Showing 25 results for کادمیم
M Davari, M Homaee, H Khodaverdiloo ,
Volume 14, Issue 52 (7-2010)
Abstract
Phytoremediation is a new, in-situ and emerging remediation technology for contaminated soils. This technology, compared to other methods, is a sustainable, natural, relatively cheap and applicable to large scale area. Modeling phytoremediation provides quantitative insight for the governing process as well as for managers to assess the remediated sites. The objective of this study was to introduce a macroscopic phytoremediation model for Ni and Cd- polluted soils. The proposed model assumes that relative transpiration reduction function can resemble total soilNi and Cd concentrations. Combining the related functions of soil and plant responses to soil Ni and Cd concentrations, the phytoremediation rate of Ni and Cd was predicted. In order to test the proposed model, large quantities of soil were thoroughly polluted with Ni and Cd. Upland Cress (Lepidum sativum) and Ornamental Kale (Brassica olerace var. Viridis) seeds were then germinated in the contaminated soils. The experimental pots were irrigated with fresh water to reach field capacity. Upland Cress and Ornamental Kale were harvested three and four times, respectively. At each harvest, relative transpiration, Ni and Cd contents of soil samples and plants were measured. Comparison of the maximum error, root mean square error, coefficient of determination, modeling efficiency and coefficient of residual mass indicated that the non-threshold non-linear model provide high efficiency to predict relative transpiration for Upland Cress and Ornamental Kale, respectively. The results also indicated that the proposed macroscopic model can well predict the phytoemediation rate of the Ni and Cd by Upland Cress (R2>0.83) and Ni by Ornamental Kale (R2=0.78).
T. Rahimi, A. Ronaghi,
Volume 16, Issue 59 (4-2012)
Abstract
Contamination of agricultural soils by heavy metals is a serious threat from both agricultural and environmental standpoints. Among heavy metals, cadmium (Cd) toxicity for humans and plants is of great concern due to its high mobility and phytoavailability in soil even at low concentrations. Opposite to Cd, Phosphorus (P) is an essential nutrient for plant growth. A greenhouse experiment was carried out in a completely randomized design to examine the influence of Cd, P and their interaction on the growth and chemical composition of spinach grown on a calcareous soil. Treatments consisted of four Cd levels (5, 10, 20 and 40 mg/kg soil as cadmium sulfate) and four P levels (0, 20, 40 and 80 mg/kg soil as mono-calcium phosphate) in three replicates. The results indicated that 40 mg Cd significantly decreased spinach dry weight by 47% but P application decreased detrimental effect of Cd on spinach dry weight. Also, phosphorus application significantly decreased Cd concentration in spinach aerial parts by 78%. Increasing Cd levels increased concentration of this element in spinach shoots. Addition of 40 mg Cd decreased P concentration by 21.5% in aerial parts. Zinc (Zn), manganese (Mn), calcium (Ca), and nitrogen (N) concentration significantly decreased with P application but increased concentration of sodium (Na). Cadmium application decreased Zn concentration but increased Ca, Na and N concentrations in spinach. Our tentative conclusion is that P application in P-deficient soils is probably effective in decreasing Cd concentration and the detrimental effect of Cd on spinach growth, indicating a negative interaction between these elements. Prior to any fertilizer recommendation, the results of this experiment should be verified under field conditions
M. Pirzadeh, M. Afyuni, A. H. Khoshgoftarmanesh,
Volume 16, Issue 60 (7-2012)
Abstract
This study was carried out to investigate zinc (Zn) and cadmium (Cd) concentration in paddy soil and rice grain produced in central and southwest Iran in relation to soil and plant factors, and their intake in peoples diet was also assessed. Rice crops and associated surface soils (0-30 cm) were collected from 136 fields in Isfahan, Fars and Khuzestan provinces. The result, showed the DTPA-Zn concentration in more than 50% of paddy soils was less than its critical deficiency concentration (2 mg kg-1). The grain Zn concentration in more than 54% of the rice samples was less than 20 mg kg-1. The measured Cd concentrations in paddy soils and edible part of rice exceeded the world health organization (WHO) value in more than 12% of the samples. By considering the average daily rice consumption of 110 g per capita, the Zn intake from rice consumption was estimated about 10% needed for female and male adult. Diet intake analysis did not indicate any excessive dietary intake of Cd when Cd mean of concentrations in rice grain was 0.04 mg/kg, but based on the results of risk analysis, it is more than safely level for contaminated rice.
