Showing 43 results for Khademi
A. Jafari, H. Khademi, Sh. Ayoubi,
Volume 16, Issue 62 (Winte - 2013 2013)
Abstract
Digital soil mapping includes soils, spatial prediction and their properties based on the relationship with covariates. This study was designed for digital soil mapping using binary logistic regression and boosted regression tree in Zarand region of Kerman. A stratified sampling scheme was adopted for the 90,000 ha area based on which, 123 soil profiles were described. In both approaches, the occurrence of relevant diagnostic horizons was first mapped, and subsequently, various maps were combined for a pixel-wise classification by combining the presence or absence of diagnostic horizons. Covariates included a geomorphology map, terrain attributes and remote sensing indices. Among the predictors, geomorphology map was identified as an important tool for digital soil mapping approaches as it helped increase the prediction accuracy. After geomorphic surfaces, the terrain attributes were identified as the most effective auxiliary parameters in predicting the diagnostic horizons. The methods predicted high probability of salic horizon in playa landform, gypsic horizon in gypsiferous hills and calcic horizon in alluvial fans. Both models predicted Calcigypsids with very low reliability and accuracy, while prediction of Haplosalids and Haplogypsids was carried out with high accuracy.
Mahin Karami, Majid Afyuni, Amir Hossein Khoshgoftarmanesh, Mohammad Ali Hajabbasi, Hossien Khademi, Ali Abdi,
Volume 17, Issue 64 (summer 2013)
Abstract
Zinc (Zn) is an essential trace element for plants as well as for animals and humans. There is a significant relationship between soils, plants and humans Zn status in a certain agro-ecosystem. The objectives of this study were to assess Zn status of soils in 3 arid and semiarid provinces of Iran and to model the relationship between wheat grain Zn and agro-ecosystem parameters. About 137 soil and wheat samples were collected randomly from the agricultural soils of Fars, Isfahan and Qom and were analysed in laboratory. Modeling the relationship between wheat grain Zn and agro-ecosystem parameters was done using least square based and robust methods. The results indicated that total Zn concentration of soils (range, 21-149 mg kg-1 mean, 75.2 mg kg-1) was in normal ranges. The DTPA-extractable Zn concentrations were below the critical level (0.8 mg kg-1) in 16% of the surveyed fields. The Zn concentration in 80% of wheat grains was sufficient (more than 24 mg kg-1) with respect to plant nutrition (range, 11.7-64 mg kg-1 mean, 31.6 mg kg-1). However, Zn bioavailability for consumers was generally low in more than 75% of the samples. This is because of high phytic acid to Zn molar ratio (more than 15). Soil DTPA-extractable Zn and available P were entered in to most of regression models significantly. Regression analysis showed that most of models fitted to wheat grain Zn concentration and soil Zn and influenced by agro-ecosystem parameters had a weak prediction power, despite their high determination coefficient. This means that factors other than those considered here have a strong influence on the uptake of Zn by wheat in these soils.
A. Mousavi, F. Khayamim, H. Khademi, H. Shariatmadari,
Volume 18, Issue 67 (Spring 2014)
Abstract
In Iran, no research has yet been performed on potassium release from feldspar in comparison with that from muscovite. The objective of this research was to compare potassium release kinetics of these minerals as influenced by organic and inorganic extractants using successive extraction method. The experiment was carried out in a completely randomized design with a factorial combination. Treatments consisted of three kinds of K-bearing minerals (Muscovite, and Yazd and Ward feldspars), three extractants including CaCl2, oxalic and citric acids of 0.01 M concentration and 6 times of extraction (1, 2, 8, 24 and 48 hours). The results indicated that the potassium release from muscovite was 6-8 times higher than that from feldspars. The type of extractant significantly affected potassium release. Potassium release by organic extractants was 2.5-3 times higher than that by CaCl2 as an inorganic extractant. Different kinetic equations showed that power function, parabolic diffusion and first order equations adequately described K release whereas Elovich equation did not. Among the three equations, power function equation was selected as the best model describing K release from the minerals. Based on the selected kinetic equations, it seems that potassium release from K-bearing minerals is controlled by diffusion process.
