JWSS - Journal of Water and Soil Science

Phytoremediation models are important to understand the processes governing phytoremediation and the management of contaminated soils. Little effort has been made for evaluating the potential of the phytoremediation of metals based on the mathematical models. Therefore, the purpose of this study was modeling the phytoremediation of the nickel-contaminated soils. For this purpose, a model was recommended for estimating the rate of the phytoremediation of nickel from the soil by means of relative transpiration reduction and concentration of nickel in the plant functions. To evaluate the model, soil was contaminated with different levels of nickel by nickel nitrate. Then, the pots were filled with contaminated soil and Basil (ocimum tenuiflirum L.) seeds were planted. To avoid the dry tension, the pots were weighed and irrigated to the point of field capacity (FC) at short time intervals (48 hours). The plants were harvested in four times. At each harvesting stage, the relative transpiration values and nickel concentration in the soil and plant samples were measured. The performance of the model was evaluated by statistical methods such as Maximum Error, Root Mean Square Error, Coefficient of Determination, Efficiency of Model and Coefficient of Residual Mass. Results demonstrated that in the case of nickel contamination in soil, changes in the relative transpiration of Basil can be measured by the two proposed models and the linear model (R2=0.94) has a better performance compared to the nonlinear one (R2=0.84). Also the model obtained from the combination of linear function and nickel's concentration in soil has a relatively good (R=0.7) fit with the measured values of the remediation rate of nickel in soil.

Phytoremediation is one of the cleanup methods of polluted soil that is possible accumulation of heavy metals in plant tissues, exclusion of these elements from contaminated soil. Therefore, to achievement the objective, this research was done in pot culture using completely randomized design at the University of Birjand in 2011. Two species Spinacia oleracea and Lepidium sativum were used to remove or reduce the concentration of Cadmium (Cd) and Chromium (Cr). In this study, different levels of Cadmium (CdCl2) concentrations including 5, 50, 100 mg kg-1 and also chromium (CrCl3) concentrations 50, 100, 150 mg kg-1 were used respectively and control as well for each species with three replications. Results indicated that the Cd and Cr concentration in shoot of Spinacia oleracea and Lepidium sativum significantly affected by their concentration in soil (p<0/01). Results revealed that increasing of Cd and Cr concentrations in soil, showed an increase concentration of both metal in shoot of Spinacia oleracea. increasing of Cd concentrations in soil, showed an increase concentration of it in shoot of Lepidium sativum but the concentration of Cr was less. Also, comparison of cadmium and chromium concentrations in shoot of Spinacia oleracea and Lepidium sativum showed that two species showed same behavior of Cd and different behavior Cr concentration. So the analysis of data showed that both of species are appropriate for absorption of Cd and Cr and phytoremediation technology as well. It can be concluded that in high soil Cr concentration for phytoremediation Lepidium sativum is not appropriate.

Evaluation of chemical and biological indicators of soil in different land uses could be helpful in sustainable range management, preventing degradation of soil quality trend. This study was conducted in Friedan in Isfahan province in 2010 to compare chemical and biological indicators in three land uses (rangeland, degraded dry land and dry land), during two growing seasons (May and September) in three slopes (0-10, 10-20, 20-30 %). Nitrogen, phosphorus, potassium, organic matter, cation exchange capacity and microbial soil respiration were measured. Results showed that all measured characteristics except potassium decreased over an increase in the slope. Maximum values of phosphorus, organic matters, cation exchange capacity and soil respiration were obtained in pasture (28.4 mg/kg, 0.62%, 20.38 cmol/kg, 33.2 mgC/day, respectively)but potassium maximum rate was seen in dry land form (406.8 mg/kg).The effect of season on all measured parameters was significant except for N, while the highest amounts of phosphorus, potassium, cation exchange capacity and soil respiration (28.7 mg/kg, 377.3 mg/kg, 19.6 cmol/kg and 25.9 mgC/day, respectively) were seen in May and the highest organic matter rate (0.68%)in September. The results of this study showed that an increase in the slope, poor range management, and the end of the growing season could be major factors degrading the soil quality indices and soil productivity.

