Showing 32 results for Cadmium
M. Pirzadeh, M. Afyuni, A. H. Khoshgoftarmanesh,
Volume 16, Issue 60 (7-2012)
Abstract
This study was carried out to investigate zinc (Zn) and cadmium (Cd) concentration in paddy soil and rice grain produced in central and southwest Iran in relation to soil and plant factors, and their intake in peoples diet was also assessed. Rice crops and associated surface soils (0-30 cm) were collected from 136 fields in Isfahan, Fars and Khuzestan provinces. The result, showed the DTPA-Zn concentration in more than 50% of paddy soils was less than its critical deficiency concentration (2 mg kg-1). The grain Zn concentration in more than 54% of the rice samples was less than 20 mg kg-1. The measured Cd concentrations in paddy soils and edible part of rice exceeded the world health organization (WHO) value in more than 12% of the samples. By considering the average daily rice consumption of 110 g per capita, the Zn intake from rice consumption was estimated about 10% needed for female and male adult. Diet intake analysis did not indicate any excessive dietary intake of Cd when Cd mean of concentrations in rice grain was 0.04 mg/kg, but based on the results of risk analysis, it is more than safely level for contaminated rice.
R. Hamzenejad Taghlidabad, H. Khodaverdiloo, S. Rezapour, Sh. Manafi,
Volume 16, Issue 60 (7-2012)
Abstract
Soil contamination with heavy metals, including Cd and Pb, is of serious concern. The aim of this study was to investigate the efficiency of Atriplex verucifera, Salicornia europaea and Chenopodium album for simultaneous remediation of soil exchangeable sodium percentage and Cd and Pb contamination in two soils with different properties. Two soils, including a saline-sodic-calcareous (S1) and calcareous (S2) soil, were selected. Different concentrations of Pb and Cd were then added to the soils. The contaminated soils were incubated under a wetting-drying cycle for nearly seven months. The plants, seeds were grown in pots containing different treatments of polluted soils and in control treatment (no Cd and Pb contaminations). The plant yields and concentrations of Pb, Cd and Na in the soil and plant samples were measured. A considerable accumulation of soil Cd by Salicornia and Pb accumulation by Atriplex and Salicornia was observed under unsuitable conditions of the saline-sodic soil, whereas Atriplex and Chenopodium had high capability for Cd in the soil S2. Also these plants caused the reduction of ESP in soil S1. The results revealed that these plants could be used for remediation of Pb and Cd contaminated soils. In this study, Salicornia with lower rate of yield reduction had the highest tolerance to Cd-stress. Understanding the complex plant and soil (salinity-sodicity and soil metal concentration) factors controlling the metals concentrations in the plants will help to design phytoextraction technology for arid, salt-affected regions.
H. Alinezhad Jahromi, A. Mohammadkhani, M. H. Salehi,
Volume 16, Issue 60 (7-2012)
Abstract
Nowadays, due to drought and water shortage, use of unconventional waters, particularly sewage, has become usual in agriculture whereas they often contain heavy metals. The present study was employed to evaluate the effect of urban wastewater of Shahrekord on growth, yield and accumulation of heavy metals (lead and cadmium) in balm (Melissa officinalis) as a medicinal plant with five treatments (0, 25, 50, 75 and 100 percent wastewater) and three replications in a completely randomized experimental design. The results showed that the highest shoot length, stem diameter and stem number, number of leaves and tillers are achieved in the treatment of 100 percent. The wet and dry weight of shoots and roots was highest in 100 % of wastewater. Oil percentage of the leaves was also the highest amount (1.23 %) in 100 % of wastewater. Accumulation of lead in roots and aerial parts and its transmission factor was not significant for the treatments. However, the highest concentration of lead in root (0.057 mg/kg) and shoots (0.013 mg/kg) was observed in 100 % of wastewater and the lowest one was related to zero percent of wastewater treatment. The lead concentration was less than the critical limit for all the treatments. The amount of cadmium was undetectable in all the plant samples. The results of this study demonstrated that urban wastewater of Shahrekord, in addition to providing water, increases plant growth and essential oil.
