JWSS - Journal of Water and Soil Science

Phytoremediation is one of the best methods for cleaning heavy metal contaminated soils. In this method, tolerant plants with high absorption potential are used to clean up the pollutant. The purpose of this greenhouse study was to find the most suitable plants with the highest Zn translocation factor and shoot concentration. Soil samples were collected from zinc and lead Bama mine in Isfahan province, Iran. To compare the hytoextraction power, Heliantus annus.L., Thlaspi caerulescens, Trifolium pretense L. and Amaranthus retroflexus were planted in 8 kilogeram pots. The experiment was conducted in completely randomized design with three replications. After seventy days, plants root and shoot were harvested and Zn concentration was measured. The result showed that Thlaspi caerulescens had significantly higher root and shoot Zn concentration (3125 and 4041 mg kg-1, respectively). The highest bioaccumulation factor and translocation factor was observed in Thlaspi caerulescens. Based on this research, Thlaspi caerulescens was one of the suitable Zn hyper accumulators for cleaning up the Zn pollution.

Advance velocity is an important factor in surface irrigation system design and simulation. Volume balance is a simple model based on continuity equation used in surface irrigation design and management. In the past volume balance models, it is generally assumed that the upstream depth of surface water is constant and equal to normal depth. This initial assumption may cause significant errors in computing advance flow. In this paper, a modified volume balance (MVB) model is developed to predict the advance curve in furrow irrigation. In the suggested method the upstream surface, water depth is actual depth and variable in time. Predicted advance distance of VB, VB-ZI and MVB was compared to the observed data obtained for the three furrow lengths of 60, 80 and 90m. Evaluation indexes indicated that the modified volume balance equation is more accurate than the previous equations by RMSE 9.26, 7.37 and 6.76 respectively. Sensitivity analysis showed that the inlet discharge has the greatest effect on the model and the model is more sensitive to decreasing the discharge amount than to increasing it

Fine-grained materials of Clayey Loess deposits of Gorgan region were mixed with sand dune in the lab with various rations and their shear behavior was measured and evaluated by direct shear test. The result of the study showed that the increase of fine-grained clay in sand dune was directly related to the adhesion force and inversely to the internal friction angle. The increase or reduction in shear strength was affected by the fine-grain percentage. Dry condition and saturation of the test and sand dune had a less influence on shear parameters but in the mixed samples in dry condition and saturation, shear parameters revealed a considerable difference. The results of this study can be used in sand stabilization, erosion prevention, slope stability, embankment construction, compaction increase, and environmental pollution, and dust and water channels avoidance.

Organic fertilizers affect soil chemical and physical properties, particularly chemical forms of zinc in soil solid phase and thereby improve soil Zn availability. The present field study was aimed to evaluate the effects of organic and chemical fertilizer (zinc sulfate) on different zinc fractions in soil solid phase of rhizosphere in two successive years in Rudasht Research Field, Isfahan. Treatments consisted of sewage sludge (5 and 10 t ha-1), cow manure (5 and 10 t ha-1), and ZnSO4 (40 Kg ha-1). The control had no added Zn. Three weeks after applying fertilizer treatments, Back Cross genotype of wheat was cultivated in each plot. Our results showed that the organic fertilizers increased Zn concentration in exchangeable fraction (EXCH-Zn), the organically bound Zn form (ORG-Zn), and Zn bound to iron and manganese oxides (FeMnOX-Zn). However, the changes in Zn fractions were dependent on the fertilizer type. Positive and significant correlation between EXCH-Zn, ORG-Zn, and FeMnOX-Zn, and the total Zn uptake by wheat indicated that these pools of Zn in solid phase are labile pools with a significant role in supplying Zn for plants.

Management of organic and inorganic treatments may have positive or negative effects on soil quality, plant growth and human nutrition. The objectives of this study were to determine the effects of organic and inorganic zinc fertilizer application on soil quality indicators and wheat yield. This research was conducted at Agricultural Research Station Roudasht, Isfahan, Iran. Sewage sludge and cow manure (5 and 10 t/ha), ash rubber (1 t/ha), powder rubber (200 kg/ha), ZnSO4 (40 kg/ha) were applied and wheat was cultivated. Soil samples were collected at tilling and harvest stages. After taking samples and measurements of the soil parameters, we determined the critical limits for each category and class rating for the each soil parameters, and the soil quality index was calculated. The results showed sewage sludge and rubber ash were significantly effective in increasing soil bioavailable Zn compared to other treatments. Application of sewage sludge and cow manure at 10 ton/ha improved soil quality. The expanded soil quality index can help better understand the effect of fertilizers on soil. A positive and significant relationship between soil quality indicators and Zn uptake and wheat yields was also observed. Our results indicate that addition of 10 t/ha sewage sludge as fertilizer can significantly improve soil quality, supplying the necessary amount of Zn for wheat growth.

