JWSS - Journal of Water and Soil Science

---

Many studies have been carried out on the effect of organic matter on soil physical, chemical, biological, and nutritional properties, including the effect of organic matter on the availability of such elements as P, N and heavy metals. There is, however, no information on the effect of organic matter on potassium uptake from micaceous minerals. The objective of this study was to investigate the effect of organic matter on potassium uptake from micaceous minerals released by alfalfa. An experiment was laid out in a completely randomized design with factorial combination and three replicates. Growth medium was a mixture of quartz sand, micaceous mineral (muscovite or phlogopite) and organic matter (0, 0.5 and 1 %). Rehnani cultivar of alfalfa was used in the experiment. During 120 days of cultivation, plants were irrigated with either complete or K-free nutrient solution and distilled water as needed. At the end of cultivation, plant shoots and roots were separately harvested and their K concentration was measured by flame photometer following dry ash extraction. Under the K-free nutrient solution, a significant increase in biomass occurred in pots containing phlogopite and organic matter as compared to those with no organic matter amendment. Also, under K-free condition, potassium concentration in shoot was above the threshold value only in phlogopite amended pots. There was no significant difference in K concentration among different levels of organic matter in control treatment as well as in muscovite added treatment. Under both nutrient solutions treatments, significant increase of K uptake occurred in pots containing phlogopite and organic matter, as compared to those without it. In contrast, under K free nutrient solution, organic matter amendment could not enhance the K uptake in pots containing dioctahedral mica (muscovite). Root activities and organic matter decomposition appear to have increased rhizosphere acidity which, in turn, facilitate the K release from trioctahedral mica (phlogopite) in K deficient medium. Thus, the effect of organic matter on K release greatly depends on the type of micaceous mineral.

---

The task of modern agriculture is to safeguard the production of high quality food, in a sustainable natural environment under the precondition of pollution not exceeding accepted norms. The sustainability of current land use in agro-ecosystems can be assessed with respect to heavy metal accumulation in soils by balancing the input/ output fluxes. The objectives of this study were to model accumulation rate and the associated uncertainty of Zn in the agro-ecosystems of 3 arid and semi-arid provinces (Fars, Isfahan and Qom). Zinc accumulation rates in the agro-ecosystems were computed using a stochastic mass flux assessment (MFA) model with using Latin Hypercube sampling in combination with Monte-Carlo simulation procedures. Agricultural information including crop types, crop area and yield, kind and number of livestock, application rates of mineral fertilizers, compost and sewage sludge and also metal concentration in plants and soil amendments were used to quantify Zn fluxes and Zn accumulation rates. The results indicated that Zn accumulates considerably in agricultural lands of the studied townships especially in Najafabad (3009 g ha-1yr-1). The major Zn input routes to the agricultural soils (and due to agricultural activities) were manure and mineral fertilizers and the major part of the uncertainty in the Zn accumulation rate resulted from manure source.

---

Magnetic susceptibility measurement is a simple and quick technique for characterizing soils and sediments and describing soil-forming processes. The interpretation of soil magnetic susceptibility data needs sufficient knowledge about the factors affecting this parameter. To identify the effects of parent material, gypsum and calcium carbonate equivalent, 42 samples were taken from horizons of soils developed on loessial, alluvial, granitic and marly materials in southern Mashhad. Gypsum and carbonates of soil samples were removed by successive washing with distilled water and diluted HCl, respectively. Magnetic susceptibility of bulk samples (lfbulk), gypsum free samples (lfGf), gypsum and carbonates free samples (lfGCf) and gypsum, carbonates and sand free samples (lfGCSf) was measured. The results revealed a strong 1:1 correlation between the measured and calculated lfGf and lfGCf. Despite the high amounts of gypsum and carbonates in soils developed on marls, their lfbulk was much more than that of the other soils and reached up to 121.8×10-8m3 kg-1. In contrast, the lfbulk values of saprolitic granite were less than 10.4×10-8m3 kg-1. The lfbulk values of loessial and alluvial soils were less than those of marly soils but higher than those of soils developed on saprolitic granite. lfbulk values were negatively correlated with the amount of sand. However, reduction in magnetic susceptibility values of marly soils after removing sand reflects the different nature of this soil. The correlation between lfbulk and amount of silt and clay is positive, but the magnetic susceptibility values are more sensitive to clay percentage, indicating the more important contribution of clay to magnetic susceptibility values. The results of this study highlight the role of parent materials, gypsum and carbonates in the soil magnetic susceptibility values that should be considered.

