JWSS - Journal of Water and Soil Science

Heavy metals in street dust, as one of the most important environmental consequences of human activities, have attracted many researchers' attention in recent years due to their toxicity and sustainability. Therefore, this study aimed to investigate the hazard of heavy metals (lead, zinc, copper, chrome, cadmium, nickel, vanadium, arsenic and cobalt) on human health in street dust in Dezful. To this end, 30 dust samples collected from sidewalks of main streets of Dezful were analyzed by Atomic Absorption (AAS). The level of heavy metals pollution was estimated based on the pollution index and Nemro Integrated Pollution Index. Moreover, the spatial pattern of the concentrations of metals in street dust was prepared in GIS. The average concentrations of heavy metals in Pb, Zn, Cu, Cr, Cd, Ni, V, As and Co were 54.2, 223.6, 50.6, 44.4, 0.4, 45.8, 37.8, 3.3 and 7.6 (mg/kg), respectively. The average concentration of all heavy metals except As, V and Co in the samples of dust in the city of Dezful was several times higher than that of the background one. Based on the average EF and PI in the target area, heavy metals of Zn and Pb have high contamination. Based on the evaluation of NIPI, 100% of samples have high degree of contamination. The results showed that the source of pollution of the studied metals such as urban transport and burning of fossil fuels was anthropogenic.

In recent decades, land use changes have been one of the most important environmental issues worldwide. This study was carried out to investigate and analyse land use changes in dust sources of south and south-east Ahwaz and surrounding lands using remote sensing technique. Firstly, based on the standard precipitation index (SPI), the years 1986, 2002 and 2016 were selected as years with near normal situation. In the next step, land use maps of the study area were extracted using a Landsat satellite images and supervised classification methods. MNDWI index was used to increase the accuracy of image classification. In order to evaluate the efficiency of each method, the overall accuracy and kappa coefficient were used. Finally, to investigate land use change a post-classification comparison method was employed. According to research findings, in the first period (1986-2002), the area of vegetation, wet land with vegetation and water bodies have increased by 419%, 219% and 40.7%, respectively, in contrast, the area of barren and poor range has reduced by 36.6%. One of the major causes of these changes is human factors such as population growth and climate variables such as proper amounts of precipitation. In the second period (2002-2016), the area of wet land with vegetation, water bodies and vegetation has been decreased by 94%, 49.3% and 46.7%, respectively; in contrast, barren and poor range land has been increased by 45.4%. Recent droughts increase the temperature and incorrect and non-principled management of water resources has been effective in reducing green cover and water bodies and increasing in bare land. The results show that, during the three decades, built-up land has been increased by 157%, while River bed has decreased by 28.8%. These results indicate a total degradation in the region due to climate change and human activities.

Long- term exposure to street dust because of the potential toxicity of heavy metals can cause harmful effects on the human's health by inhalation, ingestion and dermal contact. In this study, 25 dust samples were collected from the sidewalks of the main streets of Ilam and analyzed by inductively coupled spectroscopy (ICP- OES) method. The mean concentration of the studied metals was: Pb (58.80), Zn (213.24), Cu (63.12), Cr (45.84), Cd (0.37), Ni (43.73) V (30.92) and As (5.00) (mg / kg). Based on the average value of the potential ecological risk (Er), the heavy metals of Pb, Zn, Cu, Cr, Ni and V had a low ecological risk and Cd showed a moderate one. The highest non- carcinogenic risk (HQ) in children and adults was related to As through ingestion and Cr through the dermal contact pathway; on the other hand, the lowest amount was due to the Cd via the inhalation. Cumulative non- carcinogenic hazard (HI) of all heavy metals in the street dust have been found to be higher for children rather than adults. In both age groups, Cr and Pb had the highest and lowest risk of carcinogenicity (RI), respectively. The obtained results, therefore, indicate that the main source of heavy metals in the study area is anthropogenic sources such as traffic, industrial facilities and fossil fuels burning.