R. Hamzenejad Taghlidabad, H. Khodaverdiloo, S. Rezapour, Sh. Manafi,
Volume 16, Issue 60 (7-2012)
Abstract
Soil contamination with heavy metals, including Cd and Pb, is of serious concern. The aim of this study was to investigate the efficiency of Atriplex verucifera, Salicornia europaea and Chenopodium album for simultaneous remediation of soil exchangeable sodium percentage and Cd and Pb contamination in two soils with different properties. Two soils, including a saline-sodic-calcareous (S1) and calcareous (S2) soil, were selected. Different concentrations of Pb and Cd were then added to the soils. The contaminated soils were incubated under a wetting-drying cycle for nearly seven months. The plants, seeds were grown in pots containing different treatments of polluted soils and in control treatment (no Cd and Pb contaminations). The plant yields and concentrations of Pb, Cd and Na in the soil and plant samples were measured. A considerable accumulation of soil Cd by Salicornia and Pb accumulation by Atriplex and Salicornia was observed under unsuitable conditions of the saline-sodic soil, whereas Atriplex and Chenopodium had high capability for Cd in the soil S2. Also these plants caused the reduction of ESP in soil S1. The results revealed that these plants could be used for remediation of Pb and Cd contaminated soils. In this study, Salicornia with lower rate of yield reduction had the highest tolerance to Cd-stress. Understanding the complex plant and soil (salinity-sodicity and soil metal concentration) factors controlling the metals concentrations in the plants will help to design phytoextraction technology for arid, salt-affected regions.
H. Alinezhad Jahromi, A. Mohammadkhani, M. H. Salehi,
Volume 16, Issue 60 (7-2012)
Abstract
Nowadays, due to drought and water shortage, use of unconventional waters, particularly sewage, has become usual in agriculture whereas they often contain heavy metals. The present study was employed to evaluate the effect of urban wastewater of Shahrekord on growth, yield and accumulation of heavy metals (lead and cadmium) in balm (Melissa officinalis) as a medicinal plant with five treatments (0, 25, 50, 75 and 100 percent wastewater) and three replications in a completely randomized experimental design. The results showed that the highest shoot length, stem diameter and stem number, number of leaves and tillers are achieved in the treatment of 100 percent. The wet and dry weight of shoots and roots was highest in 100 % of wastewater. Oil percentage of the leaves was also the highest amount (1.23 %) in 100 % of wastewater. Accumulation of lead in roots and aerial parts and its transmission factor was not significant for the treatments. However, the highest concentration of lead in root (0.057 mg/kg) and shoots (0.013 mg/kg) was observed in 100 % of wastewater and the lowest one was related to zero percent of wastewater treatment. The lead concentration was less than the critical limit for all the treatments. The amount of cadmium was undetectable in all the plant samples. The results of this study demonstrated that urban wastewater of Shahrekord, in addition to providing water, increases plant growth and essential oil.