Zinc deficiency is the most widespread micronutrient disorder in the production of wheat (Triticum aestivum L.) and other cereal crops. An experiment was conducted in greenhouse, in 2013, using the sterile sand-perlite (2:1 v/v), to study the effects of two beneficial microorganisms on growth and nutritional status of wheat (Nicknejad cultivar). The study was arranged as factorial in a completely randomized design with three replications. The experimental factors consisted of Piriformospora indica (E0: Uninoculated E1: Inoculated), Pseudomonas putida (E0: Uninoculated E1: Inoculated) and Zinc (Zn0: 0 Zn1: 2µM ZnSO4 ). The results showed that inoculation by P. putida increased shoot dry weight at both levels of zinc, but this increase was observed for root dry weight only without zinc application. The iron concentration of shoot was decreased as a result of inoculation by P. putida at both levels of zinc. However, P. indica inoculation increased iron concentration in zinc application, but had no significant effect without zinc application. At both levels of zinc, the highest P, Zn, chlorophyll a and b concentrations were achieved by inoculation with P. indica. Inoculation by P. putida reduced P concentration at both levels of zinc but it reduced Zn, chlorophyll a and b concentrations only with zinc application. The results of this research showed that despite negative effect of P. putida on nutrient uptake, inoculation by P. putida and/or P. indica plays an important role in the promotion of wheat growth in zinc deficiency conditions.

Consequences of heavy metal accumulation in soils are of great concern. One way of decontaminating heavy metals from soils is using chelating agents, particularly EDTA. In this research, three contaminated soils (with total concentration of these metals of 10.5, 55.8 and 80.6 mmol kg-1) were collected from the surface layer of the lands surrounding a zinc-lead smelting plant in Zanjan province. The extent of Zn, Pb and Cd release by Na2H2EDTA (100 mmol kg-1 of dry soil) from these soils in column leaching experiments (both continuous and pulse addition methods) assembled into half of saturated hydraulic conductivity was assessed. In preliminary experiments, the leaching was stopped due to a drop in hydraulic conductivity. Therefore, the continuous addition method was performed with calcium nitrate as the background solution and the pulse addition method was conducted using this background solution coupled with pH adjustment to 8. Based on the results, the percentage removal of Cd as well as Pb was relatively the same for the two addition methods while the removal of Zn was 13% on average higher in the continuous addition method than in the pulse addition method. For both methods, the removal efficiencies followed the order of complex stability constants (as Pb>Zn>Cd) in a limited concentration range of EDTA to complex heavy metals. Furthermore, in contrast to Cd and Pb, a direct linear relationship was found between the percentage removal of Pb and its total amount in the soils. Surprisingly, the Pb concentration was on average only about one-twentieth of the Zn concentration. The breakthrough curves of both methods showed the mobility order of Cd>Zn>Pb. In general, it seems that the removal pattern of soil heavy metals is dependent not only on the soil type but also on the removal method.

This study was conducted to determine some mineral content concentration in soil and plant of three elevation classes (1500, 2200 and 3000m) and two phenological stages of flowering and seedling start in north-facing slopes of Sabalan rangelands. Soil samples from the depth of 20cm and plant samples using 1×1m plots with 10 replications were collected. After sample preparation, the concentrations of minerals such as calcium, phosphorous, sodium, potassium, ion, copper, zinc and magnesium were determined using spectrophotometer and flame photometer. Data was analyzed by SAS9.1 software using Completely Randomized Design with a Generalized Linear Model procedure. Results showed that elevation had a significant effect on Ca, Fe, Cu, Zn and Mn of soil and P, Na, K, Mg and Mn of plants in the study areas (P&le0.05). Growing stages had a significant effect on all elements of plants except Ca (P&le0.05). Moreover, results showed that in three elevation classes the high demand minerals’ concentration was higher at the starting seedling stage in comparison with the flowering stage. In contrast, the low demand minerals’ concentration in three elevation sites was higher in the flowering stage in comparison with seedling stage. Interaction effect of elevation and growing stage was also significant in relation to all elements except Ca (P&le0.05).

Zinc (Zn) is one of the essential micronutrients for plant growth and its deficiency frequently occurs in calcareous soils. But, a suitable extractant for estimation of plant-available Zn in calcareous soils, amended with sewage sludge, has not been presented yet. The aim of this research was to assess several chemical extractants (7 extractants) for estimation of available Zn in calcareous soils amended (1% w/w) and unamended with sewage sludge. Results showed that Mehlich 3 and Mehlich 1 extractants extracted the highest and the lowest concentrations of Zn in both amended and unamended soils, respectively. All wheat indices (wheat yield, Zn concentration and Zn uptake) increased by sewage sludge addition. Besides, the results indicated that in unamended soils, significant correlations were found (r=0.65^*- 0.91^**) between extracted Zn using AB-DTPA, DTPA-TEA and Mehlich 3 extractants and different wheat indices. On the contrary, in sewage sludge-amended soils, only the correlation between extracted Zn using Mehlich 2 and Zn concentration was significant (r=0.83^**). According to this study findings, the suitable extractant for extracting wheat-available Zn is thoroughly different in calcareous soils amended and unamended with sewage sludge.

