Showing 53 results for Heavy Metal
Majid Afyuni, Yahya Rezainejad, Babak Khayambashi,
Volume 2, Issue 1 (4-1998)
Abstract
Land application of sewage sludge is potentially beneficial as an inexpensive nutrient source. However, problem with the use of sludge may exist from high soil concentrations and subsequent uptake of heavy metals by plant and entering of the metals into the human and animal food chains. A field study with lettuce (Lactuca sativa L.) and spinach (Spinacia oleracea L.) was conducted to examine uptake of heavy metals from a sludge amended soil as affected by sludge rate and time of sludge application. Sludge rates were 0, 22.5, and 45 ton/ha. To determine the effect of time on heavy metal uptake, a year after the first plants were harvested, one third of each plot was planted without sludge application and to the rest of each plot sludge was added in the same rates as before. Total and EDTA-extractable Cu, Zn, Pb, and Cd concentrations in soil were determined. The metal concentrations in shoots and roots of the plants were determined separately. Total metal concentrations showed an increasing trend with addition of sewage sludge. Copper, Zn, and Pb EDTA-extractable concentrations in soil and concentrations of these metals in the plants increased significantly with sludge rate. Time of sludge application did not have any significant effect on EDTA-extractable and plant uptake of metals. Sewage sludge also increased the crop yields significantly.
H.r. Rahmani, M. Kalbasi, S. Hajrasuliha,
Volume 4, Issue 4 (1-2001)
Abstract
Soil as the third major component of our environment is exposed to different kinds of pollution. Lead has been recognized as a factor in environmental pollution. Pollution of soil and plants along the highways and roads by Pb from automobile exhaust gases has extensively been reported as the most important pollutant source in the environment. This research was carried out to determine the degree of soil pollution along the following highways: Rasht-Anzaly (Anzaly area), Kelachay-Ramsar (Ramsar area), Tehran-Karaj (Karaj area) and Isfahan-Tehran (Delijan area). In each location a transect of 100 meters long, perpendicular to the highway axis, was selected for sampling. Soil samples at different depths were taken from different distances from the highway and analysed for some physical and chemical characteristics and total Ph content by 5M HNO3 extraction.
Results indicated that the total Pb content of soil decreased exponentially with distance from the roadside. Total Pb content of soil decreased sharply with depth in all highways except in one area indicating that Pb was retained in the surface soil and that its movement down to the deep soil was slow. Total Pb content of soils was highly and directly related to the traffic volume.
Y. Rezaenejad, M. Afyuni,
Volume 4, Issue 4 (1-2001)
Abstract
Due to high production of organic residues such as sewage sludge and compost, land application is probably the best way to prevent accumulated residues in the environment. However, the risk involved in the land application of organic residues should be evaluated prior to the assessment of their economic and fertilizer values. The objective of this study was to evaluate the effect of organic residues on soil chemical properties, yield and uptake of heavy metals and nutrients by corn (Zea mays L.). The study was a randomized complete block design with three replications with four treatments including cow manure, sewage sludge, municipal compost and inorganic fertilizer.
The organic amendments were applied to the plots at a rate of 50 t ha-1 and inorganic fertilizer treatment consisted of 250 kg ha-1 ammonium phosphate and 250 kg ha-1 urea.
Organic amendments significantly increased soil organic matter content, EDTA-extractable Fe, Zn, Cu and Pb and plant available P, K, and N. Uptake and concentration of nutrient in corn grain and shoots were significantly affected by treatments, whereas Cd and Pb concentrations were the same among the treatments. Cow manure and sewage sludge treatments had the highest and compost had the lowest corn silage and grain yields. Overall, the results indicated that cow manure and sewage sludge had a high fertilizer value and led to heavy metal concentrations in soil as well as corn tissues which were much lower than the reported standards.