Spatial estimation of evapotranspiration (ET) rates is essential for agriculture and water resources management. This study aimed to estimate ET v an ET estimation algorithm called Surface Energy Balance Algorithms for Land (SEBAL) and also by using TM June 2009 satellite data in Damaneh region of Isfahan province. To calculate the ET, all the energy balance components and related parameters including net radiation, surface albedo, incoming and emitting shortwave and longwave radiation, surface emissivity, soil heat flux, sensible heat flux, NDVI vegetation index, Leaf Area Index(LAI),  and surface temperature were extracted from the geometrically and radiometrically corrected TM images. Results showed that ET rate was about 7.2 mm day^-1 in agricultural areas, which was almost equal to 6.99 mm day^-1 extracted from the FAO Penman-Monteith method in the synoptic weather station of Daran. Results here indicate that the extraction of ET rate which is almost equal to plant water requirements from remote sensing data can be used in selecting appropriate plants for agriculture and rehabilitation purposes in extensive arid and semi-arid regions of Isfahan province where severe droughts and water shortage are major problems.

Water scarcity forced farmers to use wastewater as water source, without considering its effects on environment and resultant contamination of soils and plants especially with heavy metals. The objectives of this study are to evaluate the application effects of zeolite as soil amendments on the uptake of Cd by spinach (Spinach Oleares L.) irrigated with wastewater (containing 10 ppm Cd). Different levels amounts of zeoilte (0, 1% and 5% w/w) were added to the soil and the experiment was conducted as a completely randomized design in a green house with 3 replications. The results indicated that, the addition of zeolite 1% (w/w) in soil treated with wastewater reduced cadmium concentration in plant, and consequently the percentage of extractable Cd using DTPA was decreased. However, application of zeolite 5% (w/w) increased the soil salinity, and as a result increased Cd concentration in the plant but this increase was not statistically significant, comparing with control. Spinach biomass did not differ significantly under irrigation with wastewater, but the Cd available in wastewater caused a decrease in Spinach biomass yield.

This study investigated the effects of climate change on the evapotranspiration amount and water balance in the Zayandeh-Rud river basin. Two important weather stations; Isfahan and Chelgerd stations, located in the East and West of the basin respectively, were selected for investigation in this study. The combination of 15 GCM models were created based on the weighting method and three patterns of climate change including the ideal, medium and critical were defined. Using the proposed patterns, the effects of climate change on temperature and evapotranspiration in Isfahan station and precipitation in Chelgerd station were estimated under the A2 and B1 emissions scenarios. Two indices were considered to determine the sustainability of agricultural water consumption in the study area. Ratio of evapotranspiration in the East part of the basin to precipitation in the West part was defined as EPR index (Evapotranspiration-Precipitation Ratio), and the ratio of maximum agricultural water deficit to the amount of agriculture water need, was considered as maximum deficit index (MD). Results showed that the annual temperature would increase between 0.63-1.13°C in the eastern part of the basin. The west precipitation in the basin would reduce between 6.5-30% in the ideal to critical patterns. Summer season, showed the most amount of increase in the temperature, and winter season, showed the most amount of decrease in precipitation. The A2 emission scenario showed more temperature increase and more precipitation decrease in comparison with the B1 emission scenario and also indicated that the potential evapotranspiration would increase by 3.1 to 4.8% in the basin. The EPR index will increase between 13-52% and MD index will increase between 9-35% in Zayandeh-Rud river basin under different climate change patterns. The results revealed the imbalance between agricultural water use in eastern part and the precipitation in the western part of the basin. In other words, in these conditions, appropriate management strategies and planning should be implemented to ensure the sustainability of water resources in Zayandeh-Rud River Basin.

In this research, a comprehensive simulation model for water cycle and the nitrogen dynamics modeling including all the important processes involved in nitrogen transformations such as fertilizer dissolution, nitrification, denitrification, ammonium volatilization, mineralization, immobilization as well as all the important nitrogen transportation processes including nitrogen uptake by the plant, soil particles adsorption, upward flux, surface runoff losses and drain losses, was used for fertilizer management modeling in a sugarcane farmland in Imam Khomeini Agro-Industrial Company using a system dynamics approach. For evaluating the model the data collected from Imam Agro-Industrial Company equipped with a tile drainage system with shallow ground water and located in Khuzestan province, Iran, were used. The statistical analysis of the observed and simulated data showed that the RMSE for determining the accuracy of simulation of the nitrate and ammonium concentration in drainage water is 1.73 mg/L and 0.48 mg/L, respectively. The results indicated that there is good agreement between the observed and the simulated data. Nine scenarios of fertilization at different levels of urea fertilizer were modeled including one scenario of 400 kg/ha, two spilit scenarios of 350 kg/ha, two spilit scenarios of 325 kg/ha, two spilit scenarios of 300 kg/ha, one scenario of 280 kg/ha and one scenario of 210 kg/ha. Results of the modeling showed that the scenario of 210 kg/ha has the highest nitrogen use efficiency (52.3%) and the lowest nitrogen losses consisted of denitrification, ammonium volatilization and drainage losses (17.82, 7.16 and 92.59 kg/ha, respectively). The results revealed that increasing the consumption of urea fertilizer greater than 210 kg/ha increased the overall nitrogen losses and reduced the nitrogen use efficiency. Meanwhile, this model can be used for managing the fertilizer and controlling the nitrate and ammonium concentrations in the drainage water to prevent the environmental pollution. Also, the system dynamics approach was found as an effective technique for simulating the complex water-soil-plant-drainage system.