In order to assess the status of the iron (Fe) chlorosis of plane trees in green space of Isfahan city, the chlorosis intensity of 73 trees in different regions was recorded as (1): low (less than 5% of leaves), (2): moderate (less than 50% of leaves), (3): severe (more than 50% of leaves), and (4): very severe (more than 95% of leaves). The whole leaf (with petiole) samples were taken from the top and bottom of each tree, separately, during 2008 and 2009. Then selected chemical properties of the leaves were analyzed.  The results showed that in more than 95 and 71% of the young leaves, Fe concentration was less than the critical deficiency level (202 mg/kg). Concentration of Fe in the older leaves of all plane trees even those with slight symptoms of chlorosis was less than the critical level (382 mg/kg). No significant relationship was found between the leaf zinc concentrations and intensity of iron chlorosis. In more than 92 (in the first year) and 87% (in the second year) of the plane trees, Zn concentration of young leaves and in all trees, Zn concentration of old leaves were less than the critical deficiency concentration (23 mg/Kg). The comparison between concentrations of Cu in the leaves with its critical deficiency level showed that more than 90% of young and old leaves accumulated toxic levels of Cu in both sampling years. In regard with the sufficient range of P, about 79% of the trees in the first year and 53% in the second year accumulated excess levels of this nutrient in their young leaves. This condition was slightly modified for the older leaves so that excessive concentration of phosphorus in mature leaves was not observed in the first year and in the second year, only about 29% of the samples had concentrations higher than critical levels. 

In this study, two different approaches of infiltration parameters estimation in traditional, variable and fixed alternate furrow irrigation, with and without cutback inflow, were performed and compared. Four usual methods including two-point (Elliott and Walker), Valiantzas one-point, Mailapalli one-point and Rodriguez and Martos optimization methods, as approaches based on advance data, and multilevel optimization method as an approach based on the advance, storage and recession data, were considered. Surface irrigation model: WinSRFR was used to simulate irrigation phases and infiltration value in each method. 13 furrow irrigation field experiments, from two case studies: Karaj and Urmia, were used to perform different methods. Based on the results, the multilevel optimization method predicted the advance and recession phases and runoff-infiltration with high accuracy for traditional, variable and fixed alternate furrow irrigation. The multilevel optimization method for traditional furrow irrigation, showed more accuracy than variable and fixed alternate furrow irrigation in advance and recession phases and the average root mean square error (RMSE) for predicting advance phase for the three furrow irrigation methods was 1.37, 1.8, and 1.57 minutes and for the recession phase was 3.76, 5.0, and 3.03 minutes, respectively. Also the multilevel optimization method for cutback options indicated high performance to advance and recession prediction and the average RMSE of advance and recession prediction were obtained 3.57 and 2.13 minutes for cutback option and 3.8 and 1.3 minutes for no cutback option, respectively. The multilevel optimization method indicated high performance in storage phase, too. The average of relative error (RE) of runoff estimation for traditional, variable and fixed alternate furrow irrigation was calculated 0.5, 0.4 and 0.4 percent, respectively. The runoff average RE of multilevel optimization method with cutback and no cutback option were obtained 1.85 and 0.85 percent, respectively; that showed high performance of this method for no cutback option in comparison with the cutback option. Therefore, the use of data of all irrigation phases to estimate infiltration parameters shows better performance in the prediction of irrigation and water balance components. (run-off and infiltration).

Recent urban development and population growth in Shahrood tend to adopt a strategy for ground water management. This project, which is a descriptive- analytic type study based on field observation and laboratory analysis, aims to delineate proper sites for groundwater artificial recharge using integrated AHP-TOPSIS.  First, the study area was delineated using remote sensing techniques. Then, appropriate criteria including 5 main criteria and 12 sub-criteria were obtained by field observation and literature review. Then, the appropriate sites for groundwater recharge were determined. The process of the used method consists of designing hierarchical structure of the project, preparation of pairwise comparison matrices, weighting criteria and sub criteria values by experts, and ultimately ranking them by TOPSIS method. Results showed that lithology, slope, water table depth, and land use have the main role in sites delineation. A number of control sites were employed for model validation that indicates 87.20 percent accuracy. Overally, 73.6 and 82.12 percent of the total area were grouped as very suitable and suitable classes, respectively.