S. Vaseghi, M. Afyuni, H. Shariatmadari, M. Mobli,
Volume 7, Issue 3 (10-2003)
Abstract
Excessive application of sewage sludge leads to the accumulation of potentially toxic elements in soils. The objective of this greenhouse study was to examine the DTPA–extractability of Fe, Zn, Cu, Mn, Pb, Cd, Ni, and Co in relation to soil pH and to investigate the concentrations of these metals in corn (Zea mayz). The study was conducted using a factorial experiment in a completely randomized design with three replications. Sewage sludge was applied at 0, 50, 100, and 200 t/ha on four soils [Langaroud (pH= 4.8), Lahijan (pH= 5.7), Rasht (pH= 6.8), and Isfahan (pH= 7.9)]. Application of sewage sludge significantly increased DTPA-extractable Fe, Zn, Cu, Pb, Cd, and Ni in all soils. The increasing effect was in accordance with sludge level. Langaroud soil had the highest and Isfahan soil the lowest levels of DTPA-extractable metals. Application of sewage sludge increased plant growth and metals in the foliage of corn plants. The metal concentration in corn tissues also increased with decreasing soil pH. Overall, the application of sewage sludge as an organic material, particularly in acid soils, may increase availability of heavy metals, which may, in turn, result in soil pollution. Therefore, addition of sewage sludge to soils should be managed on the basis of the changes in soil heavy metal concentration.
M. Hoodaji, A. Jalalian,
Volume 8, Issue 3 (10-2004)
Abstract
Soil pollution and accumulation of heavy metals in crops in industrial areas are the most important bioenvironmental problems that threaten the life of plants, animals and humans. The objective of this study was to determine Ni, Mn and Cd distribution in soil and crops shoots around the Mobarakeh Steel Plant. In this study, we separated 50 zones based on soil utility maps taking into consideration the dominant wind direction (south-western to north- eastern). In each zone, soil was sampled at 0-5, 5-10, 10-20 and 20-40 cm depths (200 samples) and DTPA-extractable concentrations of Ni, Mn and Cd were determined in soil samples. Also 36 plant samples from shoots of 18 main crops were collected in the region and the concentrations of heavy metals were determined in crop samples.
Results showed that maximum DTPA-extractable concentrations of Ni and Mn were in the northeast of the region in the 0-5 cm layer (4.2 and 312 mg/kg.soil, respectively) and decreased in 5-10,10-20 and 20-40 cm layers (2.7,2.7,2.1 and 200,212,146 mg/kg.soil, respectively). The concentrations of Ni and Cd in shoots of crops were undetectable with atomic absorption method. The concentration of Mn in rice shoots was 716.6 mg/kg.dry.m. It was higher than USEPA standards (15-100 mg/kg.dry.m).
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M. A. Nazari, H. Shariatmadari, M. Afyuni, M. Mobli, Sh. Rahili,
Volume 10, Issue 3 (10-2006)
Abstract
Sewage sludge and effluents, as cheap sources of irrigation water and fertilizer, can supply plants with water and nutrients however, contamination of these sources with heavy metals and the possibility of human food chain contamination using these sources should be considered. In this research, the effects of industrial sewage sludge and effluents on concentration of some nurtients, heavy metals and sodium and dry matter yield of wheat (Triticum aestivum), barley (Hordeum vulgare) and corn (Zea mays) were investigated. The experiment was carried out in a greenhouse using a complete randomized design with four replication. The treatments comprised well water, well water + sewage sludge(50 tons/ha), and three industrial effluents from Iran Polyacryl factory including the cooling tower, the over flow and the factory outlet effluents. Chemical analysis showed the following results: The concentration of the elements in the sludge and the effluents were below the critical contaminating levels. The application of the treatments did not supply enough nitrogen for corn the cooling tower effluent could not supply enough nitrogen for wheat and barley all the treatments supplied enough P for wheat. None of the treatments could supply enough P for corn. The cooling tower, over flow and the factory outlet effluents could not supply enough P for barley, the micronutrient and heavy metal concentrations in the plant tissues using the effluents and the sewage sludge were higher than those for well water the dry matter yield of plants’roots and shoots was highest using well water + sludge and in comparison with the well water, effluents could increase the shoot dry matter yield.