S. Jafari, Z. Iranshahi , Gh. Fathi, S. A. Syadat,
Volume 16, Issue 61 (10-2012)
Abstract
Cadmium is a toxic element in plant nutrition and is considered as a contaminant of food and feed. A greenhouse experiment was carried out to examine the effects of combined application of cadmium and zinc on responses of wheat on a clay loam soil texture. This experiment was designed in a factorial experiment with randomized complete block design (RCBD) and four replicates per treatment. Three levels of cadmium (Cd 0, Cd 50 and Cd 100 mg kg-1) and three levels of zinc (Zn 0, Zn 50 and Zn 100 mg kg-1) were added to the pot in factorial(9 treatments), and then Chamran seed variety of wheat (triticum aestivum L.) was planted in each pot. The statistical analyses showed that Cd application significantly (P0.01) decreased grain, straw, and total yield, but Zn application increased these parameters significantly (P0.01). Application of Cd separately decreased the grain yield by 61.5 while application of Zn separately increased the grain yield by 36.9. Cd application increased the Cd concentration and uptake by grain and straw as well as total uptake but by increasing Zn application, Cd uptake was decreased by wheat. Cd concentration was higher in straw than that grain, but Zn showed a different trend. Decreasing Zn applications decreased total uptake of Cd from 42.9 in Zn0 to 7.8 mg kg-1 in Zn100 treatment. Although this soil was very calcareous, this characteristic did not control Cd absorbtion.
A. Madani, A. Lakzian, Gh. Haghnia, R. Khorasani ,
Volume 17, Issue 63 (6-2013)
Abstract
Mycorrhizal fungus colonization of roots may modify plant metal acquisition. In order to study the role of external hyphae of mycorrhizal fungi in metals transferring, the root and hyphal growth zone were separated by 30 µm nylon meshes. Plants were inoculated with G. mosseae and G. intraradices and grown in the root compartment. Six combinations of metals (400 mg of Zn, 25 mg of Cd, 400 mg of Zn + 25 mg of Cd, 50 mg P, 50 mg of P+ 400 mg of Zn + 25 mg of Cd, and no metal kg-1 soil sample) were added to the hyphal compartments. This experiment was carried out as a completely randomized design (CRD) with factorial arrangement in three replications. The results showed that dry shoot weight and phosphorus concentration in mycorrhizal treatments increased significantly compared with non mycorrhizal treatments. of the two fungal species, G. mosseae had more effect on phosphorus concentration in white clover plant. AM fungi increased the Zn concentration in shoot and root of white clover. AM fungi also significantly increased cadmium concentration in root of mycorrhizal treatments compared to non mycorrhizal plants. of the two fungal species, G. intraradices accumulated more cadmium in clover roots. ALL in all the results demonstrated that AM fungi increased phosphorus and Zn transferring to the shoots while cadmium transferring was decreased by stabilizing in the roots.
L. Divband, S. Boroomand Nasab, M. Behzad, J. Abedi Koupai,
Volume 17, Issue 65 (12-2013)
Abstract
Heavy metals in water resources are one of the most important environmental problems in most of countries. Up to now, various methods for removing these metals including using low price materials have been used. In this study, two new absorbents (zizyphus spinachristi leaf and its fly ash) were studied for adsorption of cadmium from aqueous solutions using batch experiments. The effect of contact time, pH, and amount of adsorbent on adsorption efficiency was evaluated and the best kinetic and isotherm model was determined. Results showed that optimal absorption of pH was 5 and 6 for zizyphus spinachristi leaf and its fly ash, respectively. The equilibrium time was 45 min for zizyphus spinachristi leaf and 30 min for ash. Adsorption efficiency was increased by increasing the adsorbent dose. By comparing the parameters of isotherm models, it was observed that the cadmium adsorption capacity of fly ash (4.27 mg/gr) was higher than that of zizyphus spinachristi (3.91 mg/gr).