T. S. Taleghani , H. Khademi, M. Afyuni ,
Volume 18, Issue 67 (Spring 2014)
Abstract
Stabilizing heavy metals in polluted soils is a method to prevent them from entering plants. Clay minerals are considered good sorbents for heavy metals due to their low cost, high abundance, easy manipulation and harmlessness to the environment. The objective of this study was to investigate the potential of clay deposits containing smectites and palygorskite to sorb cadmium and to reduce its movement into canola. Two selected deposits are located in the Isfahan Province. Physical and chemical characteristics of clay deposits were determined. The clay fraction was then separated from each deposit sample. This study showed that palygorskite was the dominant clay mineral in deposit sample 1 and smectites in deposit sample 2. These clays were then used as an amendment to plant growth medium. Pot experiment was carried out with canola (Brassica napus) as a test plant with 3 replicates. Treatments included three growth media: smectite + quartz sand, palygorskite + quartz sand and pure quartz sand (control treatment) under 3 Cd concentrations: 0, 2.5 and 7.5 ppm. Results obtained from the pot experiment indicated that deposits containing smectite and palygorskite were very useful in stabilizing cadmium in polluted soils and could prevent Cd from entering plant. Smectite clay mineral could retain a higher quantity of cadmium as compared to palygorskite. Plants in pots amended with smectite had a higher growth rate as compared to those in control and palygorskite amended pots. Cadmium accumulation in plant roots was much higher than that in shoot. Furthermore, the higher Cd concentration in growth media resulted in the higher amount of Cd uptake by the plant.
Z. Mahmoodi, H. Khademi ,
Volume 18, Issue 67 (Spring 2014)
Abstract
Atmospheric dust is an important source of heavy metals, particularly in urban environments. Heavy metals can easily attach to dust particles and be distributed in large areas. The objective of this study was to evaluate the status of major heavy metals in the atmospheric dust of Isfahan and adjacent cities. A total of 144 dust samples were taken during a period from August to December 2010 from Isfahan, Khomeynishahr, Falavarjan, Mobarake and Zarinshahr cities. Dust samples were extracted with HNO3 65% and the total concentration of metals including Pb, Zn, Cd, Cu, Ni, Co, Cr and Mn in the samples was measured by an atomic absorption spectrometer. The mean concentration of these metals was 223.5, 470.3, 3.5, 71.0, 82.0, 26.5, 24.4 and 426.3 mg kg-1, respectively. Results indicated that heavy metals concentration in any area was different depending on the source of pollution and it was much higher than the mean concentration of the corresponding heavy metal in soils. Besides, the highest deposition rate of all the heavy metals in this study was found in November-December period. This could be attributed to an increase in the use of heating systems and also to a temperature inversion event prevailed in the area. Atmospheric deposition seems to be an important pathway of heavy metals addition to soils. For example, it is responsible for 35-91% and 12-47% of Pb and Cd entering the soil in the area, respectively.
H. Hatami, A. Karimi, A. Fotovat, H. Khademi,
Volume 18, Issue 69 (fall 2014)
Abstract
Organic acids play an important role in improving the bioavailability of soil nutrients. The objectives of this study were to determine the effect of oxalic acid on the release of soluble, exchangeable and non-exchangeable forms of K from micaceous minerals and potassium feldspars, and also to investigate the trend of K release by time. A laboratory study was carried out using a completely randomized design with two replicates. Biotite, phlogopite, muscovite, Zanjan and Yazd K-feldspars (< 50 μm size) were treated with 0, 10 and 100 mM of oxalic acid solutions for a period of 5 hours and 20, 60 and 90 days. The amount of K was determined by flame photometer. The results indicated that most amount of soluble, exchangeable and no-exchangeable K was released by 100 mM of oxalic acid. The maximum soluble K (0.86 gKg-1) was released from phlogopite, and the maximum exchangeable and non-exchangeable K (1.5 and 29.6 gKg-1, respectively) were released from biotite. Muscovite with 0.19, 0.34 and 1.41 gKg-1 of soluble, exchangeable and non-exchangeable K, respectively, had the lowest release of K among the studied minerals. The kinetics K release from minerals consisted of two phases. The first phase was relatively rapid and then it had a slow rate until the end of the experiment. Given that the applied concentration of organic acid was high, potassium release during the experiment period did not reach the steady state. Therefore, a longer period of release experiment is suggested.