S. Jafari, Z. Iranshahi , Gh. Fathi, S. A. Syadat,
Volume 16, Issue 61 (10-2012)
Abstract
Cadmium is a toxic element in plant nutrition and is considered as a contaminant of food and feed. A greenhouse experiment was carried out to examine the effects of combined application of cadmium and zinc on responses of wheat on a clay loam soil texture. This experiment was designed in a factorial experiment with randomized complete block design (RCBD) and four replicates per treatment. Three levels of cadmium (Cd 0, Cd 50 and Cd 100 mg kg-1) and three levels of zinc (Zn 0, Zn 50 and Zn 100 mg kg-1) were added to the pot in factorial(9 treatments), and then Chamran seed variety of wheat (triticum aestivum L.) was planted in each pot. The statistical analyses showed that Cd application significantly (P0.01) decreased grain, straw, and total yield, but Zn application increased these parameters significantly (P0.01). Application of Cd separately decreased the grain yield by 61.5 while application of Zn separately increased the grain yield by 36.9. Cd application increased the Cd concentration and uptake by grain and straw as well as total uptake but by increasing Zn application, Cd uptake was decreased by wheat. Cd concentration was higher in straw than that grain, but Zn showed a different trend. Decreasing Zn applications decreased total uptake of Cd from 42.9 in Zn0 to 7.8 mg kg-1 in Zn100 treatment. Although this soil was very calcareous, this characteristic did not control Cd absorbtion.
A. Madani, A. Lakzian, Gh. Haghnia, R. Khorasani ,
Volume 17, Issue 63 (6-2013)
Abstract
Mycorrhizal fungus colonization of roots may modify plant metal acquisition. In order to study the role of external hyphae of mycorrhizal fungi in metals transferring, the root and hyphal growth zone were separated by 30 µm nylon meshes. Plants were inoculated with G. mosseae and G. intraradices and grown in the root compartment. Six combinations of metals (400 mg of Zn, 25 mg of Cd, 400 mg of Zn + 25 mg of Cd, 50 mg P, 50 mg of P+ 400 mg of Zn + 25 mg of Cd, and no metal kg-1 soil sample) were added to the hyphal compartments. This experiment was carried out as a completely randomized design (CRD) with factorial arrangement in three replications. The results showed that dry shoot weight and phosphorus concentration in mycorrhizal treatments increased significantly compared with non mycorrhizal treatments. of the two fungal species, G. mosseae had more effect on phosphorus concentration in white clover plant. AM fungi increased the Zn concentration in shoot and root of white clover. AM fungi also significantly increased cadmium concentration in root of mycorrhizal treatments compared to non mycorrhizal plants. of the two fungal species, G. intraradices accumulated more cadmium in clover roots. ALL in all the results demonstrated that AM fungi increased phosphorus and Zn transferring to the shoots while cadmium transferring was decreased by stabilizing in the roots.
L. Divband, S. Boroomand Nasab, M. Behzad, J. Abedi Koupai,
Volume 17, Issue 65 (12-2013)
Abstract
Heavy metals in water resources are one of the most important environmental problems in most of countries. Up to now, various methods for removing these metals including using low price materials have been used. In this study, two new absorbents (zizyphus spinachristi leaf and its fly ash) were studied for adsorption of cadmium from aqueous solutions using batch experiments. The effect of contact time, pH, and amount of adsorbent on adsorption efficiency was evaluated and the best kinetic and isotherm model was determined. Results showed that optimal absorption of pH was 5 and 6 for zizyphus spinachristi leaf and its fly ash, respectively. The equilibrium time was 45 min for zizyphus spinachristi leaf and 30 min for ash. Adsorption efficiency was increased by increasing the adsorbent dose. By comparing the parameters of isotherm models, it was observed that the cadmium adsorption capacity of fly ash (4.27 mg/gr) was higher than that of zizyphus spinachristi (3.91 mg/gr).
S. Farahi, M. Hamidpour, H. Shirani, H. Dashti, M. Heshmati,
Volume 17, Issue 66 (2-2014)
Abstract
This research was conducted to study the effect of natural and polyacrylamide-modified montmorillonite on the sorption of Cd from aqueous solutions. The sorption of Cd on the sorbents was studied as a function of pH (Cd concentration: 10 mg L-1) in the range of 4-8.5, and as a function of metal concentration (Cd concentration in the range of 1-10 mgL-1) using a 24h batch equilibration. Experimental and modeling data from equilibrium investigations revealed that the Koble–Corrigan sorption model describes the interaction between Cd and the two sorbents better than the Freundlich and Langmuir models. The values of KF constant of Freundlich and KL constant of Langmuir models were higher for sorption of Cd onto the modified montmorillonite than for those of natural montmorillonite. Maximum sorption capacity calculated from the Langmuir model was 0.6 and 0.7 mg g-1 for natural and modified montmorillonite, respectively. These values are indications of high sorption affinity of Cd to montmorillonite in the presence of polyacrylamide. The amount of Cd sorbed by modified montmorillonite decreased by increasing solution pH while Cd sorption by natural montmorillonite increased by increasing the solution pH.