A. Ghanbari, J. Abedi Koupai, J. Taie Semiromi,
Volume 10, Issue 4 (1-2007)
Abstract
A field study was conducted at the Zabol Agricultural Research Center during the years (2003-2004) to investigate the effect of irrigation with treated municipal wastewater on the yield and quality of wheat and some soil properties. Irrigation treatments were: T1: Irrigation of wheat with well water during entire period of growing season T2: Irrigation of wheat with well water until the begging of flowering stage, and irrigation with wastewater in every other turns of irrigation T3: Irrigation of wheat with well water until the beginning of booting stage, and irrigation with wastewater in every other turns of irrigation T4: Irrigation of wheat with well water until the begging of tilling stage, and irrigation with wastewater in every other turns of irrigation and T5: Irrigation of wheat with wastewater during entire period of growing season. A complete randomized block design with four replications was adopted for this experiment. The soil was sandy loam with no limitation for internal drainage. Chemical and physical aspects of soil were measured during the experiment. Grain yield, yield components and chemical composition of wheat grain were also measured. The results showed that yield of wheat and total biomass production were statistically significant in T3, T4 and T5 compared with the control treatment. Plant height, width and length of flag leaf, numbers of fertile tillers, length of panicle, numbers of grains per panicle and weight of 1000 grains were also statistically significant with the control treatment. Percentages of protein were statistically different among various irrigation treatments. No significant changes in accumulation of heavy metals in soil and plant grains were observed. The increase of SAR, ECe, O.C% and total nitrogen in the T4 and T5 were statistical significant compared with the control treatment. In summary, for sustainable use of Zabol municipal wastewater, the growth stages of wheat should be irrigated with municipal wastewater and other growth stages should be irrigated with nonsalinty water, so that the maximum yield is obtained and soil salinitisation and sodication is prevented.
Gh. Sayyad, M. Afyuni, S. F. Mousavi,
Volume 11, Issue 1 (4-2007)
Abstract
Accumulation of heavy metals (HMs) in cultivated soils is an important environmental problem in many parts of the world. In recent years, HM leaching through preferential paths and also in the form of metal-organic acids complexes has received much attention. For this reason, the effects of plants on creating preferential flow through the soil is important. The objective of this study was to assess the mobility of Cd, Cu, Pb and Zn in a calcareous soil (Typic Haplocalcids) planted with safflower (Carthamus tinctorious). The study was conducted on 12 undisturbed soil columns (22.5 cm in diameter and 50 cm in depth) in greenhouse. The top 10 cm of soil in half of the columns were contaminated with Cd, Cu, Pb, and Zn at the rates of 19.5, 750, 150 and 1400 kg ha-1, respectively. Half of the contaminated and uncontaminated columns were planted with safflower at a rate of 20 seeds m-2. Leachate was collected continuously and analyzed for these four heavy metals. After the crop harvest, soil samples were taken at 10 cm intervals and analyzed for DTPA-extractable and water-soluble HMs concentration. Results showed that heavy metal concentrations (DTPA and soluble) of the subsoil in planted columns were more than in fallow columns. The DTPA-extractable Cd, Cu and Zn concentrations in contaminated planted columns were 3.3-, 1.5- and 1.5-times more than in contaminated fallow columns, respectively. The water-soluble Cd, Cu and Zn in planted treatments increased 2.4, 1.2- and 1.1 times more than the fallow treatment. Lead concentrations in both planted and fallow treatments were similar. Metal uptake by safflower increased such that Cd and Zn uptake was more than Cu and Pb. Cd, Cu, Pb and Zn concentrations in the leachate of planted columns increased 32.0-, 2.5-, 6.0- and 2.7- time more than the uncontaminated planted columns. In summary, although topsoil contamination increased metal uptake by safflower, however the presence of safflower increased DTPA-extractable and also soluble metal concentrations in the soil profile and therefore enhanced metal mobility. The order of metal mobility was Cd > Zn >Cu >Pb.