F. Jafari, H. Khademi,
Volume 18, Issue 70 (winter 2015)
Abstract
Dust deposition occurs extensively in arid and semiarid regions of the world. Since dust particles are fine-sized, they have a high adsorption capacity and also high contamination potential. The objective of this study was to evaluate the temporal and spatial distribution of the rate of atmospheric dust deposition in different locations in Kerman urban area. Dust samples were collected monthly using glass traps installed on the roof of 35 one-story buildings in Kerman for 7 months from April 20 to Nov. 20, 2012 (a total of 245 samples). After each monthly sampling, traps were washed and dust samples transferred to the laboratory and weighed. The mean dust deposition rate of 7 months was mapped using the inverse distance weighting (IDW) approach. The wind rose of Kerman was drawn by WRPLOT 7.0.0. The results showed that the average rate of dust deposition decreased during the 7 months studied from 17.4 to 5 g/m2. month, which could be attributed to the decrease in wind velocity. The spatial distribution of the samples also showed that the dust deposition rate varied from 4.84 in the southern parts to 14.84 g/m2.month, mostly in the northern locations of the city. The wind rose based on the average wind speed of the 7 months of sampling indicated the prevailing wind blows from north, northeast and northwest and the dust spatial distribution well follows the wind direction. In general, the rate of dust deposition in Kerman city is high and therefore, the source of dust has to be well detected and proper management practices are necessary.
M. S. Mousavi Dastenaei, H. Khademi,
Volume 18, Issue 70 (winter 2015)
Abstract
Few investigations have been carried out on the ability of different plants to take up non-exchangeable potassium (K). The objective of this investigation was to examine the ability of different alfalfa cultivars to absorb K from phlogopite. An experiment was carried out with a completely randomized design with 3 alfalfa cultivars including Pickseed 2065 (MF), Rehnani (R) and Hamadani (H) grown in a quartz sand medium containing <53 micron sized phlogopite under complete and K-free nutrient solutions for a period of 6 months. During the growth period, the shoot was harvested 4 times. At the end of the experiment, the root was also separated from the growth medium and collected. Plant samples were extracted using the dry ash method and their K concentration was determined. Under the K-free nutrient solution, the highest shoot and root K concentration and uptake were found for the MF cultivar. The shoot and root K concentration in this cultivar were respectively 1.6 and 1.5 times higher than those in the R cultivar and 1.8 times greater than those in the H cultivar. The K uptake in the shoot and root of the MF cultivar was respectively 1.6 and 1.9 times higher than that of the H cultivar and 1.6 and 1.5 times higher than that of the R cultivar. Thus, in addition to other parameters, the type of plant variety should be taken into account when K requirement is evaluated.
F. Khayamim, H. Khademi, B. Stenberg, J. Wetterlind,
Volume 19, Issue 72 (summer 2015)
Abstract
Vis-NIR spectroscopy has been introduced as a non-destructive, fast, and cheap technique, with minimal sample preparation and no loss or damage to the environment. No investigation has yet been carried out to examine the ability of this method to estimate soil properties in Iran. The objective of this research was to investigate the capability of Vis-NIR spectroscopy to predict the amount of organic matter, carbonate and gypsum in surface soils of Isfahan province. A total of 248 surface soil samples were collected from the study area. Soil organic matter content, gypsum and carbonates percentages were measured by standard laboratory methods. Soil spectral analyses were performed by a field spectrometer using 350-2500 nm wavelength range. Different pre-processing methods were evaluated after recording the spectra. Partial least squares regression was used to predict soil parameters. R2 values for organic matter, carbonates and gypsum were 0.61, 0.45 and 0.8, respectively. Based on RPD (Ratio of Prediction to Deviation) values, the precision of prediction model for gypsum was quite good, and acceptable for organic matter, whereas the prediction of the model for soil carbonates was poor. Consequently, vis-NIR spectroscopy is capable of predicting some soil properties simultaneously and the model accuracy is acceptable.