---

Digital soil mapping includes soils, spatial prediction and their properties based on the relationship with covariates. This study was designed for digital soil mapping using binary logistic regression and boosted regression tree in Zarand region of Kerman. A stratified sampling scheme was adopted for the 90,000 ha area based on which, 123 soil profiles were described. In both approaches, the occurrence of relevant diagnostic horizons was first mapped, and subsequently, various maps were combined for a pixel-wise classification by combining the presence or absence of diagnostic horizons. Covariates included a geomorphology map, terrain attributes and remote sensing indices. Among the predictors, geomorphology map was identified as an important tool for digital soil mapping approaches as it helped increase the prediction accuracy. After geomorphic surfaces, the terrain attributes were identified as the most effective auxiliary parameters in predicting the diagnostic horizons. The methods predicted high probability of salic horizon in playa landform, gypsic horizon in gypsiferous hills and calcic horizon in alluvial fans. Both models predicted Calcigypsids with very low reliability and accuracy, while prediction of Haplosalids and Haplogypsids was carried out with high accuracy.

---

Zinc (Zn) is an essential trace element for plants as well as for animals and humans. There is a significant relationship between soils, plants and humans Zn status in a certain agro-ecosystem. The objectives of this study were to assess Zn status of soils in 3 arid and semiarid provinces of Iran and to model the relationship between wheat grain Zn and agro-ecosystem parameters. About 137 soil and wheat samples were collected randomly from the agricultural soils of Fars, Isfahan and Qom and were analysed in laboratory. Modeling the relationship between wheat grain Zn and agro-ecosystem parameters was done using least square based and robust methods. The results indicated that total Zn concentration of soils (range, 21-149 mg kg-1 mean, 75.2 mg kg-1) was in normal ranges. The DTPA-extractable Zn concentrations were below the critical level (0.8 mg kg-1) in 16% of the surveyed fields. The Zn concentration in 80% of wheat grains was sufficient (more than 24 mg kg-1) with respect to plant nutrition (range, 11.7-64 mg kg-1 mean, 31.6 mg kg-1). However, Zn bioavailability for consumers was generally low in more than 75% of the samples. This is because of high phytic acid to Zn molar ratio (more than 15). Soil DTPA-extractable Zn and available P were entered in to most of regression models significantly. Regression analysis showed that most of models fitted to wheat grain Zn concentration and soil Zn and influenced by agro-ecosystem parameters had a weak prediction power, despite their high determination coefficient. This means that factors other than those considered here have a strong influence on the uptake of Zn by wheat in these soils.

---

In Iran, no research has yet been performed on potassium release from feldspar in comparison with that from muscovite. The objective of this research was to compare potassium release kinetics of these minerals as influenced by organic and inorganic extractants using successive extraction method. The experiment was carried out in a completely randomized design with a factorial combination. Treatments consisted of three kinds of K-bearing minerals (Muscovite, and Yazd and Ward feldspars), three extractants including CaCl2, oxalic and citric acids of 0.01 M concentration and 6 times of extraction (1, 2, 8, 24 and 48 hours). The results indicated that the potassium release from muscovite was 6-8 times higher than that from feldspars. The type of extractant significantly affected potassium release. Potassium release by organic extractants was 2.5-3 times higher than that by CaCl2 as an inorganic extractant. Different kinetic equations showed that power function, parabolic diffusion and first order equations adequately described K release whereas Elovich equation did not. Among the three equations, power function equation was selected as the best model describing K release from the minerals. Based on the selected kinetic equations, it seems that potassium release from K-bearing minerals is controlled by diffusion process.