A Jalali, M Galavi, A Ghanbari, M Ramroudi, M Yousef Elahi,
Volume 14, Issue 52 (7-2010)
Abstract
Using treated wastewater led to increasing crop yield, but it may causes heavy metals accumulations and also their toxicity in soil and plant. In order to investigate the effects of wastewater on yield, forage yield components, and heavy metals concentrations in stem and leaf of sorghum, an experiment was conducted in the agricultural Research Institute of Zabol University in 2006-2007, using a randomized complete block design with four replication. The irrigation treatments were: 1) well water for whole growing season as control (T1), 2) well water for all growing season along with NPK application (T2), 3) wastewater during the first half of growing season (T3), 4) wastewater during the second half of growing season (T4), 5) wastewater and tapwater alternately (T5) and 6) wastewater for whole growing season (T6). The results showed that irrigations with wastewater and well water alternately and wastewater for whole growing season produced the maximum forage yield and the maximum heavy metal accumulation in plant organs observed by irrigation with wastewater for hole growing season, and wastewater and well water alternately. There was significant increase between T5 and T6 relative to control and other treatments. The elements concentration such as Cu, Pb and Fe in leaf was more than stem, but Zn and Ni concentration in stem were more than leaves. There were no significant differences for Mo and Cr concentration between stem and leaf. Forage yield in T6 and T5 relative to T2 were increased 38.96 and 51.95 percent respectively. In all irrigation treatments the amount of elements and heavy metals in sorghum were lower than standard limits. Based on the results, alternative irrigation method (T5) is recommended for forage sorghum production.
L. Khodakarami, A. Soffianian, N. Mirghafari, M. Afyuni, A. Golshahi,
Volume 15, Issue 58 (3-2012)
Abstract
Among the environmental pollutants, heavy metals according to their irresolvable and physiological effects on living organisms at low concentrations, are of special importance These elements due to low mobility are gradually accumulated in soil Being accumulated in soil, they eventually enter the food chains and threaten human health and other creatures Therefore, studying concentration distribution of heavy metals for soil pollution monitoring and maintaining environmental quality is essential In this study we investigated the effect of agricultural land use and geology on the concentration of heavy metals contamination of soil and spatial distribution map, using collected data, GIS and GeostatisticsUsing systematic stratified random sampling, 135 surface soil samples( 0-20 cm) from an area of 7262 sq km area and we measured total concentration of elements Nickel, Chromium and Cobalt and soil characteristics including pH, organic matter and texture. The mean value of elements concentrations turned out to be Cr: 88.9+22.7 Co: 17.6+3.5 Ni 63.1+17.7 mg per kg and the mean acidity is 7.8 which in the area is an indication …… property. Formetal concentrations interpolation procedures, Geostatistics was used. By the aid of spatial correlation analysis, appropriate interpolation method using functions mean absolute error and bias average error were selected. Interpolation map concentrations of heavy metals Chromium, Cobalt and Nickel with ordinary kriging method and the exponential model were developed Interpolation map analysis of heavy metals by the aid of geological and land use maps show that the distribution of the elements Chromium, Cobalt and Nickel are consistent with the geology classes However, they did not match the agriculture pattern Findings of this study in the area give us appropriate information about the concentration distribution of heavy metals Chromium, Cobalt and Nickel which can be used in monitoring and evaluation processes of heavy metals pollution in agricultural lands area. But on the other hand sampling in the areas far away from human effects, showed that the heavy metals concentration is naturally high.
N. Najafi, S. Mardomi, Sh. Oustan,
Volume 15, Issue 58 (3-2012)
Abstract
The effects of waterlogging, sewage sludge and manure on the Fe, Mn, Zn, Cu, Pb and Cd uptake and concentrations in roots and shoots of sunflower (Helianthus annuus L.) were investigated in greenhouse conditions. A factorial experiment based on a completely randomized design with three replications including duration of waterlogging at five levels (0, 2, 4, 8, 22 days) and source and amount of organic fertilizer at five levels (0, 15 and 30 grams of both manure and sewage sludge per kg of soil) was conducted. The results showed that by increasing the duration of waterlogging, the Mn uptake and concentration in shoots and Mn concentration in roots increased but Mn uptake in roots did not change significantly. The uptake and concentration of Fe in shoots and Cd concentration in shoots and roots initially increased and then decreased after soil waterlogging, while Zn and Cu concentration of roots increased after an initial decrease. The effect of soil waterlogging on the Pb, Cu and Zn concentrations in shoots was not significant. By application of sewage sludge and manure the uptake and concentration of Fe, Mn, and Zn in shoots and Cu uptake in shoots increased but the uptake and concentration of Pb in shoots increased only by application of sewage sludge. The effect of source and amount of organic fertilizer on the Cd uptake and concentration in shoots, Cd concentration in roots and Cu concentration in shoots was not significant. By application of sewage sludge the root concentration of Fe, Mn, Cu and Zn increased but root concentration of Cd and Pb did not change significantly. The maximum uptake of heavy metals in shoots was obtained by application of 30 g sewage sludge/kg of soil. The effect of soil waterlogging on the heavy metals uptake and concentrations in the roots and shoots was dependent on the source and amount of organic fertilizer. Sunflower plant accumulated Fe, Mn, Zn, Cu, and Pb in roots while the Cd concentration in roots did not differ with shoots significantly.