One of the reasons for soil salinization is the accumulation of salts in it by transmission through water and wind. In order to investigate the phenomenon of transfer of salts with dust in the arid regions of the north of Yazd- Ardakan plain, field samples were taken using 32 MDCO sediments traps with uniform dispersion in an area of 20,000 hectares at some stage in 4 seasons of 2017. After washing the sediment collector with a liter of distilled water in the field and transferring the samples to the laboratory, for the quantitative analysis of saline dust, similar to measuring the Water Electrical Conductivity (EC_w), the Total Soluble Solids (TDS) were additionally measured through evaporation technique. The form and distribution of the dust particle size were additionally investigated using a Scanning Electron Microscope (SEM) tool. Within the qualitative examine of salts, effective cations and anions in salinity including Na⁺, K⁺, Ca⁺⁺, Mg⁺⁺, C1^-, HCO^-₃ and SO^-₄ were measured The results confirmed that, in general, the fallout was 11.1 g.m^-2 of soluble material with dust particles (13.28%) in the course of only 12 months. Particles with a diameter of 5 to 10 microns were the most frequent. Considering the high correlation between C1^- and Na⁺ in the spring, autumn and winter, due to the high correlation between Ca⁺⁺ and SO^-₄ in summer dust, sodium chloride (NaCl) and gypsum (CaSO₄) 2H₂O)), the most abundant composition of dust- containing salts could be expected in these seasons. By determining the percentage of solutes in the fallout dust, it was observed that the impact of the amount of the deposited salt from dust was slight and insignificant in the short time period; with the assumption of no change in the rate of subsidence, it was anticipated that it would explain the poor salinity in non- saline mass soils for up to 10 cm in 72 years. In general, the capability of airborne salt in increasing the soil salinity in the study area can be in long- term periods. Therefore, it is recommended to investigate other environmental effects of this phenomenon in order to identify its hazards.

The purpose of this study was to analyze the temporal variations of dust phenomenon and its relationship with the climatic elements in Yazd city, located near one of the critical centers of dust production in the center of Iran. For this purpose, the Dust Storm Index was first calculated. After the standardization of precipitation, temperature, maximum wind speed, average wind speed, relative humidity and, dust storm index, the co-linearity effect between variables was calculated by using inflation variance factor. Then, several regression models were prepared based on the optimal Ridge parameter. The performance of the models was evaluated based on the determination coefficient, F value and Root Mean Square Error. Finally, by using the most accurate model, the impact of climate parameters on the dust events changes was determined. The results showed that the incidence of dust events in the spring was more than the rest of the year. Based on the optimal model (Model 12), it was found that the main factor influencing the dust storm index variations in different seasons was the surface winds speed. It was also shown that 39%, 25%, 46% and 31% of dust storm index changes in winter, spring, summer, and autumn were due to the interaction of the five climatic parameters studied in this study.

The occurrence of wind erosion and the spread of dust particles can be regarded as one of the most important and threatening environmental factors. Climate change and the frequency of droughts have played an important role in exacerbating or weakening these events. The primary objective of the present study was to investigate the trend of changes in four important climatic elements (precipitation, temperature, wind speed and relative humidity) and dust storm index (DSI) in Qazvin city using the Mann-Kendall pre-whitened test and to determine the relationship between them based on the multiple linear regression method. Assessment of the meteorological drought status based on two standardized precipitation index and standardized precipitation, as well as the evapotranspiration index and analysis of their effect on activity level of dust events, was the other objective of this study in the study area. For this purpose, after preparing and processing the climatic data and calculating the dust storm index, the trend of changes and the relationship between climatic parameters and dust events were investigated. The results showed that the changes of trend in the annual precipitation and relative humidity in Qazvin city were increasing, while the trend of annual changes in the wind speed and the mean air temperature was a decreasing one. Investigation of the monthly changes in the dust events also showed that there was a sharp decrease in the occurrence of wind erosion and the spread of domestic dust particles only in July. On a seasonal scale, with the exception of winter that has been reported without trends, in other seasons, the intensity of these events was significantly reduced. The effect of the meteorological drought on wind erosion was estimated to be 11% at the confidence level of 99%. In general, these findings indicate a decreasing trend of land degradation and desertification caused by wind erosion in Qazvin.