---

Stabilizing heavy metals in polluted soils is a method to prevent them from entering plants. Clay minerals are considered good sorbents for heavy metals due to their low cost, high abundance, easy manipulation and harmlessness to the environment. The objective of this study was to investigate the potential of clay deposits containing smectites and palygorskite to sorb cadmium and to reduce its movement into canola. Two selected deposits are located in the Isfahan Province. Physical and chemical characteristics of clay deposits were determined. The clay fraction was then separated from each deposit sample. This study showed that palygorskite was the dominant clay mineral in deposit sample 1 and smectites in deposit sample 2. These clays were then used as an amendment to plant growth medium. Pot experiment was carried out with canola (Brassica napus) as a test plant with 3 replicates. Treatments included three growth media: smectite + quartz sand, palygorskite + quartz sand and pure quartz sand (control treatment) under 3 Cd concentrations: 0, 2.5 and 7.5 ppm. Results obtained from the pot experiment indicated that deposits containing smectite and palygorskite were very useful in stabilizing cadmium in polluted soils and could prevent Cd from entering plant. Smectite clay mineral could retain a higher quantity of cadmium as compared to palygorskite. Plants in pots amended with smectite had a higher growth rate as compared to those in control and palygorskite amended pots. Cadmium accumulation in plant roots was much higher than that in shoot. Furthermore, the higher Cd concentration in growth media resulted in the higher amount of Cd uptake by the plant.

---

Atmospheric dust is an important source of heavy metals, particularly in urban environments. Heavy metals can easily attach to dust particles and be distributed in large areas. The objective of this study was to evaluate the status of major heavy metals in the atmospheric dust of Isfahan and adjacent cities. A total of 144 dust samples were taken during a period from August to December 2010 from Isfahan, Khomeynishahr, Falavarjan, Mobarake and Zarinshahr cities. Dust samples were extracted with HNO3 65% and the total concentration of metals including Pb, Zn, Cd, Cu, Ni, Co, Cr and Mn in the samples was measured by an atomic absorption spectrometer. The mean concentration of these metals was 223.5, 470.3, 3.5, 71.0, 82.0, 26.5, 24.4 and 426.3 mg kg-1, respectively. Results indicated that heavy metals concentration in any area was different depending on the source of pollution and it was much higher than the mean concentration of the corresponding heavy metal in soils. Besides, the highest deposition rate of all the heavy metals in this study was found in November-December period. This could be attributed to an increase in the use of heating systems and also to a temperature inversion event prevailed in the area. Atmospheric deposition seems to be an important pathway of heavy metals addition to soils. For example, it is responsible for 35-91% and 12-47% of Pb and Cd entering the soil in the area, respectively.

---

Organic acids play an important role in improving the bioavailability of soil nutrients. The objectives of this study were to determine the effect of oxalic acid on the release of soluble, exchangeable and non-exchangeable forms of K from micaceous minerals and potassium feldspars, and also to investigate the trend of K release by time. A laboratory study was carried out using a completely randomized design with two replicates. Biotite, phlogopite, muscovite, Zanjan and Yazd K-feldspars (< 50 &mu;m size) were treated with 0, 10 and 100 mM of oxalic acid solutions for a period of 5 hours and 20, 60 and 90 days. The amount of K was determined by flame photometer. The results indicated that most amount of soluble, exchangeable and no-exchangeable K was released by 100 mM of oxalic acid. The maximum soluble K (0.86 gKg-1) was released from phlogopite, and the maximum exchangeable and non-exchangeable K (1.5 and 29.6 gKg-1, respectively) were released from biotite. Muscovite with 0.19, 0.34 and 1.41 gKg-1 of soluble, exchangeable and non-exchangeable K, respectively, had the lowest release of K among the studied minerals. The kinetics K release from minerals consisted of two phases. The first phase was relatively rapid and then it had a slow rate until the end of the experiment. Given that the applied concentration of organic acid was high, potassium release during the experiment period did not reach the steady state. Therefore, a longer period of release experiment is suggested.