A. Mohammadi, M. Chorom, N.hosseini Zare, H. Amerikhah, A. Ramazan Poor,
Volume 17, Issue 65 (12-2013)
Abstract
The purpose of this study was to investigate cadmium adsorption through Freundlich and Langmuir equations in sediments of Karun River in three hydrometric stations (5th Ahvaz Bridge, Darkhovin and Khorramshahr) in the low-water and high-water seasons. Fitting of data from experiments on cadmium absorption to Freundlich and Langmuir equation showed they are compatible. According to the conducted experiments, there was a significant difference at 0.01 levels between b coefficient of Langmuir equation with the organic matter percentage and the clay content in both Low and high water seasons, while there was no significant difference between k coefficient of Langmuir equation with the organic matter percentage and the clay content for the two seasons. The results also suggested that there is a significant relationship between Kf of Freundlich equation with the organic matter percentage and clay content, at significant levels of 0.05 and 0.01 for the organic matter percentage and the clay content, respectively. Comparison of the means of low and high water seasons revealed that there is no significant relationship between Langmuir coefficients, whereas in Freundlich equation, a significant difference at 0.01 level was observed between kf coefficients. Generally, the obtained results indicated that cadmium adsorption by sediments in low-water season is higher than high-water season. Also, cadmium adsorption by the 5th Ahvaz Bridge sediments due to the sandy texture was less than those adsorbed by both Darkhovin and Khorramshahr sediments.
T. S. Taleghani , H. Khademi, M. Afyuni ,
Volume 18, Issue 67 (6-2014)
Abstract
Stabilizing heavy metals in polluted soils is a method to prevent them from entering plants. Clay minerals are considered good sorbents for heavy metals due to their low cost, high abundance, easy manipulation and harmlessness to the environment. The objective of this study was to investigate the potential of clay deposits containing smectites and palygorskite to sorb cadmium and to reduce its movement into canola. Two selected deposits are located in the Isfahan Province. Physical and chemical characteristics of clay deposits were determined. The clay fraction was then separated from each deposit sample. This study showed that palygorskite was the dominant clay mineral in deposit sample 1 and smectites in deposit sample 2. These clays were then used as an amendment to plant growth medium. Pot experiment was carried out with canola (Brassica napus) as a test plant with 3 replicates. Treatments included three growth media: smectite + quartz sand, palygorskite + quartz sand and pure quartz sand (control treatment) under 3 Cd concentrations: 0, 2.5 and 7.5 ppm. Results obtained from the pot experiment indicated that deposits containing smectite and palygorskite were very useful in stabilizing cadmium in polluted soils and could prevent Cd from entering plant. Smectite clay mineral could retain a higher quantity of cadmium as compared to palygorskite. Plants in pots amended with smectite had a higher growth rate as compared to those in control and palygorskite amended pots. Cadmium accumulation in plant roots was much higher than that in shoot. Furthermore, the higher Cd concentration in growth media resulted in the higher amount of Cd uptake by the plant.
A. Mohammadi, M. A. Bahmanyar,
Volume 18, Issue 68 (9-2014)
Abstract
In order to investigate the cumulative effect of three-year application of municipal solid waste compost (C) and the compost accompanied with chemical fertilizer (CF) on the concentrations of some heavy metals in various organs of rice plant, a field experiment with completely randomized design in three replications was performed in 2009. Treatments were as follows: Control (without C and CF), CF (100 kg urea, 100 kg super phosphate and 100 kg potassium sulphate per ha), 15, 30 and 45 tons of C without CF, 15, 30 and 45 tons of C with 25%, 50% and 75% CF. Results showed that application of compost in three years would increase the amounts of Ni, Pb, Cd and Cr in different organs of rice plant. Also, application of C accompanied with CF increased the amount of Ni, Pb, Cd and Cr in various organs of rice compared to C. The highest concentration of nickel and lead (9.1 and 7.8 mg.kg-1 respectively) were obtained in grains in 45 ton C + 50% CF per ha treatment. Meanwhile, the maximum content of cadmium in grain (1.6 mg.kg-1) in 30 ton C + 75% CF ha-1treatment, and the highest amount of chromium in grain (1.8 mg.kg-1 ) resulted from 30 ton + 25% CF ha-1treatment.