S. Norouzi, H. Khademi,
Volume 19, Issue 72 (summer 2015)
Abstract
Spatial and temporal distribution of dust deposition rate (DDR) in Isfahan city and the influencing climatic parameters were studied. Dust samples were collected using glass trays placed on the roof of one-story buildings from 20 sites in Isfahan city for 12 months. Climatic data were obtained from Meteorological Organization and analyzed. The highest and the lowest amount of DDR in agreement with the direction of prevailing wind were observed for dry months with eastern and northeastern wind directions and wet periods with western and southwestern wind directions, respectively. This can indicate dust emission from the desert located in eastern part of Isfahan city. Statistically significant inverse correlation between DDR and precipitation and relative humidity, and significant and positive correlation of DDR with Min and Max temperatures in all the studied months and also with Max and average wind speed for dry sampling months may well justify the temporal distribution of DDR in the city. In dry months, finer particles from eastern desert can be transported a longer distance and deposited in the western part of the city, far from the source area. In wet seasons, however, soil aggregates become coarser as a result of particle adhesion. This, in turn, results in the deposition of dust near the source area as the transporting power of dust reduces.
Sh. Ahmadi Doabi, M. Afyuni, H. Khademi, M. Karami,
Volume 20, Issue 76 (Summer 2016)
Abstract
Heavy metals in dust can directly enter to the human body through ingestion and inhalation. They can pollute the water and soil resources via atmospheric precipitation and accumulate in the plant tissues and then enter human body through water and food. This research aimed to study the heavy metals concentration in dust in Kermanshah province and to identify their sources. 49 samples of dust were collected in the cities of Kermanshah, Songhor, Gilangharb, Ghasre-Shirin, Sahneh, Sarpolzahab, Kangavar, Paveh and Javanrood during the spring 2013. The concentration of Zn, Cu, Ni, Cr, Mn and Fe were determined using an atomic absorption spectrometer following the sample extraction with a mixture of HCL and HNO3 (3:1 ratio). The average concentrations of Zn, Cu, Ni, Cr, Mn and Fe were 182.3, 48.6, 115.3, 73.9, 428.1 and 23161 mg kg-1, respectively. Correlation, cluster and principal component analyses were used to identify probable natural and anthropogenic sources of contaminants, and the enrichment factor was used to identify probable effects of human activity on the concentration of heavy metals. The results indicated that metal concentrations, except for Fe and Mn, were higher in comparison with the world soils. Zn, Cu, Ni and Cr are mainly of anthropogenic origin, while Fe and Mn are mainly of natural origin. Zn and Cu are mainly of traffic sources and partly of industrial sources, and Ni and Cr are mainly derived from industrial sources, combustion processes, combined with traffic sources. The analysis of EF revealed moderate enrichment for Mn and Cr, and significant enrichment for Zn, Cu and Ni. Based on the results of this study, more attention should be paid to identifying and controlling the sources of contaminants such as heavy metals in dust in order to prevent their associated pollution.
F. Jafari , H. Khademi,
Volume 21, Issue 1 (Spring 2017)
Abstract
Dust deposition phenomenon is an important climatic and environmental issue in arid and semi-arid regions. The objective of this study was to examine important characteristics of atmospheric dust in Kerman as one of the major cities in arid areas of our country with high potential of dust production. Dust samples were collected monthly using glass traps installed on the roof of 35 one-story buildings in Kerman for 7 months from April 20 to Nov. 20, 2012. To compare the results of atmospheric dust with those of soil, 60 surface soil samples (0-10 cm) from outside Kerman and 35 soil samples from urban areas were also collected. Some physical and chemical characteristics such as pH, electrical conductivity, organic matter, calcium carbonate equivalent, and particle size distribution were determined in dust and soil samples. The results of chemical analyses indicated that the amount of these properties is much higher than that in soils. Atmosphere dust particles appear to mainly originate from alkaline and saline soils surrounding the city of Kerman. Dust particle size distribution analysis further confirmed that dust particles have been transferred to Kerman city from medium to long distance areas. Temporal variability in dust chemical properties indicates that the contribution of anthropogenic and natural sources to urban dust in Kerman has seasonal changes. Based on the results obtained, it is necessary to control dust production outside and inside the city and its distribution in populated areas employing proper management practices.