In agricultural development many factors such as weather conditions, soil, fertilizer, irrigation timing and amount are involved that are necessary to be considered by the plant growth simulation models. Therefore, in this study, the values of soil water content at different depths of soil profile, dry matter production and grain yield of winter wheat were simulated using AquaCrop and WSM models. The irrigation treatments were rain-fed, 0/5, 0/8, 1 and 1/2 times of full irrigation conducted in Agricultral College of Shiraz University during 2009-2010 and 2010-2011. The models were calibrated using measured data in the first year of experiment and validated by the second year data. The accuracy of soil water simulation was used to refer to the accuracy of simulated evapotranspiration. The accuracy of soil water content at different layers of root depth in the validation period was good for the WSM model (Normalized Root Mean Squer Error, NRMSE= 0/14). But the AquaCrop model showed less accuracy for soil water content (NRMSE=0/26). However, the values of predicted and measured crop evapotranspiration were close together at full irrigation treatment, the accuracy of AquaCop predictions was decreased with inceasing water stress. WSM model has had a good estimation of the dry matter and grain yield simulation with NRMSE of 0/15 and 0/18, respectively. However, they were simulated with less accuracy in the AquaCrop model with NRMSE of 0/19 and 0/39.

Accurate estimation of ET₀ in any region is very important. The aim of this study is to compare and calibrate the 20 empirical methods of estimating evapotranspiration (ET₀) based on three categories in monthly timescale at the Urmia Lake watershed. These categories are: 1) temperature-based models (Hargreaves (HG), Thornthwaite (TW), Blaney-Criddle (BC), Linacre (Lin)), 2) radiation-based model (the Doorenbos-Pruitt (DP), Priestly-Taylor (PT), Makkink (Mak), Jensen-Haise (JH), Turc (T), Abtew (A), McGuinness-Bordne (MB)) and 3) mass transfer-based model (Meyer (M), Dalton (D), Rohwer (R), Penman (P), Brockamp-Wenner (BW), Mahringer (Ma), Trabert (Tr), WMO and Albrecht (AL)). For this purpose, the information of 10 synoptic meteorological stations during the period of 1986-2010 was used. Results from the above mentioned methods were compared with the output of the FAO Penman-Monteith (PMF-56) method. Performance of the methods evaluated using the R², RMSE, MBE and MAE statistics. The best and worst methods of each category were determined for the study area. The best methods of each category were calibrated for the area under study. Results indicated that there is a significant difference between the results of selected methods of each category and the PMF-56 method. Performance of the selected methods remarkably increased after calibration. Among the temperature-based group, the HG method having the median R² value of 0.9597 was recognized as the best method. After calibration the medians of RMSE, MBE, and MAE were 72.09, 3.14 and 10.70 mm/ month, respectively. After HG, the Lin and BC found to be the best second and third methods in the study area. The TW showed Large error, therefore, it was not a suitable method for ET₀ estimation in study area. Among the radiation-based group, the DP model was selected as the best method in the study area. Furthermore, the median of R² values was 0.982. In this method, the medians of RMSE, MBE and MAE after calibration were 7.89. -0.62 and 6.03 mm/month, respectively. Following DP, the PT method was recognized as the 2^nd best one. The methods namely M, JH, T, A and MB were put in the 3^rd to seventh rank of the radiation category. Finally, among the mass transfer-based group, having R²=0.8945, the Meyer method was selected as the best method of this group for the study area. In the mentioned method (after calibration) the medians of RMSE, MBE, and MAE were 21.8, -8.7 and 17.3 mm per month, respectively. From mass transfer based group, the D method was found as the second best method in the study area. The methods namely R, P, BW, Ma, Tr, WMO and A were ranked 3^rd to 7^th, respectively. In general, the performance of radiation based methods was superior than others in Urmia Lake basin. Temperature based methods and mass transfer based methods were ranked second and third, respectively. Further examination of the performance resulted in the following rank of accuracy as compared with the PMF-56: DP (Radiation based), HG (Temperature based) and Meyer (Mass transfer). In general, it can be concluded that after calibration the DP method is suitable to estimate reference crop evapotranspiration among 20 selected methods in the Urmia Lake basin.