---

Dust deposition occurs extensively in arid and semiarid regions of the world. Since dust particles are fine-sized, they have a high adsorption capacity and also high contamination potential. The objective of this study was to evaluate the temporal and spatial distribution of the rate of atmospheric dust deposition in different locations in Kerman urban area. Dust samples were collected monthly using glass traps installed on the roof of 35 one-story buildings in Kerman for 7 months from April 20 to Nov. 20, 2012 (a total of 245 samples). After each monthly sampling, traps were washed and dust samples transferred to the laboratory and weighed. The mean dust deposition rate of 7 months was mapped using the inverse distance weighting (IDW) approach. The wind rose of Kerman was drawn by WRPLOT 7.0.0. The results showed that the average rate of dust deposition decreased during the 7 months studied from 17.4 to 5 g/m2. month, which could be attributed to the decrease in wind velocity. The spatial distribution of the samples also showed that the dust deposition rate varied from 4.84 in the southern parts to 14.84 g/m2.month, mostly in the northern locations of the city. The wind rose based on the average wind speed of the 7 months of sampling indicated the prevailing wind blows from north, northeast and northwest and the dust spatial distribution well follows the wind direction. In general, the rate of dust deposition in Kerman city is high and therefore, the source of dust has to be well detected and proper management practices are necessary.

---

Few investigations have been carried out on the ability of different plants to take up non-exchangeable potassium (K). The objective of this investigation was to examine the ability of different alfalfa cultivars to absorb K from phlogopite. An experiment was carried out with a completely randomized design with 3 alfalfa cultivars including Pickseed 2065 (MF), Rehnani (R) and Hamadani (H) grown in a quartz sand medium containing <53 micron sized phlogopite under complete and K-free nutrient solutions for a period of 6 months. During the growth period, the shoot was harvested 4 times. At the end of the experiment, the root was also separated from the growth medium and collected. Plant samples were extracted using the dry ash method and their K concentration was determined. Under the K-free nutrient solution, the highest shoot and root K concentration and uptake were found for the MF cultivar. The shoot and root K concentration in this cultivar were respectively 1.6 and 1.5 times higher than those in the R cultivar and 1.8 times greater than those in the H cultivar. The K uptake in the shoot and root of the MF cultivar was respectively 1.6 and 1.9 times higher than that of the H cultivar and 1.6 and 1.5 times higher than that of the R cultivar. Thus, in addition to other parameters, the type of plant variety should be taken into account when K requirement is evaluated.

---

Vis-NIR spectroscopy has been introduced as a non-destructive, fast, and cheap technique, with minimal sample preparation and no loss or damage to the environment. No investigation has yet been carried out to examine the ability of this method to estimate soil properties in Iran. The objective of this research was to investigate the capability of Vis-NIR spectroscopy to predict the amount of organic matter, carbonate and gypsum in surface soils of Isfahan province. A total of 248 surface soil samples were collected from the study area. Soil organic matter content, gypsum and carbonates percentages were measured by standard laboratory methods. Soil spectral analyses were performed by a field spectrometer using 350-2500 nm wavelength range. Different pre-processing methods were evaluated after recording the spectra. Partial least squares regression was used to predict soil parameters. R2 values for organic matter, carbonates and gypsum were 0.61, 0.45 and 0.8, respectively. Based on RPD (Ratio of Prediction to Deviation) values, the precision of prediction model for gypsum was quite good, and acceptable for organic matter, whereas the prediction of the model for soil carbonates was poor. Consequently, vis-NIR spectroscopy is capable of predicting some soil properties simultaneously and the model accuracy is acceptable.

