JWSS - Journal of Water and Soil Science

Today, to reduce the risks of contaminants, new remediation techniques have been focused on low-cost and environmentally friendly manners. Given the frequency of access, inexpensiveness and good physical and chemical properties, biochar has a high potential for the remediation of water pollutants. In this paper, the efficiency of chitosan engineered biochar (Bc-Ch) and pristine biochar (Bg-Bc) prepared from sugarcane bagasse biomass (Bg) in the Cd²⁺ removal in aqueous solution was investigated. To this aim, the effects of contact time, adsorbent dosage and solution pH on cadmium removal were evaluated by adsorption isotherms and Kinetic models. The results indicated that the Langmuir isotherm and the pseudo-second-order kinetic model could be well fitted with the process of cadmium biosorption. The maximum adsorption capacities of Bc-Ch, Bg-Bc and Bg ,according to Langmuir model, were found to be 32/78 mg/g, 11/57 mg/g and 2/23 mg/g, respectively. For these absorbents, the pseudo-second-order kinetic model showed the best fit to the experimental adsorption data. This study, therefore, indicated that the chitosan engineered biochar could be used as an effective, low-cost, and environmentally-friendly sorbent to remediate heavy metals contamination in the environment.

The use of additives to modify the physical, chemical and mechanical properties of soil and soil stabilization is one of the most common methods that have a history. By adding one or more additives to the soil and carrying out the required measures, the engineering properties of soils could be improved due to chemical reactions. Selecting the type and amount of additive depends on several factors such as: soil type, stabilization purpose, additives inherent characteristics, etc.; these are determined based on the technical and economic aspects of the projects. In this study, the effects of the simultaneous use of three types of additives including lime, stone powder and polypropylene fibers on the unconfined compressive strength of a clayey soil were investigated.  To do this, four different levels of lime (0, 2, 3 and 5 percent by weight of soil) and four different levels of stone powder waste (0, 2, 5 and 10 percent by weight of soil) and Polypropylene fibers with different percentages in five levels of 0, 0.25, 0.5 and 1 percent by weight of soil were added into a high plastic clay soil classified as CH. Then, some physical and mechanical characteristics of different mixtures including plasticity, compaction and unconfined compressive strength were determined. The results showed that the samples were stabilized with lime and stone powder waste and reinforcement them with polypropylene fibers modified Atterberg Limits, optimum moisture and maximum dry density of the mixtures. Also, it was found that a combination of waste stone powder, lime and polypropylene fibers containing 5, 5 and 1 percent by weight of soil increased the unconfined compressive strength 8-fold, as compared to the natural soil. The curing time also had a significant impact on the compressive strength of the treated samples in which the 28-day compressive strength of was found to be about 2 times of the 7-day samples.

The main purpose of the study is the operational simulation of main irrigation canal and evaluation of water delivery and distribution locally, regionally and overall using adequacy, efficiency, and equity indicators and “Desirability of water delivery and distribution” indicator. To achieve this goal, the hydrodynamic model of Roodasht irrigation network’s main canal was developed. The results of the calibration and validation of the hydrodynamic model showed that the two processes were satisfactory. All available scenarios including normal, water shortages and fluctuations were considered for water delivery and distribution in different conditions. In the local assessment, the adequacy varied from 7 to 85%, and the efficiency in all scenarios was 100%. The adequacy, efficiency, and equity indicators in the regional evaluation varied from 6 to 89, 91 to 100, and 13 to 46%, respectively. The overall evaluation of the canal showed that the most desirable situation is related to a harsh fluctuation increasing with the adequacy, equity and efficiency indicators equal to 82, 23 and 91%, respectively. Calculation of the “Desirability of water delivery and distribution” indicator showed poor performance in all operational scenarios except harsh fluctuation scenario with 82% of which, the canal performance was estimated in fair level.

The present study was intended to improve the chemical properties of a saline-sodic soil using the individual application of alfalfa residue and two biochars produced from sugarcane bagasse and walnut shell, at the weighting ratio of 5%; their concomitant application with gypsum, aluminum sulfate and the mixture of these two chemical amendments was considered. The experiment was conducted in three replications using the factorial experiment in a completely randomized design. After four months of incubation, the soil samples were measured for their main chemical properties. The results showed that alfalfa residues were the most effective treatment to reduce the soil pH; so the concomitant application of this organic amendment with gypsum lowered the soil pH from 9.13 in the control (untreated soil) to 7.24. It was also observed that the addition of gypsum and/or aluminum sulfate to the soil led to the increase of the soil electrolyte concentration and consequently, the increase of soil electrical conductivity to three times greater than control, through an increase of ions, like calcium and sulfate in the soil solution. Increasing the soluble sodium concentration by replacing exchangeable sodium by other similar ions showed that the studied treatments enhanced the sodium adsorption ratio (SAR), which could be regulated by washing. Concomitant application of the walnut-shell biochar with gypsum had the most increasing effect on the soil SAR, enhancing it from 22.6 in the control to 54.3. Potassium was released from organic amendments, improving the soil general conditions; addition of chemical amendments elevated soil exchangeable potassium contents; however, the elevated soil available phosphorus contents were less influenced by chemical amendments application. As the conclusion, it seems that the positive impacts of the applied chemical and organic amendments would supplement each other; as a result, the concurrent use of both treatments not only improves the bad soil chemical properties, but also enhances the soil fertility.