M. Najafi-Ghiri, Y. Kiassi, F. Khademi, A. R. Mahmoodi, H. R. Boostani, Dr M. Mokarram, M. J. Gholami,
Volume 22, Issue 3 (Fall 2018)
Abstract
Little information is available regarding the effect of road on the adjacent vegetation and soil. The current investigation was done to study the effect of Darab-Bandar Abbas road on vegetation, soil properties and nutrient availability of the adjacent soils. For this purpose, eighteen soil samples in three different regions from the roadside and the adjacent land (50m from the road edge) were collected and the vegetation type and density were determined. Soil properties and the availability of N, P, K, Fe, Mn, Zn and Cu were also determined. Roadside soil had more organic matter and sand contents and less clay content and pH in comparison to the adjacent lands. The mean contents of N, Fe, Zn and Cu available in the roadside soils were 0.13%, 4.2, 3.2 and 0.7 mg kg-1, respectively; these were significantly more than those of the adjacent lands (0.06%, 2.8, 0.6 and 0.3 mg kg-1, respectively). Vegetation of roadside was more varied, consisting of Artemisia sieberi and Astragalus fasciculifolius. Vegetation cover in the roadside (13.8%) was significantly more than that of the adjacent lands (8.5%). Generally, it could be concluded that roadside soils had a suitable moisture condition and fertility for the vegetation development and this could be considered in the soil conservation management of the roadside soils.
M. Zeraatpisheh, Sh. Ayoubi, H. Khademi, A. Jafari,
Volume 23, Issue 1 (Spring 2019)
Abstract
Landscapes are considered as a series of different land units with a size, shape and location arrangement that are permanently under the influence of natural events and human activities. Understanding the dynamics and heterogeneity of landscapes and environmental changes is of great importance. In order to quantitatively analyze and interpret the factors affecting the changes in the environment and terrain diversity, diversity indices were used to analyze the ecosystem. In this study, the relationships between soils evolution and geomorphic surfaces were investigated by applying pedodiversity indices in a part of a semi-arid region of Chaharmahal-Va-Bakhtiyari Province. In the studied area, three orders were recognized: Mollisols, Inceptisols, and Entisols. The results showed that soil evolution in the studied area was mostly influenced by topography, parent material and the underground water level; that is, in the higher lands, the lowest evolution was observed while in the plain ones, the soil of the higher evolution observed. In addition, the effect of geomorphic surfaces were obvious. Pedodiversity indices increased under the decrease of the hierarchy levels. In addition, the obtained equations revealed the nonlinear relationships in the area of geomorphic surfaces. The positive and nonlinear relationship between pedodiversity indices confirmed the nonlinear dynamic system in the studied soils.
V. Shahrokh, H. Khademi, H. Shariatmadari,
Volume 23, Issue 2 (Summer 2019)
Abstract
Despite the great importance of potassium applied as a fertilizer in the orange orchards, no information is currently available regarding the rate of potassium release from rhizosphere and the bulk soils of such trees. The objectives of this study were to investigate the weathering of micaceous minerals and their non-exchangeable K release and also, to examine the status of different forms of K in the rhizosphere and bulk soils of orange orchards with different ages in Darab, Fars Province. Samples were, accordingly, taken from the rhizosphere and bulk soils of orange orchards with the ages of 5, 10 and 20 years; also, virgin soils (control) were obtained from three soil depths including 0–30, 30–60, and 60–100 cm. Water soluble, exchangeable and nonexchangeable K, and the clay mineralogy of the soils were determined. The results demonstrated that the concentration of soluble and exchangeable K in the cultivated soils was less than that in the control soil and that the concentration of nonexchangeable K in the soils of 20-year-old orchards was less, than that in other soils. Soluble and exchangeable K values decreased with depth in all soils. Clay mineralogy investigation also showed that the quantity of illite decreased and that of smectite and illite-smectite increased as the age of orange trees was raised. With increasing the age of orange trees and root development, more potassium could be taken up from soil and more changes occurred in the soil minerals. In order to avoid a very high decline in the reserved K in the soils under orange trees, particularly in the orchards with older trees, K fertilization has to be taken more seriously based on the soil testing results.