---

Spatial and temporal distribution of dust deposition rate (DDR) in Isfahan city and the influencing climatic parameters were studied. Dust samples were collected using glass trays placed on the roof of one-story buildings from 20 sites in Isfahan city for 12 months. Climatic data were obtained from Meteorological Organization and analyzed. The highest and the lowest amount of DDR in agreement with the direction of prevailing wind were observed for dry months with eastern and northeastern wind directions and wet periods with western and southwestern wind directions, respectively. This can indicate dust emission from the desert located in eastern part of Isfahan city. Statistically significant inverse correlation between DDR and precipitation and relative humidity, and significant and positive correlation of DDR with Min and Max temperatures in all the studied months and also with Max and average wind speed for dry sampling months may well justify the temporal distribution of DDR in the city. In dry months, finer particles from eastern desert can be transported a longer distance and deposited in the western part of the city, far from the source area. In wet seasons, however, soil aggregates become coarser as a result of particle adhesion. This, in turn, results in the deposition of dust near the source area as the transporting power of dust reduces.

---

Heavy metals in dust can directly enter to the human body through ingestion and inhalation. They can pollute the water and soil resources via atmospheric precipitation and accumulate in the plant tissues and then enter human body through water and food. This research aimed to study the heavy metals concentration in dust in Kermanshah province and to identify their sources. 49 samples of dust were collected in the cities of Kermanshah, Songhor, Gilangharb, Ghasre-Shirin, Sahneh, Sarpolzahab, Kangavar, Paveh and Javanrood during the spring 2013. The concentration of Zn, Cu, Ni, Cr, Mn and Fe were determined using an atomic absorption spectrometer following the sample extraction with a mixture of HCL and HNO₃ (3:1 ratio). The average concentrations of Zn, Cu, Ni, Cr, Mn and Fe were 182.3, 48.6, 115.3, 73.9, 428.1 and 23161 mg kg^-1, respectively. Correlation, cluster and principal component analyses were used to identify probable natural and anthropogenic sources of contaminants, and the enrichment factor was used to identify probable effects of human activity on the concentration of heavy metals. The results indicated that metal concentrations, except for Fe and Mn, were higher in comparison with the world soils. Zn, Cu, Ni and Cr are mainly of anthropogenic origin, while Fe and Mn are mainly of natural origin. Zn and Cu are mainly of traffic sources and partly of industrial sources, and Ni and Cr are mainly derived from industrial sources, combustion processes, combined with traffic sources. The analysis of EF revealed moderate enrichment for Mn and Cr, and significant enrichment for Zn, Cu and Ni. Based on the results of this study, more attention should be paid to identifying and controlling the sources of contaminants such as heavy metals in dust in order to prevent their associated pollution.

---

Dust deposition phenomenon is an important climatic and environmental issue in arid and semi-arid regions. The objective of this study was to examine important characteristics of atmospheric dust in Kerman as one of the major cities in arid areas of our country with high potential of dust production. Dust samples were collected monthly using glass traps installed on the roof of 35 one-story buildings in Kerman for 7 months from April 20 to Nov. 20, 2012. To compare the results of atmospheric dust with those of soil, 60 surface soil samples (0-10 cm) from outside Kerman and 35 soil samples from urban areas were also collected. Some physical and chemical characteristics such as pH, electrical conductivity, organic matter, calcium carbonate equivalent, and  particle size distribution were determined in dust and soil samples. The results of chemical analyses indicated that the amount of these properties is much higher than that in soils. Atmosphere dust particles appear to mainly originate from alkaline and saline soils surrounding the city of Kerman. Dust particle size distribution analysis further confirmed that dust particles have been transferred to Kerman city from medium to long distance areas.  Temporal variability in dust chemical properties indicates that the contribution of anthropogenic and natural sources to urban dust in Kerman has seasonal changes. Based on the results obtained, it is necessary to control dust production outside and inside the city and its distribution in populated areas employing proper management practices.

---

---

---

---

---