Dusts contain heavy metals such as Pb, Zn, Cu, Cr, Cd and As that can threat human's health and environment. Therefore, the spatial distribution of heavy metals concentration and soil pollution monitoring and environmental quality protection seem to be essential. To assess heavy metals pollution level in Ahvaz street dust, 115 street dust samples were collected from main pedestrians. The samples were analyzed by Atomic Absorption (AAS). The pollution level was estimated based on the geo-accumulation index (I_geo), contamination factor (CF) and the enrichment factor (EF). The average concentration values of Pb, Zn, Cu, Cr, Cd and As were found to be 197.6, 150.1, 179.7, 101, 5.6 and 14.2 mg/kg, respectively. Pearson's correlation coefficient also indicated that Pb, Zn, Cu and Cr had a significant correlation showing similar possible anthropogenic sources. On the other hand, Cd and As showed a lower correlation with other metals, indicating that they belonged to the geogenic sources. The results of contamination factor, enrichment factor and geo-accumulation index also indicated that Pb, Zn, Cu and Cd had a high contamination level.  Also, areas with high population density, heavy traffic volume, and industrial activities exhibited a high level of heavy metals contamination.

Dust deposited on the leaves of trees can be effectively used as the monitors of polycyclic aromatic hydrocarbons (PAHs). The dust deposited on the leaves can be used as an appropriate index for evaluating PAHs in the atmosphere. This research was conducted to determine the origin and health risk assessment of PAHs accumulated on the leaves of trees in the city of Ahvaz. For this purpose, samples were taken at leaves on 10 points with different land uses including industrial, recreational, high-traffic and residential ones. After preparation, to determine the type and concentration of PAHs, the compounds were analyzed by GC-MS. The results showed that 15 types of PAHs had been identified from 16 important compounds identified by EPA in the dust samples. The concentration of compounds was the range of 3.3-110 microgram per kilogram. The maximum and minimum of PAHs carcinogenic in particles trapped on leaves were in the Kut-Abdolah with 530 ppb and Shahrvand Park Station with 5.13 ppb, respectively. Also, the average relative of LMW/HMW in the aromatics contained in the deposition of particles on trees was 0.5; further the analysis of the main components of aromatic hydrocarbons (PAHs) showed that there was  no specific source for these compounds in Ahvaz, and these compounds could be from fossil fuels, urban traffic, natural gas,   generally showing a pyrogenic origin.

In this study, spatial-temporal variation of dust deposition rate in the western and eastern half of Tehran and its climatic parameters affecting were studied. At 34 points in the city, dust samples were collected by glass traps from the roof, for twelve months, and the climatic data were obtained and analyzed from relevant organizations. The highest deposition rate is in the western half of the city and its total amount has varied from 54.52 to 121.21 g/m²/y. In both halves of the city, summer has the highest dust deposition rate and its central areas have the highest amount. There were significant positive correlations between dust deposition rate with temperature and medium wind speed, and there were significant negative correlations between dust deposition rate with rainfall and relative humidity in all months, which justifies the high dust deposition rate in the dry seasons of the year. The results of stepwise regression showed that rainfall was the most important factor affecting the dust deposition rate in both halves of the city. The city of Tehran has a special geographical location the presence of mountains like a barrier has prevented dust from leaving the city and the air inlet corridor of Tehran has faced problems due to the expansion of building construction and high-rise building. Other factors affecting the rate of dust deposition in this city, in addition to the distance from the main source of dust production, atmospheric parameters can be mentioned the existence of barren lands around the city, vegetation cover, construction operations, and traffic.

The southern regions of Kerman Province have repeatedly encountered dust storms. Therefore, the objective of this study was to identify dust sources using effective parameters such as vegetation cover, land surface temperature, soil moisture, soil texture, and slope as well as to detect dust storms originating from these regions based on 31 MODIS images in 2016 and SRTM data. After normalizing parameters, the dust source map was prepared by fuzzy logic and assessed with an error matrix and available dust source map. Results showed that 30.5% of the study area was classified as a low source of dust, 39.55% as moderate, and 29.85% as severe-very severe. The overall accuracy of the produced map was about 70% and the producer and user accuracy of the severe-very severe class was more than 87%. The detection of dust storms originated from the identified dust sources also confirmed a crisis situation in the region. Due to the repeatability and continuity of obtained dust source map at pixel scale, it can be used to update available dust source maps and manage dust crisis in the region, properly.