S. Marofi, N. Parsafar, Gh. Rahimi, F. Dashti,
Volume 16, Issue 61 (10-2012)
Abstract
In this study, a completely randomized experiment was designed with four irrigation treatments and three replicates. The irrigation programs were raw wastewater, treated wastewater, a combination of 50% raw wastewater and 50% potable water and a combination of 50% treated wastewater and 50% potable water. The experiments were run within a greenhouse. The lysimeters were built up on September 2009 and they were filled with two layers of soil. The upper (0-30 cm in depth) and lower (30-70 cm in depth) layers were sandy loam and sandy clay loam, respectively. A total of eight watering programs with an interval of elevens-day were applied. After each irrigation program, intake wastewater and drainage water of each Lysimeter was sampled in order to analyse the transport of heavy metals (Cu, Zn, Fe and Mn, Ni, Cd and Pb). Results showed that the effect of water quality was significant on percentage of transport of heavy metals. The lowest transport percentage of heavy metals belonged to raw wastewater treatment. Also, the highest percentage of transport of Cu, Zn, Fe, Ni and Pb belonged to the combination of 50% raw wastewater and 50% potable water. In most cases, we observed that the transport percentage of these elements increased by continuing the irrigation
S. Jafari, Z. Iranshahi , Gh. Fathi, S. A. Syadat,
Volume 16, Issue 61 (10-2012)
Abstract
Cadmium is a toxic element in plant nutrition and is considered as a contaminant of food and feed. A greenhouse experiment was carried out to examine the effects of combined application of cadmium and zinc on responses of wheat on a clay loam soil texture. This experiment was designed in a factorial experiment with randomized complete block design (RCBD) and four replicates per treatment. Three levels of cadmium (Cd 0, Cd 50 and Cd 100 mg kg-1) and three levels of zinc (Zn 0, Zn 50 and Zn 100 mg kg-1) were added to the pot in factorial(9 treatments), and then Chamran seed variety of wheat (triticum aestivum L.) was planted in each pot. The statistical analyses showed that Cd application significantly (P0.01) decreased grain, straw, and total yield, but Zn application increased these parameters significantly (P0.01). Application of Cd separately decreased the grain yield by 61.5 while application of Zn separately increased the grain yield by 36.9. Cd application increased the Cd concentration and uptake by grain and straw as well as total uptake but by increasing Zn application, Cd uptake was decreased by wheat. Cd concentration was higher in straw than that grain, but Zn showed a different trend. Decreasing Zn applications decreased total uptake of Cd from 42.9 in Zn0 to 7.8 mg kg-1 in Zn100 treatment. Although this soil was very calcareous, this characteristic did not control Cd absorbtion.
Sh. Mahmoudi, M. Naderi, J. Mohammadi,
Volume 17, Issue 63 (6-2013)
Abstract
This research was carried out to determine spatial distribution of heavy metals concentration in soil particle size classes using Landsat ETM+ reflectance in Southern Isfahan city in the vicinity of Bama mine. To fulfill this goal, 100 compound soil surface samples were collected randomly from the area. The samples were air dried and soil particle size classes 250-500, 125-250, 75-125, 50-75 and <50 μm were determined using appropriate sieves after dispersion of the bulk samples of soil using ultrasonic apparatus. Total Zn, Pb and Cd concentrations were measured using Atomic Absorption Spectrophotometer after wet digestion of samples in acid nitric. The results indicated significant negative correlation coefficients between heavy metals concentrations of soil particle size classes and soil spectral reflectance in the visible, near infrared and panchromatic bands of Landsat ETM+ satellite. Stepwise multiple regression models were used for estimating heavy metals concentration in soil particle classes through satellite data. Furthermore, spatial distributions of heavy metals were mapped using stepwise multiple regression equations. Results also showed heavy metals concentrations in all soil particle size classes were maximum close to the mines and decreased by increasing the distance from these sources.