F. Jafari, H. Khademi, H. Shariatmadari, S. Ayoubi,
Volume 23, Issue 4 (winter 2020)
Abstract
The production of compost and vermicompost from manure and different organic residues and also, their enrichment with some fertilizers and other treatments have been extensively investigated. However, no study has yet been conducted on the enrichment of composted and vermicomposted manure with clay minerals. This research was, therefore, carried out to investigate the selected properties of phlogopite enriched manure during the composting process with and without earthworm activity. The experiment was conducted in plastic containers with the lid under an average temperature of 27.5°C and the humidity of 42.5% using a factorial arrangement in a completely randomized design with 3 replications. Factors included levels of phlogopite addition (0%, 20% and 40% by weight), with or without the earthworm Eisenia fetida for different time periods of 1.5, 3, 4.5 and 6 months. At the end of the experiment, the total of organic carbon, nitrogen, potassium, magnesium, and iron, as well as the contraction the available magnesium, potassium and iron, was determined. The results showed that the percent of organic carbon was decreased while the total nitrogen, the total and available potassium, iron and magnesium were increased with time. The results also indicated that a significant percentage of the total content of the elements in all treatments without phlogopite was available. However, in treatments containing phlogopite, the amount of the available elements was increased slowly with time. This was Due to the weathering of phlogopite mineral and the decomposition of manure. In general, it seems that the enrichment of composted and vermicomposed manure with phlogopite can guarantee the supply of nutrients such as potassium, iron and magnesium in a longer period, as compared with the ordinary composts.
R. Rezaeinejad, H. Khademi, Sh. Ayoubi, H. Jahanbazy Goujani,
Volume 24, Issue 2 (Summer 2020)
Abstract
In arid and semi-arid ecosystems, isolated trees significantly influence the soil properties and can have a great impact on the soil fertility as well as the conservation and improvement of soil quality. This investigation was conducted to examine the influence of wild almond (Amygdalus arabica Olive.) trees having different ages on the physical and chemical soil properties. Soil samples were taken from the depths of 0-20, 40-60, 80-100 and 120-140 cm at two distances from the tree crown including the basal area (referred to as the rhizosphere) and the canopy edge in 3 replications for the 30, 50, and 130 year-old stands and also, in a control site, all in the Anjarak area, southeast of Baft city, Kerman Province. Soil properties including pH, EC, organic matter, calcium carbonate equivalent, available and non-exchangeable potassium and soil texture were measured in all samples. The results indicated that the measured soil properties in different depths in the study area had been influenced by the age and the canopy size of the wild almond trees. The highest and the lowest amount of pH were found in the control soil and the soils covered by 130 year-old trees, respectively. Besides, the electrical conductivity of the soil under the tree crown was more than that of the soil in the canopy edge. The accumulation of C, N, and other nutrients under the tree canopies resulted in the creation of fertility islands surrounding the trees. Furthermore, the soil physical and chemical properties were greatly improved with the increase in the tree age of Amygdalus arabica Olive. As the conclusion, wild almond trees could have very positive effects on soil properties. Therefore, it is essential to protect the trees. Otherwise, the risk of soil quality reduction would be increased and soils might become more susceptible to soil erosion.
F. Khayamim, H. Khademi, S. Ayoubi,
Volume 24, Issue 2 (Summer 2020)
Abstract
Understanding the abundance of clay minerals in soil and also, their spatial variability can provide more comprehensive information about soil properties, behavior and functions. The objectives of this research were: (i) to map the spatial distribution of the dominant clay minerals in the soils of Isfahan Province and its relationship with climate and parent materials, and (ii) to determine the quantity of the dominant clay minerals in different climatic classes of Isfahan Province. The amount of palygorskite, illite, expanded minerals and chlorite were semi-quantitatively determined for 100 soil samples collected from Isfahan Province. Maps of the dominant clay minerals were prepared by the Inverse Distance Weighting method. The results showed that palygorskite mostly occurred in the soils of dry areas with higher temperature throughout the province. This mineral was not present in the more humid areas of the province. Besides, palygoskite was found to be dominant in the soils derived from the Qom Formation, as well as Lower and Upper Red Formations belonging to Miocene and Pliocene. It seems, therefore, that the parent material plays a major role in entering palygoskite to the soil system, while the dry climate mostly guarantees the stability of this clay minerals and, to some extent, its limited neoformation in such soils. Both illite and chlorite occur in all soils throughout the province, regardless of their climate, following no particular trend. This may indicate that parent materials play a major role in the occurrence of these minerals. Both climate and parent material appear to have affected the distribution of expandable clays in the soils. In more humid areas of the province (west and southwest), climate plays a larger role in the distribution of this mineral. In other areas of the study region, especially in the eastern parts of the province with a much drier climate, the role of the parent material on the dominant soil clay minerals is more pronounced.