Street dust is mainly affected by the pollution of polycyclic aromatic hydrocarbons (PAHs). PAHs are a group of organic pollutants consisting of two or more benzene rings and are mainly produced during incomplete combustion. PAHs have attracted widespread attention due to their high carcinogenic and mutagenic properties in humans. Therefore, the purpose of this study was to investigate the sources and extent of the impact of these compounds on human health and the environment. To achieve this goal, 30 dust samples were collected from the sidewalks of the main streets of Dezful and the concentration of PAHs was determined by gas chromatography-mass spectrometry (GC-MS). The total concentration of PAHs in street dust of Dezful varied from 562.85 to 51447.10 μg / kg. The ratio of carcinogenic compounds to total PAHs was in the range between 0.73 to 0.91. Low molecular weight and high molecular weight PAHs accounted for 12% and 88% of total PAHs, respectively. The most important sources of PAHs in Dezful are the combustion of fossil fuels and petroleum products and emissions from vehicles and traffic. Moreover, incremental lifetime cancer risk (ILCR) in pathways ingestion in children was higher than in adults, but the ILCR in pathways dermal contact and inhalation in adults was higher than in children. The total cancer risk (CR) for children (5.77×10^-3) was higher than adults (5.56×10^-3), which shows the high potential for CR in the study area.

Individuals spend a lot of time indoors, thus they can generally be exposed to polycyclic aromatic hydrocarbons (PAHs) as a teratogen, mutagen, and carcinogen pollutants with the potential for environmental and also human health risks. Therefore, the current study was performed to analyze PAHs in household dust samples of the city of Khorramabad, Iran in 2019. A total of 50 indoor dust samples were collected from 10 sampling sites. After the extraction of analytes, the gas chromatography/mass spectrometry (GC–MS) method was used to determine PAHs in the studied samples. All statistical analyses were performed by SPSS software. The results showed that 16 priority PAHs were detected in the samples with the minimum, maximum, and mean values of 14.0, 23.3, and 19.2 µg/kg. Also, based on the results the mean contents of detected PAHs were lower than the maximum permissible concentration (MPC) established by MHWS and Iran DOE. In conclusion, due to exposure risks of PAHs, regular and periodic analysis of these pollutants in different environmental samples including soil, sediment, dust, particulate matter, air, water, and tissues of living organisms for environmental and human health maintenance is recommended.

The water footprint is an analytical tool that offers a better and more comprehensive view of how consumers or producers engage with freshwater consumption. Given the water crisis in the country, particularly in Isfahan Province, this study aims to estimate and compare the direct and indirect water footprints of several large industries, including Mobarakeh Steel, Iron Smelting, Refinery, and Power Plant, located in the Zayandeh River Basin. After identifying the desired objectives and study areas, as well as confirming the availability of the required data, information was gathered from the selected industries. Two methods were then utilized to aggregate the entire chain and the sum of steps to calculate the water footprint in the researched industries. According to the calculations, the direct and indirect water footprint in the iron smelting industry amounts to 196.9 cubic meters per ton of steel annually, of which 4.026 cubic meters is attributed to direct consumption and 17.5 cubic meters to indirect consumption. In a refinery, 18.80 liters of water are consumed directly and indirectly to produce one barrel of product (gasoline or diesel). Additionally, the direct and indirect water footprint of the Islamabad power plant is 1,198,320 cubic meters per terajoule, equating to 4.31 liters per kilowatt hour. The results of this study indicate that the indirect water footprint in the analyzed industries is equal to or exceeds direct water consumption, with both being equally significant. Finally, it is important to note that the results of this study can support decision-makers and policymakers in the industry, including those in the iron and steel, refinery, and power plant sectors, in managing their water footprint.