Morning glory spillway is one of the spillways and used when it is not possible to use any other spillways. With the onset of submergence and flow loss, and intensification of circulation and vortexes, spillway performance decreases severely. With decreasing discharge coefficient, the height of water in the reservoir increases and the risk of dam damage, caused by the lack of spillway ability of great flow discharge, increases. Anti-vortex piers are used to solve this problem. The increase of the submergence threshold can provide ability of greater flow discharging, without spillway submergence and its negative consequences. Anti-vortex piers, in addition to correcting circulation and vortexes, may also be effective in increasing the submergence threshold. To investigate this possibility, 110 experiments were performed with the physical model on spillways with square and circular inlet section in different modes and number of anti-vortex piers. Results show that increasing number of Anti-vortex piers increases the submergence threshold and spillway can discharge greater inflow and height of water without being submerged. The effect of the overflow of the circle shape, because currents and vortexes spinning in a circle overflow is higher than square spillway. Also the maximum discharge coefficient was observed when 4 vortex breakers were installed at the angle of 90 degrees.

The use of organic matter such as urban sewage sludge may help sustainable soil fertility via improving the physical, chemical and biological soil characteristics. The main purpose of this study was to determine the effect of urban sewage sludge on chemical properties, soil basal respiration and microbial biomass carbon in a calcareous soil with silty clay loam texture. Therefore, three levels of water repellency (zero, weak and strong) were artificially created in a silty clay loam soil by adding urban sewage sludge (S0=0:100; S50=50:50 and S80=80:20 sludge weight: soil ratio). Water repellency was determined by water drop penetration time (WDPT) method. Also some chemical properties such as soil acidity (pH) and Electrical Conductivity (EC), Soil Organic Carbon (OC), soluble sodium (Na⁺) and soluble potassium (K⁺) were measured. The samples were incubated at 23-25 ºC for 30 days and their moisture was maintained at 70-80 % under field capacity and soil basal respiration and microbial biomass carbon of incubation period were evaluated. The results showed that the effect of urban sewage sludge on chemical properties was significant (P ≤0.0001). The application of urban sewage sludge led to significant increase in basal respiration (16 and 27 times) and microbial biomass carbon (15.2 and 26.5 times) in the water repellency soils (S50 and S80) compared to control soil. The observed positive effect of sewage sludge might be due to a high content of organic carbon and nutrients in urban sewage sludge and decrease in the labile organic matter and nutrients during incubation period.
 
 

This study was designed to investigate the possibility of using the surface energy balance algorithm for land (SEBAL) and mapping evapotranspiration at high resolution with internalized calibration (METRIC) models to estimate evapotranspiration (ET) in Shahrekord  plain (Chaharmahal va Bakhtiari province, Iran). Two sets of Landsat ETM+ data dated June 30^th and August 21^st, 1999 were provided to estimate and compare reference evapotranspiration (alfalfa) at regional scale using Landsat ETM+ data to ET estimations by five mathematical methods (experimental and combined) known as standardized Penman-Monteith by American Society of Civil Engineers (ASCE-stPM), Penman-Monteith (F56PM), Blaney-Cridle (F24BC), Hargreaves-Samani (HS) and evaporation pan (F24P). Results showed that ET at cold anchor pixel for SEBAL were 6.97 and 6.77 millimeters per day and for METRIC were 10.27 and 9.31 millimeters per day, on days when the satellite passed over. Hargreaves-Samani ET values, as the suitable mathematical model for the studied area, were 8.0 and 7.5 millimeters per day, respectively, on two satellite passes. Results showed that, in the first pass all statistical indices for SEBAL were less than the second pass, maybe due to higher air temperature and wind speed. On the other way, statistical indices in METRIC on the alternate pass, however, showed higher values over the corresponding values in SEBAL. ET values on two satellite passes for anchor pixels were 5.65 and 5.93 mm/day in SEBAL, and 5.22 and 6.65 mm/day in METRIC, respectively. ET values on the same days of satellite overpass for Hargreaves – Samani (HS) were 8.0 and 7.5 mm/day. Consequently, based on the results, both RS-ET models were comparable to empirical models such as (HS). Generally, the results showed that SEBAL had higher accuracy than METRIC, presumably due to lack of accurate weather data (hourly data), so SEBAL is recommended in similar conditions. Generally, the results showed that SEBAL had higher accuracy in comparison to HS and lysimeters data than METRIC, so SEBAL is recommended in similar conditions.