Hadis Feizi, Mostafa Chorom, Arsalan Heidari,
Volume 17, Issue 64 (9-2013)
Abstract
In order to describe soils polluted with hydrocarbons, the amount and distribution pattern of soil heavy metals (Ni, Cd) in soils were studied. Soil samples were taken from one of the western oil field of Iran. The field was naturally exposed to crude oil spillage into soil and consequently was environmentally polluted during the development, production, transportation and storage of crude oil. Sampling was started near the oil wells with maximum relative contamination and continued to the remote places based on grid sampling pattern. Samples were characterized by physicochemical analysis. The results revealed different levels of total hydrocarbons (from 0.12 to 2.99 mg/kg of dry soil), Ni (from 32 to 136 mg/kg. of dry soil) and Cd (from 0 to 4mg/kg of dry soil). In addition, the role of soil agents such as pH and EC and sedimentary indexes was considerable in controlling the pollution trend in the studied area. Finally, by interpolation module and prediction of unknown values via Kriging techniques, the expansion plans were created. The extracted plans obviously illustrated the decrease in the levels of pollution indexes with the increase in distance from the given centers of pollution
K. Hashemimajd, Sh. Jamaati-E-Somarin,
Volume 17, Issue 65 (12-2013)
Abstract
Improper properties of sewage sludge include odors, trace elements concentration, and presence of pathogens limit its use in agriculture. Composting and using of earthworms in this process is one of the most suitable methods for stabilization and removal of unsuitable properties of sewage sludge. To investigate the effects of kind and mixing proportion of bulking material and sewage sludge decomposition stage on vermicompost quality, an experiment was carried out in a split plot design with three replications. In this experiment, the stage of sewage decomposition (raw sewage, digested sludge in digester, dewatered sludge in lagoons, and final dried sludge in lagoons) was main factor and kind of bulking materials (woodchips, three leaves, and wheat straw) and mixing proportion of bulking materials to swage sludge (0, 15, 30, and 45 %, V/V) were as subordinate factors. Chemical properties of sewage in different decomposition stages and bulking materials were determined. After 5 months of incubation in the controlled moisture and temperature condition, and in the presence of earthworms, the pot's contents were harvested, and nutrients and heavy metal concentration of vermicomposts were measured. Vermicomposts had relatively low pH and EC. Their nutrients content especially N, P, Fe, and Zn were high. These properties showed vermicompost suitability for use as a soil amendment and organic fertilizer. Heavy metals concentrations of vermicomposts, except for Zn, were lower than recommended values by EPA. Despite no significant difference between the kinds of bulking materials, mixing of these materials with sewage sludge decreased pH, N, and Pb content of produced vermicompost. According to the results, 30% (v/v) mixing of bulking material and sewage sludge is recommended
M. Nasrifard, G.h. Sayyad, A.z. Jafarnejadi, M. Afyuni,
Volume 17, Issue 65 (12-2013)
Abstract
Environmental pollution caused by heavy metals such as lead is a serious and growing problem. Due to the importance of wheat in the human nutrition, this research was conducted to study concentration of lead in the soil and also seeds of wheat farms in Khuzestan Province. Therefore, in the agricultural year of 2007-2008, the soil and wheat seed samples were collected from 100 farms whose locations were specified using weighing sampling method. The lead concentrations in soil (total and available), and wheat seeds samples were measured. The result revealed that lead concentrations in soil and seeds in none of the studied regions exceeded the respective critical levels (50 and 30-300 mg/kg, respectively). Ezeh with an average of 0.01 µg/kg had the lowest amount of lead in the wheat seeds, while BaghMalek with an average of 190 µg/kg had the highest amount. The mean concentration of available lead in the soils of study region was 0.6 mg/kg. The concentration of available lead had a negative and significant correlation (r=-0.2*) with the ECe. Also, lead concentration in wheat seeds had a positive and significant correlation (r=0.3**) with the amount of calcium carbonate equivalent. More lead concentration in seeds of bread wheat cultivars showed its higher potential for accumulation of lead than durum wheat.
