of heavy metals up to toxic levels for plants, animals, and entails environmental hazards in different aspects. The aim of this study was to assess the effect of using a deep emitter installation on lowering the potential heavy metal accumulation in soil and wheat grain, and health risk under drip irrigation with treated municipal wastewater. A field experiment was conducted according to a split block design with two treatments (fresh and wastewater) and three sub treatments (0, 15 and 30 cm depth of emitters) in four replicates in Esfahan, Iran. Soil samples were collected before planting (initial value) and after harvesting (final value) in each year. Elemental concentrations (Cu, Zn, Cd, Pb, Cr, and Ni) in soil and grain were determined using an atomic absorption spectrophotometer. A pollution load index (PLI) showed that there was not substantial buildup of heavy metals in the wastewater-irrigated soils compared to the freshwater-irrigated soils. Cu, Pb, Cr and Zn concentrations in wheat grain were within permissible EPA limits, but concentrations of Cr was above the safe limits of EPA. In addition, concentrations of Ni in wheat grain were several folds higher than EPA standards. A health risk index (HRI) which is usually adopted to assess the health risk to hazard materials in foods showed values higher than 1 for Cd and Cu, whereas children might also be exposed to health risk of Cd, Cu and Cr. Based on aforementioned results, it can be concluded that the depth of emitter in drip irrigation does not play a significant role in the accumulation of heavy metals from TWW in our sandy loam soil.

Today, modern irrigation systems are constructed at a very high cost to operate for optimal use of water and soil. Lack of appropriate technical, social and economic studies, caused high maintenance costs of these facilities during operation. Water resources have been polluted due to industrial development, increasing human population and non-compliance with environmental standards. Most of hydraulic structures are built in areas with poor water quality. Furthermore, engineering properties of fine-grained soils, especially the clay soils, depend on factors such as salinity of solute in the pore water. So that any change in salinity of solute leads to change in the physical and mechanical properties of soils, and consequently make damage to hydraulic structure. This study investigated the effect of water salinity on engineering properties of fine-grained soils. For this purpose, NaCl, with 5 different levels (0, 0.1, 0.2, 0.41 and 0.72 mol/L) was added to the soil and the mechanical properties of soil including compaction, shear parameters, Atterberg limits and consolidation parameters were investigated. The results showed that the addition of NaCl had made no significant changes to the maximum dry unit weight and optimum moisture content of the soil, but it reduced cohesion of soil and increased the internal friction angle .Also, Limit Liquid (LL) are decreased, but it had little effect on the Plastic Limit(PL) of soil.
 

The aim of this work was to study distribution of some heavy metals in different soil particle-size fractions and to assess their spatial distribution. The study was carried out in Kafe Moor (Kerman, Iran) where the Gol-Gohar Iron Mine is located. One hundred twenty composite soil samples were randomly collected and transferred to the laboratory in bags. After air-drying, the samples were fractionated into six classes including 2- 0.5, 0.5-0.25, 0.25-0.125, 0.125- 0.075, 0.075-0.05 and <0.05 mm. Elemental concentrations (Fe, Mn, Cu, Zn, Pb and Ni) were determined using acid digestion method (HNO₃, 4.0 N) and an atomic absorption spectrophotometer in each class. Ordinary Kriging technique was used for predicting spatial distribution of heavy metals. The results showed that content of metals in soil increased with decreasing particle size. The results also showed that the concentration of Fe, Mn, Cu, Zn, Pb and Ni in <0.05 mm size fraction were 2.13, 1.70, 4.79,2.43, 1.42, and 3.47 times higher than in 2-0.05 mm size fraction, respectively. In addition, mapping the concentrations of heavy metals with kiriging showed that metals pollution decreased with increasing distance from mines area.
 

Today, the growth of population, the excessive growth of cities and subsequently, the industries development in all parts of the planet are evident. Such development leads to the entrance of chemical martials with various compounds, particularly heavy metals, in aquatic ecosystems. In this study, the contamination of the sediments around the Mighan wetland basin with heavy metals such as lead, zinc, copper and nickel was investigated using CF indexes (contamination factor), IGeo geo-accumulation indexes, and IPOLL sediment contamination severity. The results indicated a high concentration of copper and nickel metals, in comparison to zinc and lead metals, in the studied area. Also, regarding the location of sampling stations and their proximity of the industries around the wetland, the comparison of the results related to the measured metal concentration and the sediment quality indices, indicated a high concentration of the pollutants under examination in the southern part of the wetland, thereby emphasizing the need to control the pollutants in the wetland.