A. Hassanpour, M. Zahedi, A. H. Khoshgoftarmanesh,
Volume 18, Issue 68 (9-2014)
Abstract
In a pot experiment, the effect of soybeans, mung beans and beans on the corn and sunflowers in a cadmium contaminated soil was studied in a completely randomized design with three replications. The treatments consisted of intercropping of corn and mung bean corn and beans, corn and soybean, sunflower and mung bean, sunflower and beans, sunflower and soybean monoculture of corn, and monoculture of sunflower. There were significant effects of cocropping of companion crops on shoot dry weigh, the concentration of cadmium and zinc and the chlorophyll content of corn and sunflower. In this study the shoot weight of corn grown with bean and soybean and that of sunflower grown with bean plants was decreased as compared to the related monocultures. The concentration of cadmium was increased in the corn grown with soybean or mungbean and in sunflower grown with soybean. Co- cropping with bean plants had no significant effects on the concentration of cadmium in corn or sunflower. Among companion crops, the concentration of cadmium was higher in bean plants compared to those of soybean and mungbean plants. The chlorophyll content in the leaves of corn plants grown with mungbean was increased with an increase in cadmium concentration. However, this trend was not observed in other treatments. The results of this study show that co- cropping with either soybean or mungbean may increase cadmium uptake by corn and sunflower which in turn may increase the risk of inflowing of toxin cadmium into the food chain. However, further study needs to re-evaluate the effect of these companion crops on the distribution of cadmium in the edible parts of corn and sunflower.
S. Jahanbakhshi, M. R. Rezaei, M. H. Sayyari-Zahan,
Volume 18, Issue 70 (3-2015)
Abstract
Phytoremediation is one of the cleanup methods of polluted soil that is possible accumulation of heavy metals in plant tissues, exclusion of these elements from contaminated soil. Therefore, to achievement the objective, this research was done in pot culture using completely randomized design at the University of Birjand in 2011. Two species Spinacia oleracea and Lepidium sativum were used to remove or reduce the concentration of Cadmium (Cd) and Chromium (Cr). In this study, different levels of Cadmium (CdCl2) concentrations including 5, 50, 100 mg kg-1 and also chromium (CrCl3) concentrations 50, 100, 150 mg kg-1 were used respectively and control as well for each species with three replications. Results indicated that the Cd and Cr concentration in shoot of Spinacia oleracea and Lepidium sativum significantly affected by their concentration in soil (p<0/01). Results revealed that increasing of Cd and Cr concentrations in soil, showed an increase concentration of both metal in shoot of Spinacia oleracea. increasing of Cd concentrations in soil, showed an increase concentration of it in shoot of Lepidium sativum but the concentration of Cr was less. Also, comparison of cadmium and chromium concentrations in shoot of Spinacia oleracea and Lepidium sativum showed that two species showed same behavior of Cd and different behavior Cr concentration. So the analysis of data showed that both of species are appropriate for absorption of Cd and Cr and phytoremediation technology as well. It can be concluded that in high soil Cr concentration for phytoremediation Lepidium sativum is not appropriate.