Iran is located in the dry belt of the earth and is predicted to face water stress in the next half-century. Currently, the area of sugarcane cultivation in Khuzestan is over 85,000 hectares and due to the high water needs of sugarcane and drought conditions, optimization of water consumption and irrigation management is necessary to continue production. Therefore, in this study, the values of soil moisture, canopy cover, biomass yield in five treatments and irrigation levels (start of irrigation at 40%, 50%, 60%, 70%, and 80% soil moisture discharge) during 2 planting dates in the crop year 2015-2016 on sugarcane cultivar CP69-1062 in Amirkabir sugarcane cultivation and industry located in the south of Khuzestan was simulated by AquaCrop model. The measured data on the first culture date (D1) and the second culture date (D2) were used to calibrate and validate the model.  The results of NRMSE statistics in canopy cover simulation in calibration and validation sets with values of 2.1 to 15.6% and 3.8 to 18.3%, respectively, and in biomass simulation with values of 6.2 to 15.2%, and 9.5 to 12.6%, respectively and coefficient of determination (R2), range 0.98 to 0.99 indicated that the high ability of the AquaCrop model in simulation canopy cover and biomass yield. whereas, the values of NRMSE of soil depth moisture in the calibration and validation sets ranged from 11.6 to 23.8, and 12.2 to 22.7, respectively, with a coefficient of determination (R2), 0.73 to 0.96 (calibration) 0.8 to 0.93 (validation) showed less accuracy of the model in the simulation. The best scenario is related to the third proposal that water consumption, water use efficiency, and yield are 1710 mm, 1.53, and 42.27 tons per hectare, respectively, which shows a reduction in water consumption of 360 mm.

Inefficient use of limited water resources, along with increasing population and increasing water demand for food production has severely threatened agricultural water resources. One way to overcome this problem is to improve water productivity by introducing new crops that tolerate water stresses such as quinoa. In this study, the effect of water stress at different stages of plant growth (vegetative, flowering, and grain filling) was studied on plant parameters, yield, and water productivity of quinoa (cv. Titicaca). This study was conducted under field conditions and the treatments were performed as a block experiment in a completely randomized design with four replications. Experimental factors were: treatment without water stress or full irrigation (F) and water stress treatment (D) at 50% of the need for full irrigation at different stages of quinoa growth. The application of deficit irrigation during different stages of plant growth decreased stomatal conductance, leaf area index, leaf water potential, seed yield, and water productivity, while deficit irrigation increased the green canopy temperature. According to the results of the present study, the flowering stage of quinoa was very sensitive to water stress leading to produce lower yield compared with the amount of yield obtained when vegetative and or grain filling stages are under water stress conditions.

Water quality characteristics play a crucial role in water resources management, watershed health assessment, and implementing effective management strategies. The objective of this research was to present an overall assessment of the surface water quality in the Gorganrood River Basin to be utilized for developing effective watershed management plans and programs. Various physicochemical water quality data including main anions and cations, Total Dissolved Solids (TDS), Electrical Conductivity (EC), Sodium Absorption Ratio (SAR), pH, and total hardness recorded at 25 hydrometric stations across the basin were analyzed and assessed with the Canadian (CCME) Water Quality Index. The mean water quality index for drinking, agriculture, and industrial purposes indicated that headwaters and higher areas generally exhibited better water quality compared to the downstream areas of the basin. Geochemical processes and the introduction of various pollutants during water flow from the headwaters to the basin outlet contribute to a decline in water quality. The highest water quality was observed in the Kabudval and Shirabad stations, whereas the Baghesalian station exhibited the lowest. For drinking water use, hardness, bicarbonate, and chloride were identified as variables contributing to water quality decline in the headwaters and upstream areas. However, these areas predominantly maintained a moderate to good quality for drinking purposes. Conversely, downstream areas experienced a significant deterioration in water quality with higher pollutant levels such as total dissolved solids (TDS), sulfate, and sodium, resulting in relatively poor to poor conditions. Approximately 60% of the stations in the basin had excellent water quality for agricultural use, with no limiting factors. Only three stations near the basin's outlet exhibited relatively poor to poor water quality due to elevated chloride levels, sodium adsorption ratio (SAR), and electrical conductivity. only 28% of hydrometric stations demonstrated good water quality for industrial use. Hardness, pH, and TDS are the main variables contributing to water quality decline for industrial use in the upstream, while downstream areas are impacted by chloride and sulfate. The outcomes of this study hold significant implications for effective water resources management, watershed preservation, and natural resource conservation in the Gorganrood basin. From industry and especially health aspects, however, more detailed investigations are needed, taking into account some other important variables of water quality (including nitrate, total coliform, fecal coliform, etc.).