T. S. Taleghani , H. Khademi, M. Afyuni ,
Volume 18, Issue 67 (6-2014)
Abstract
Stabilizing heavy metals in polluted soils is a method to prevent them from entering plants. Clay minerals are considered good sorbents for heavy metals due to their low cost, high abundance, easy manipulation and harmlessness to the environment. The objective of this study was to investigate the potential of clay deposits containing smectites and palygorskite to sorb cadmium and to reduce its movement into canola. Two selected deposits are located in the Isfahan Province. Physical and chemical characteristics of clay deposits were determined. The clay fraction was then separated from each deposit sample. This study showed that palygorskite was the dominant clay mineral in deposit sample 1 and smectites in deposit sample 2. These clays were then used as an amendment to plant growth medium. Pot experiment was carried out with canola (Brassica napus) as a test plant with 3 replicates. Treatments included three growth media: smectite + quartz sand, palygorskite + quartz sand and pure quartz sand (control treatment) under 3 Cd concentrations: 0, 2.5 and 7.5 ppm. Results obtained from the pot experiment indicated that deposits containing smectite and palygorskite were very useful in stabilizing cadmium in polluted soils and could prevent Cd from entering plant. Smectite clay mineral could retain a higher quantity of cadmium as compared to palygorskite. Plants in pots amended with smectite had a higher growth rate as compared to those in control and palygorskite amended pots. Cadmium accumulation in plant roots was much higher than that in shoot. Furthermore, the higher Cd concentration in growth media resulted in the higher amount of Cd uptake by the plant.
A. Hassanpour, M. Zahedi, A. H. Khoshgoftarmanesh,
Volume 18, Issue 68 (9-2014)
Abstract
In a pot experiment, the effect of soybeans, mung beans and beans on the corn and sunflowers in a cadmium contaminated soil was studied in a completely randomized design with three replications. The treatments consisted of intercropping of corn and mung bean corn and beans, corn and soybean, sunflower and mung bean, sunflower and beans, sunflower and soybean monoculture of corn, and monoculture of sunflower. There were significant effects of cocropping of companion crops on shoot dry weigh, the concentration of cadmium and zinc and the chlorophyll content of corn and sunflower. In this study the shoot weight of corn grown with bean and soybean and that of sunflower grown with bean plants was decreased as compared to the related monocultures. The concentration of cadmium was increased in the corn grown with soybean or mungbean and in sunflower grown with soybean. Co- cropping with bean plants had no significant effects on the concentration of cadmium in corn or sunflower. Among companion crops, the concentration of cadmium was higher in bean plants compared to those of soybean and mungbean plants. The chlorophyll content in the leaves of corn plants grown with mungbean was increased with an increase in cadmium concentration. However, this trend was not observed in other treatments. The results of this study show that co- cropping with either soybean or mungbean may increase cadmium uptake by corn and sunflower which in turn may increase the risk of inflowing of toxin cadmium into the food chain. However, further study needs to re-evaluate the effect of these companion crops on the distribution of cadmium in the edible parts of corn and sunflower.