F. Alsadat Hodaee Koskkoee, H. Shariatmadari, M. Hamidrpour, M. Shirvani,
Volume 18, Issue 70 (3-2015)
Abstract
Sorption hysteresis in soil constituents has important environmental implications such as pollutant transport and bioavailability. This research was carried out to study sorption reversibility of cadmium (Cd) on natural zeolite. Sorption isotherms were derived by sorption of Cd (П) from solutions containing different concentrations of Cd in the range of 1 to 10 mg L-1 using a 24h batch equilibration experiment. Desorption of Cd(II) was studied with the clay samples initially treated with the metal loadings of 50 and 100% maximum sorption capacity (SCmax) during the sorption study. Sorption isotherms of Cd were well described by the Freundlich and Coble-Korrigan models (R2=0.96). Desorption isotherms of Cd from zeolite showed little deviation from sorption data indicating reversible sorption. On the other hand, the results revealed no hysteresis. The average amount of 71.75 % of the initially sorbed Cd was desorbed from zeolite after five successive desorption steps. Release of such a relatively high proportion of sorbed Cd indicates that zeolite is an effective sorbent for the repeated purification of polluted water and wastewater.
A. Parnian, M. Chorom, N. Jafarzadeh Haghighi Fard, M. Dinarvand,
Volume 18, Issue 70 (3-2015)
Abstract
Cadmium is a trace element which is harmful to life and is considered as a dangerous pollutant. This element leads to pollution and reduction of water quality and sometimes even to toxicity through contaminated sources such as wastewater (municipal and industrial). Due to the growing population's need for more water resources and increased water resource pollution, a need for new and inexpensive methods for remediation and improving water quality is felt. Phytoremediation with aquatic macrophytes is an effective and inexpensive method for improving water quality and wastewater. In this study, biological removal of cadmium from simulated wastewater was reviewed within 11 days of cultivation of Lemna gibba in Hoagland nutrient solution, at four different concentrations of cadmium (0, 1, 2, 4, and 6 mg L-1). Maximum Bioconcentration Factor and maximum Uptake Index were calculated from 6 mg L-1 metal concentration. Maximum (4.71 g/day) and minimum (2 g/day) Biomass production measurement was obtained from 0 mg L-1 and 6 mg L-1 of pollutant concentration. The plant used in this study was able to accumulated cadmium with the efficiency of up to 91%. However, the pollutant remediation was not completed in a short time. Thus, pollutants' bioremediation from wastewater solutions by Lemna gibba, a native hydrophyte of southern Iran’s pounds, is efficient and appropriate.
R. Mollaei, J. Abedi Koupai, S. S. Eslamian,
Volume 20, Issue 75 (5-2016)
Abstract
Water scarcity forced farmers to use wastewater as water source, without considering its effects on environment and resultant contamination of soils and plants especially with heavy metals. The objectives of this study are to evaluate the application effects of zeolite as soil amendments on the uptake of Cd by spinach (Spinach Oleares L.) irrigated with wastewater (containing 10 ppm Cd). Different levels amounts of zeoilte (0, 1% and 5% w/w) were added to the soil and the experiment was conducted as a completely randomized design in a green house with 3 replications. The results indicated that, the addition of zeolite 1% (w/w) in soil treated with wastewater reduced cadmium concentration in plant, and consequently the percentage of extractable Cd using DTPA was decreased. However, application of zeolite 5% (w/w) increased the soil salinity, and as a result increased Cd concentration in the plant but this increase was not statistically significant, comparing with control. Spinach biomass did not differ significantly under irrigation with wastewater, but the Cd available in wastewater caused a decrease in Spinach biomass yield.
Msc S. Shahmoradi, Dr M. Afyuni, Dr M. Hajabbasi, Dr A. H. Khoshgoftarmanesh, Dr M. Shirvani,
Volume 21, Issue 2 (8-2017)
Abstract
During last century, waste water of gold mine has accumulated heavy metals such as lead, zinc and cadmium in Zarshuran region soil, and thus has increased epidemic disease in this region drastically. The purpose of this research was to reduce the mobility and bioavailability of zinc, lead and cadmium in rhizosphere of sunflower grown in soil around the mine by inorganic sorbents. A pot experiments was carried out with three levels of raw zeolites (1, 6, 12 wt%), three levels of raw bentonite (1, 6, 12 wt%) and control (without sorbent) in a completely randomized block design with three replications. After cultivation, soil and plant samples were taken and the concentration of lead, cadmium and zinc in their samples were measured. Different levels of bentonite reduced the absorbable concentration of lead and zinc; and also reduced their absorbable concentrations in plant tissue, but had no significant effect on reducing absorbable concentration of cadmium. Transfer factor for all three metals in the roots was more than shoot and reducing the concentration of heavy metals in the plant had no impact on plant growth. According to the study, level of 12 wt% of the raw bentonite was the most suitable sorbent for the stabilization of lead and zinc; and level of 12 wt% for raw zeolite was the best sorbent for stabilization of cadmium.