B. Akbari, H. Khademi,
Volume 27, Issue 4 (Winter 2023)
Abstract
Street dust enters the urban environments due to the resuspension of particles smaller than 100 micrometers. The magnetic properties of street dust and their relationship with the concentration of heavy metals have received less attention from researchers worldwide, and not much study has been performed on this issue in Iran. The objectives of this study were: (i) to investigate the spatial and seasonal changes in street dust, and (ii) to determine their relationships with the concentration of selected heavy metals in several cities in the Isfahan province. Sampling was carried out in the first half of the second month of each season including 20 samples from Isfahan city and 10 samples from Natanz, Shahreza, Falavarjan, Khomeinishahr, and Najafabad. The concentration of selected heavy metals was measured using an atomic absorption spectrometer. Also, the magnetic susceptibility values of the samples at low and high frequencies were determined and frequency-dependent magnetic susceptibility was calculated. The results showed that the presence of ferromagnesian minerals in the parent materials could be the reason for the high values of magnetic receptivity in Natanz City. However, the high level of this characteristic in the street dust of other cities could be due to human activities, especially in Isfahan city. Based on the results of principal component analysis, the high correlation of the first component with magnetic susceptibility and the concentration of zinc, copper, and chromium elements most likely indicates the absorption of these elements by particles close to superparamagnetic (SP). The high correlation of the second component with frequency-dependent magnetic susceptibility and concentration of nickel and cobalt is most likely related to the adsorption of magnetic elements and heavy metals into coarse polyhedral particles that remained on the street floor after the re-deposition of street dust particles. Also, the high correlations between magnetic parameters and the concentration of copper and zinc confirm their anthropogenic origin. On the other hand, low or negative correlations of Pb, Ni, Cr, and Co concentrations with magnetic susceptibility might confirm their natural or non-anthropogenic origin. The higher values of magnetic parameters of street dust in the spring season reflect the significant contribution of magnetic minerals in this season, compared to autumn and winter, and indicate the higher influence of human activities.
Z. Naderizadeh, H. Khademi, A. Shamsollah,
Volume 28, Issue 1 (Spring 2024)
Abstract
Although several reports are available on the distribution of Palygorskite in the soils of arid regions of Iran, there is not much information about the presence and abundance of this important fibrous clay mineral in the soils of Bushehr Province. This research was carried out: (1) to investigate the distribution of Palygorskite and other major associated clay minerals, and (2) to evaluate the relationship between the relative quantity of Palygorskite in clay-sized fraction and the most important soil properties in Dashtestan County, Bushehr Province. Five geomorphic surfaces including eroded rock outcrop, rock outcrop, dissected hill, alluvial fan, and alluvial plain were identified in the study area using Google Earth images and field observations. After sampling representative pedons, the clay mineralogy of two horizons from each pedon was determined. X-ray diffractograms and SEM images showed that in the studied soils, which were classified as either Aridisols or Entisols, Palygorskite was present in different quantities on all geomorphic surfaces. Moreover, Illite, Chlorite, Smectite, irregularly interstratified Chlorite/Illite, and Kaolinite were the other clay minerals that existed in the soils studied. The relative quantity of Palygorskite and Smectite was variable on different geomorphic surfaces. Regardless of the type of geomorphic surface, petrogypsic and gypsic horizons showed the highest quantity of Palygorskite as compared to other horizons which seems to be due to the suitable geochemical conditions of these horizons for the formation and stability of Palygorskite mineral. The higher correlation of Palygorskite content with gypsum, as compared to that with the carbonates, indicates the importance of gypsum in Palygorskite distribution in the soils of the study area. The findings also indicated that the amount of Palygorskite was positively correlated with soluble Mg/Ca ratio, pH, gypsum, and soluble Mg. These parameters appear to control the genesis and distribution of Palygorskite in the soils studied. In general, it is necessary to pay special attention to their clay mineralogy, especially the significant amount of Palygorskite to manage the soils of the study area and to reasonably predict their behavior.