F. Alsadat Hodaee Koskkoee, H. Shariatmadari, M. Hamidrpour, M. Shirvani,
Volume 18, Issue 70 (3-2015)
Abstract
Sorption hysteresis in soil constituents has important environmental implications such as pollutant transport and bioavailability. This research was carried out to study sorption reversibility of cadmium (Cd) on natural zeolite. Sorption isotherms were derived by sorption of Cd (П) from solutions containing different concentrations of Cd in the range of 1 to 10 mg L-1 using a 24h batch equilibration experiment. Desorption of Cd(II) was studied with the clay samples initially treated with the metal loadings of 50 and 100% maximum sorption capacity (SCmax) during the sorption study. Sorption isotherms of Cd were well described by the Freundlich and Coble-Korrigan models (R2=0.96). Desorption isotherms of Cd from zeolite showed little deviation from sorption data indicating reversible sorption. On the other hand, the results revealed no hysteresis. The average amount of 71.75 % of the initially sorbed Cd was desorbed from zeolite after five successive desorption steps. Release of such a relatively high proportion of sorbed Cd indicates that zeolite is an effective sorbent for the repeated purification of polluted water and wastewater.
R. Mollaei, J. Abedi Koupai, S. S. Eslamian,
Volume 20, Issue 75 (5-2016)
Abstract
Water scarcity forced farmers to use wastewater as water source, without considering its effects on environment and resultant contamination of soils and plants especially with heavy metals. The objectives of this study are to evaluate the application effects of zeolite as soil amendments on the uptake of Cd by spinach (Spinach Oleares L.) irrigated with wastewater (containing 10 ppm Cd). Different levels amounts of zeoilte (0, 1% and 5% w/w) were added to the soil and the experiment was conducted as a completely randomized design in a green house with 3 replications. The results indicated that, the addition of zeolite 1% (w/w) in soil treated with wastewater reduced cadmium concentration in plant, and consequently the percentage of extractable Cd using DTPA was decreased. However, application of zeolite 5% (w/w) increased the soil salinity, and as a result increased Cd concentration in the plant but this increase was not statistically significant, comparing with control. Spinach biomass did not differ significantly under irrigation with wastewater, but the Cd available in wastewater caused a decrease in Spinach biomass yield.
A. Khosravi-Dehkordi, M. Afyuni, A. Soffianian,
Volume 20, Issue 77 (11-2016)
Abstract
Pollutants are considered the disturbing factors of environment, and among them the heavy metals are more important considering their non-degradability and physiological effects on organisms in low concentrations. The goal of this research was to investigate the effect of industrial landuse on Cd and Pb concentrations in surface soils of the southwest Isfahan. According to satellite images and topographic maps (1:50000) of the study area, soil samples (depth: 0–20 cm) were collected using random sampling. A total of 38 surface soil samples were obtained from industrial areas (lowest distance = 1480 m) in the area of 73481 ha. Total concentrations of Cd and Pb in the digested solution were measured by Atomic Absorption Spectrophotometry (AAS). Using Arc GIS, the spatial distribution patterns and Cd and Pb variography of samples were analysed and finally the best models of spatial distribution of heavy metals were achieved. The primary results showed that the mean concentrations of Cd, and Pb of surface soil samples in industrial areas were 1.8 to 31.5 mg Kg-1 higher than the world’s mean values, respectively. Although the mean concentrations of Cd and Pb were respectively 8 to 700 mg Kg-1 lower than the standard of Iranian Department of Environment for industrial landuse.
Msc S. Shahmoradi, Dr M. Afyuni, Dr M. Hajabbasi, Dr A. H. Khoshgoftarmanesh, Dr M. Shirvani,
Volume 21, Issue 2 (8-2017)
Abstract
During last century, waste water of gold mine has accumulated heavy metals such as lead, zinc and cadmium in Zarshuran region soil, and thus has increased epidemic disease in this region drastically. The purpose of this research was to reduce the mobility and bioavailability of zinc, lead and cadmium in rhizosphere of sunflower grown in soil around the mine by inorganic sorbents. A pot experiments was carried out with three levels of raw zeolites (1, 6, 12 wt%), three levels of raw bentonite (1, 6, 12 wt%) and control (without sorbent) in a completely randomized block design with three replications. After cultivation, soil and plant samples were taken and the concentration of lead, cadmium and zinc in their samples were measured. Different levels of bentonite reduced the absorbable concentration of lead and zinc; and also reduced their absorbable concentrations in plant tissue, but had no significant effect on reducing absorbable concentration of cadmium. Transfer factor for all three metals in the roots was more than shoot and reducing the concentration of heavy metals in the plant had no impact on plant growth. According to the study, level of 12 wt% of the raw bentonite was the most suitable sorbent for the stabilization of lead and zinc; and level of 12 wt% for raw zeolite was the best sorbent for stabilization of cadmium.