M. Hosseini, E. Adhami, H. R Owliaie,
Volume 22, Issue 1 (6-2018)
Abstract
Cadmium (Cd) is of special importance among heavy metals because its toxicity to the plant is 20 times higher than other heavy metals. The present study was conducted to evaluate the trend of available soil Cd changes over time and its relationship with soil properties. Treatments consisted of 13 soil samples and two Cd rates (12.5 and 25 mg kg-1) as a factorial in a complete randomized design with two replications. DTPA extractable Cd was measured upon 5, 10, 20, 30, 60 and 90 days after adding Cd rates to the soils. The results showed that DTPA extractable Cd was increased as Cd application rates was raised in all soils. DTPA extractable Cd was decreased over time; however, at the end of the experiment, much of the added cadmium to the soil remained in use. Among the soil properties, calcium carbonate showed a significant negative correlation with DTPA extractable Cd in most of the incubation times in both Cd rates. DTPA extractable Cd also showed a significant negative correlation with pH and soil sand and a significant positive correlation with OC. Also, the results of the fitting of cadmium adsorption data with the kinetic equations showed that the exponential function equation was the most suitable kinetics descriptive equation for variations in cadmium adsorption in the studied soils.
E. Chavoshi, Sh. Arabi,
Volume 22, Issue 4 (3-2019)
Abstract
The objectives of this study were to estimate the concentration of lead (Pb) and cadmium (Cd) in agricultural products and the health risks of them on the human healths around the Irankooh Mine in Isfahan Province. The soil samples (0-20 cm of surface layer) and crop samples (rice and wheat) were collected using the composite and random sampling method. The total concentrations of Pb and Cd in soil were found to be 71.18 and 1.57 mg kg-1. The mean Pb concentrations in rice and wheat were 7.81 and 2.31 mg kg-1, respectively. These values for Cd were 0.15 and 0.124 mg kg-1, respectively. The mean daily intake of Pb through the consumption of cereals was more than the dietary reference intake (3.6 μg kg−1 day−1), but the daily intake of Cd was less than the dietary reference intake. The hazard index (HI) mean value for Pb and Cd for children and adults was 4.60 and 4.64, respectively. It showed that the consumption of the entire foodstuff could lead to potential health risks for consumers. There is also the cancer risk associated with exposure to lead.
E. Mirzakhani, H. Motaghian, A. Hosseinpur,
Volume 25, Issue 4 (3-2022)
Abstract
Pollution of the environment by heavy metals, especially soil pollution with cadmium (Cd), is one of the most important environmental problems. Also, salinization of soils due to a decrease in irrigation water quality reduces plants growth. To investigate the effect of sugarcane bagasse biochars and salinity on Cd available and Cd fractions in a contaminated soil (15 mg kg-1 Cd), an experimental factorial design in a completely randomized design including (1) biochar factor with control, 1% (w/w) bagasse, 1% (w/w) biochar 400 °C and 1% (w/w) biochar 600 °C, and (2) salinity factor with control, 20, and 40 mmol kg-1 as sodium chloride were performed in 3 replications. The amount of available Cd was determined by the DTPA-TEA method and the Cd fractions were determined by Tessier et al. (1979). The results showed that biochar and salinity had no significant effect on soil pH (P > 0.05) but increased soil EC (P < 0.05). Interaction of biochar and salinity was not significant (P > 0.05) on available Cd and Cd fractions. Biochar application reduced Cd -DTPA-TEA (P < 0.05), whereas salinity increased Cd -DTPA-TEA (P < 0.05). Application of biochar prepared at 600 °C reduced (P < 0.05) exchangeable Cd (23.8%) and increased (P < 0.05) Cd associated with iron and manganese oxides (25.2%) and residual (15.6%) compared to the control. The results showed that salinity had no significant effect on the Cd fractions (P > 0.05) and soil treated with sugarcane bagasse biochar can reduce Cd available due to changing the Cd distribution from unstable forms to stable forms.