N. Parsafar, S. Marofi ,
Volume 17, Issue 66 (2-2014)
Abstract
In this study, a completely randomized experiment was designed with five irrigation treatments and three replicates. The irrigation programs were raw wastewater (T1), treated wastewater (T2), a combination of 50% raw wastewater and 50% fresh water (T3), a combination of 50% treated wastewater and 50% fresh water (T4), and fresh water (T5). The experiments were run within a greenhouse. The lysimeters were built up in September 2009 and they were filled with a two layer soil. The upper (30 cm) and lower (40 cm) layers were sandy loam and sandy clay loam, respectively. The results showed that the effects of watering treatments on transfer coefficients of heavy metals from soil to shoots (except Cd) and tubers of potato (except Zn and Cu) were significant (p <0.01). Maximum and minimum transfer coefficients of heavy metals were observed in the (T1) and (T5) treatments, respectively. Also, the transfer coefficients of Cd from soil to shoots were lower than tubers. In the case of Zn, Cu and Pb, transfer coefficients from soil to tubers were lower than shoots. In this study, the maximum transfer coefficients to shoots were Cd (0.331-0.463), Zn (0.383-0.230), Cu (0.173-0.386) and Pb (0.003-0.057), respectively. Maximum transfer coefficients toward tubers (except T5) were Cd (0.439-0.572), Cu (0.081-0.138), Zn (0.170-0.217) and Pb (0-0.017), respectively. The combination of wastewater and fresh water use in short-term irrigation might be feasible, but a heavy metal monitoring program is necessary.
M.salehipour Baversad, H.ghorbani, M.afyuni, H.kheirabadi,
Volume 18, Issue 67 (6-2014)
Abstract
Regards to the importance of using safe vegetables, controlling the concentrations of heavy metals is necessary for
consumer's health. Therefore, this study was aimed to evaluate the potential risk of heavy metals on human health for
non-cancerous and cancerous diseases through consumption of agricultural products in Isfahan province. The samples
were included wheat, rice, carrots, onions, leafy vegetables and potatoes which were collected randomly from the
studied area. In order to assess the risk of non-cancerous diseases, Target Hazard Quotient (THQ) and Hazard Index
(HI) were calculated for a specific element as well as combinations of different elements. The results showed that the
THQ for arsenic was more than one in wheat and was less than one for other heavy metals if one product is consumed.
This indicates that the likely effects of arsenic for noncancerous diseases of wheat are not alone, rather they are for
other elements in various products. Risk indicators for men and women are 2.6 and 2.9 respectively, which indicates the
effects of noncancerous diseases resulting from consumption of products. Cancer risk due to arsenic in samples of
wheat consumption is higher than the Onion and potential cancer risk for this disease for this element is in the middle.
The parameters for the lead element in both cases is low.
A. Hasani Nekou, A. Karimi, Gh. Haghnia, M. H. Mahmoudy Gharaie ,
Volume 18, Issue 67 (6-2014)
Abstract
The aim of this study was to investigate the effect of parent materials and pedogenic processes on distribution of Pb, Zn, Cu, and Ni in the residual soils derived from different parent materials in the Binaloud zone, western Mashhad. Two soil profiles on the summit of granitic, ultrabasic and metamorphic rocks were described and sampled from their genetic horizons. Pseudototal concentrations of selected heavy metals and fractions of these metals were determined using aqua-regia and sequential extraction methods, respectively. 178.1-419.7 mg kg-1of Ni in ultrabasic soil versus 0.7-27.5 mg kg-1 in the granitic soil make the Ni a distinctive element in the studied area. Cu with the average contents of 60 and 56.3 mg kg-1 in the ultrabasic and metamorphic soils respectively showed more concentration in comparison to granitic soils with 12.1 mg kg-1. The amount of Zn was not significantly different among the soils, although the average of this element in the granitic soil (55 mg kg-1) is slightly more than the other soils. Pb was only detectable in the surface layers of all pedons reaching up to 6 mg kg-1. Residual fraction except Ni and Cu in granitic soil was the main fraction for all of the studied heavy elements that was expectable according to the low weathering intensity of the soils. The eolain addition of gypsum and carbonates have influenced heavy metals concentration, especially in surface horizons. In conclusion, the amount of heavy metals was significantly affected by parent materials and the eolian deposition must be considered as the secondary influencing factor.