M. H. Rasouli0-Sadaghiani, H. Khodaverdiloo, M. Barin, S. Kazemalilou,
Volume 22, Issue 1 (6-2018)
Abstract
The use of plants and soil microorganisms is a promising technique for the phytoremediation of heavy metal-contaminated soils. This study was carried out in order to evaluate the soil microbial potential with four Cd concentration levels (0, 10, 30 and 100 mg kg-1); the study also addressed the inoculation of arbuscular mycorrhizal fungi (AMF) species (a mixture of Glomus species including G. intraradices, G. mosseae and G. fasciculatum) as well as plant growth promoting rhizobacteria (PGPR) (a mixture of Pseudomonas species including P. putida, P. fluorescens, and P. aeruginosa) with the Centaurea cyanus plant. The soil sample was spiked uniformly with Cd nitrate salt to create different Cd concentrations. The contaminated soils were then sterilized and subsequently inoculated with AMF and PGPR. The results indicated that with increasing the soil Cd concentration, colonization percent, abundance of rhizobateria, shoot biomass, and shoot relative biomass were significantly decreased, while the proline content and the shoot Cd concentration were significantly increased (P≤0.05). The mean of Cd extracted in AMF and PGPR treatments was 1.8 and 2.8 and the translocation factor was 1.2 and 1.5 times higher, as compared to the corresponding control treatments, respectively. It could be concluded that microbial inoculation, in addition to improving plant growth, plays an important role in the Cd phytoremediation efficiency by plant.
M. Hosseini, E. Adhami, H. R Owliaie,
Volume 22, Issue 1 (6-2018)
Abstract
Cadmium (Cd) is of special importance among heavy metals because its toxicity to the plant is 20 times higher than other heavy metals. The present study was conducted to evaluate the trend of available soil Cd changes over time and its relationship with soil properties. Treatments consisted of 13 soil samples and two Cd rates (12.5 and 25 mg kg-1) as a factorial in a complete randomized design with two replications. DTPA extractable Cd was measured upon 5, 10, 20, 30, 60 and 90 days after adding Cd rates to the soils. The results showed that DTPA extractable Cd was increased as Cd application rates was raised in all soils. DTPA extractable Cd was decreased over time; however, at the end of the experiment, much of the added cadmium to the soil remained in use. Among the soil properties, calcium carbonate showed a significant negative correlation with DTPA extractable Cd in most of the incubation times in both Cd rates. DTPA extractable Cd also showed a significant negative correlation with pH and soil sand and a significant positive correlation with OC. Also, the results of the fitting of cadmium adsorption data with the kinetic equations showed that the exponential function equation was the most suitable kinetics descriptive equation for variations in cadmium adsorption in the studied soils.
E. Mirzakhani, H. Motaghian, A. Hosseinpur,
Volume 25, Issue 4 (3-2022)
Abstract
Pollution of the environment by heavy metals, especially soil pollution with cadmium (Cd), is one of the most important environmental problems. Also, salinization of soils due to a decrease in irrigation water quality reduces plants growth. To investigate the effect of sugarcane bagasse biochars and salinity on Cd available and Cd fractions in a contaminated soil (15 mg kg-1 Cd), an experimental factorial design in a completely randomized design including (1) biochar factor with control, 1% (w/w) bagasse, 1% (w/w) biochar 400 °C and 1% (w/w) biochar 600 °C, and (2) salinity factor with control, 20, and 40 mmol kg-1 as sodium chloride were performed in 3 replications. The amount of available Cd was determined by the DTPA-TEA method and the Cd fractions were determined by Tessier et al. (1979). The results showed that biochar and salinity had no significant effect on soil pH (P > 0.05) but increased soil EC (P < 0.05). Interaction of biochar and salinity was not significant (P > 0.05) on available Cd and Cd fractions. Biochar application reduced Cd -DTPA-TEA (P < 0.05), whereas salinity increased Cd -DTPA-TEA (P < 0.05). Application of biochar prepared at 600 °C reduced (P < 0.05) exchangeable Cd (23.8%) and increased (P < 0.05) Cd associated with iron and manganese oxides (25.2%) and residual (15.6%) compared to the control. The results showed that salinity had no significant effect on the Cd fractions (P > 0.05) and soil treated with sugarcane bagasse biochar can reduce Cd available due to changing the Cd distribution from unstable forms to stable forms.