N. Azadi, F. Raiesi,
Volume 26, Issue 1 (5-2022)
Abstract
Biochar as an efficient strategy for the improvement of soil properties and organic waste management may reduce the potential effects of abiotic stresses and increase soil fertility. However, the effects of this organic amendment on soil microbial indicators under combined salinity and pollution have not been studied yet. Therefore, the objective of this study was to evaluate the influence of sugarcane bagasse biochar on some soil bioindicators in a Cd-polluted soil under saline and non-saline conditions. A factorial experiment was carried out with two factors, including NaCl salinity (control, 20 and 40 mM NaCl) and sugarcane bagasse biochar (soils unamended with biochar, amended with uncharred bagasse, 400 oC biochar, and 600 oC) at 1% (w/w) using a completely randomized design. Results showed that salinity increased the mobility of Cd (12-17%), and subsequently augmented its toxicity to soil microorganisms as indicated by significant decreases in the abundance and activities of the soil microbial community. Conversely, sugarcane bagasse biochar application reduced the concentration of soil available Cd (14-18%), increased the contents of soil organic carbon (89-127%), and dissolved organic carbon (4-70%), and consequently alleviated the effect of both abiotic stresses on soil microbial community and enzyme activity. In conclusion, this experiment demonstrated that the application of sugarcane bagasse biochar could reduce the salinity-induced increases in available Cd and mitigate the interaction between salinity and Cd pollution on the measured soil bioindicators.
E. Mirzakhani, H.r. Motaghian, A.r. Hosseinpur,
Volume 27, Issue 3 (12-2023)
Abstract
In addition to the distribution of elements in the soil solid phase, element species in the solution are also very important due to their importance of providing elements for root uptake. For a deeper study of the chemical cycle of elements in saline soils treated with biochar, the study of speciation is very useful and provides a method to reduce or transform the toxicity caused by toxic elements in saline soils. Therefore, to investigate the effect of biochar on Cd speciation in two saline calcareous soils, 15 mg kg-1 Cd as cadmium chloride was added to the soil sample (200 g), and the soils were incubated for three weeks at 25±2 °C at 80% field capacity. After the incubation period, salinity levels of 20 and 40 mmol kg-1 as sodium chloride (equal to 3.65 and 7.30 dS m-1) were added to the soils. Then, the 1% (w/w) of the sugarcane bagasse and biochars produced at 400 and 600 °C were added to the soils, and then incubated for three months at 25±2 °C at 80% field capacity. At the end of the incubation period, for the speciation of Cd in the soil solution (in a 1 to 2 ratio), the concentration of dissolved cations and anions in the soil samples was measured. The results showed that the interaction between salinity, biochar, and soil on Cd2+, CdCl+, CdCl20, and Cd(SO4)22- was significant. The application of biochar in sandy soil reduced (p <0.05) the concentration of CdCl+, CdCl20, CdSO40, and CdOH+ species compared to the control soil, while it did not affect clay soil. Also, salinity caused by sodium chloride in sandy soil increased the concentration of CdCl+ and CdCl20 species and decreased CdSO40 and CdOH+ species compared to the control soil (p <0.05). The results showed that biochar in saline sandy soil was more effective than clay soil in reducing Cd toxicity.