N. Azadi, F. Raiesi,
Volume 26, Issue 1 (5-2022)
Abstract
Biochar as an efficient strategy for the improvement of soil properties and organic waste management may reduce the potential effects of abiotic stresses and increase soil fertility. However, the effects of this organic amendment on soil microbial indicators under combined salinity and pollution have not been studied yet. Therefore, the objective of this study was to evaluate the influence of sugarcane bagasse biochar on some soil bioindicators in a Cd-polluted soil under saline and non-saline conditions. A factorial experiment was carried out with two factors, including NaCl salinity (control, 20 and 40 mM NaCl) and sugarcane bagasse biochar (soils unamended with biochar, amended with uncharred bagasse, 400 oC biochar, and 600 oC) at 1% (w/w) using a completely randomized design. Results showed that salinity increased the mobility of Cd (12-17%), and subsequently augmented its toxicity to soil microorganisms as indicated by significant decreases in the abundance and activities of the soil microbial community. Conversely, sugarcane bagasse biochar application reduced the concentration of soil available Cd (14-18%), increased the contents of soil organic carbon (89-127%), and dissolved organic carbon (4-70%), and consequently alleviated the effect of both abiotic stresses on soil microbial community and enzyme activity. In conclusion, this experiment demonstrated that the application of sugarcane bagasse biochar could reduce the salinity-induced increases in available Cd and mitigate the interaction between salinity and Cd pollution on the measured soil bioindicators.
E. Mirzakhani, H.r. Motaghian, A.r. Hosseinpur,
Volume 27, Issue 3 (12-2023)
Abstract
In addition to the distribution of elements in the soil solid phase, element species in the solution are also very important due to their importance of providing elements for root uptake. For a deeper study of the chemical cycle of elements in saline soils treated with biochar, the study of speciation is very useful and provides a method to reduce or transform the toxicity caused by toxic elements in saline soils. Therefore, to investigate the effect of biochar on Cd speciation in two saline calcareous soils, 15 mg kg-1 Cd as cadmium chloride was added to the soil sample (200 g), and the soils were incubated for three weeks at 25±2 °C at 80% field capacity. After the incubation period, salinity levels of 20 and 40 mmol kg-1 as sodium chloride (equal to 3.65 and 7.30 dS m-1) were added to the soils. Then, the 1% (w/w) of the sugarcane bagasse and biochars produced at 400 and 600 °C were added to the soils, and then incubated for three months at 25±2 °C at 80% field capacity. At the end of the incubation period, for the speciation of Cd in the soil solution (in a 1 to 2 ratio), the concentration of dissolved cations and anions in the soil samples was measured. The results showed that the interaction between salinity, biochar, and soil on Cd2+, CdCl+, CdCl20, and Cd(SO4)22- was significant. The application of biochar in sandy soil reduced (p <0.05) the concentration of CdCl+, CdCl20, CdSO40, and CdOH+ species compared to the control soil, while it did not affect clay soil. Also, salinity caused by sodium chloride in sandy soil increased the concentration of CdCl+ and CdCl20 species and decreased CdSO40 and CdOH+ species compared to the control soil (p <0.05). The results showed that biochar in saline sandy soil was more effective than clay soil in reducing Cd toxicity.
