JWSS - Journal of Water and Soil Science

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As apparent Zn recovery in mineral soils (saturated and unsaturated) is nill, the precise assessment of processes responsible for Zn retention in these soils is of great importance. A laboratory study was conducted to characterize Zn adsorption in eight lowland calcareous soils. The fit of sorption data was evaluated by Freundlich and Langmuir isotherms. In this study, 2-g soil samples were equilibrated for 24 hours with 40 mL 0.0lM CaCl₂ solution containing 5 to 500 mg Zn L^-1. The amount of Zn adsorbed was calculated based on the difference between the initial and equilibrium Zn concentrations.

Zinc adsorption data were fitted to a linear form of Freundlich equation. However the Langmuir isotherm was divided into two distinct linear portions, representing two different types of adsorption sites. The Langmuir K₁ was higher and adsorption maxima (b₁) was lower in part I (corresponding to lower Zn concentration) than in part II (corresponding to higher Zn concentration). Thus, it seems that in parts I and II, sites are more important for their high adsorption energy and adsorption capacity, respectively. Langmuir adsorption maxima (b₂) was positively correlated with clay content, CCE and P concentration and negatively correlated with CEC.

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Phosphorus (P) and iron (Fe) are essential nutrients for plants. Iron availability is low in calcareous soils of Iran due to the excessive amounts of CaCO₃ and high pH. Overfertilization of P fertilizers may also decrease Fe availability. The objective of this study was to evaluate the effect of P and Fe on the growth and chemical composition of corn (Zea mays L.) under greenhouse conditions. Treatments consisted of a factorial arrangement of P rates (0, 40, 80, 120 and 160 mg kg-1 as KH₂PO₄) and Fe rates (0, 2.5, 5 and 10 mg kg^-1 as Fe EDDHA) in a completely randomized design with four replications. Plants were grown for 8 weeks in a loamy soil, calssified as Chitgar series (fine-loamy, carbonatic, thermic, Typic Calcixerepts). Results showd that P application up to 80 mg kg^-1 increased corn top dry matter. Corn P concentration and total uptake increased by P application but decreased by Fe application. Application of Fe up to 5 mg kg^-1 increased dry matter but decreased it at higher rates. Concentration and total uptake of Fe increased by Fe application but decreased by P application. Zinc and copper concentrations decresed significantly when P was added. Manganese concentration increased at 40 mg P kg^-1 but decreased at higher rates. Iron application decreased zinc and manganese concentrations but had no effect on copper.

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Iron (Fe) availability is low in calcareous soils of Iran due to high pH levels and presence of excessive amounts of CaCO₃. Overfertilization by phosphorus (P) fertilizers may also decrease Fe availability. The objective of this study was to evaluate the effects of P, Fe and their interactions on the growth and chemical composition of soybean [Glycine max (L.) Merrill] under greenhouse conditions. Treatments consisted of a factorial arrangement of P rates (0, 40, 80, 120 and 160 mg kg^-1 as KH₂PO₄) and Fe rates (0, 2.5, 5 and 10 mg kg^-1 as FeEDDHA) in a completely randomized design with four replications. Plants were grown for 8 weeks in a loamy soil, classified as Chitgar series (fine-loamy, carbonatic, thermic, Typic Calcixerepts). Results showed that P application up to 80 and Fe at 2.5 mg kg^-1 increased shoot dry matter. Phosphorus concentration, total uptake and P:Fe ratio in soybean increased by P application but decreased by Fe application. Application of Fe up to 2.5 mg kg^-1 increased dry matter but decreased it at higher rates. Concentration and total uptake of Fe increased by Fe application but decreased by P application. Interaction of P and Fe had no effect on shoot dry matter. Zinc (Zn) and copper (Cu) concentrations decreased significantly when P was added and manganese (Mn) concentration increased up to 40 mg P kg^-1 but decreased at higher rates. Iron application had no effect on soybean Zn and Cu concentrations but decreased Mn concentration at all rates. Prior to any fertilizer recommendations, it is necessary to study the effects of P, Fe and their interactions on soybean under field conditions.

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In the current experiment seven catheterized broiler breeder hens were used at 60 weeks of age. Retention of ¹⁴CO₂ in the body of the hens following continuous infusion of NaH¹⁴CO₃ during each of tow-30-hr continuous infusion studies was determined. Oxidation rate plateau was established within two hours in each experiment. Recovery of ¹⁴CO₂ at the steady state in the first and second study were 91.09 and 87.55 percent respectively and were not significantly different. Mean breath ¹⁴CO₂ recovery was 89.32 percent and hence retention was 10.68 percent. Recovery of ¹⁴CO₂ in breath was not significantly affected by laying of egg or photoperiod. Recovery of ¹⁴CO₂ during the fed state was significantly lower than the fasted state. The results of this experiment indicated that, using of uncorrected data for the retained isotope into body, lead to 10.68 percent AA requirements underestimation in broiler breeder hens by indicator amino acid oxidation technique.

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  Soil properties play a significant role in phosphorus (P) sorption. Information about P sorption is limited in Hamadan soils. The objectives of this research were to study the P sorption in twelve soils of Hamadan, assess the capability of different kinetics equations describing P sorption and correlate the P sorption characteristics with the soil properties. The soils were fertilized with 200 mg P kg^-1 as KH₂PO₄. Fertilized soil was incubated at 25±1 ˚C for 2520 h. The incubated samples at 1, 2, 4, 8, 24, 48, 72, 96, 120, 144, 168, 240, 336, 504, 672, 840, 1008, 1176, 1344, 1512, 1680, 1848, 2016, 2186, 2352, 2520 hours after P addition were extracted by two extractants. The soil phosphorous was extracted by 0.5 M sodium bicarbonate (Olsen solution) or by AB-DTPA. Zero order, first order, simplified Elovich equation, parabolic diffusion law and power function equations were fitted on the experimental data. The results showed that P sorption was initially rapid followed by a slow phase. The amounts of P sorption after 2520 h, ranged from 162.7 to 253.84 and 193.37 to 235.11 mg kg^-1 for the Olsen and AB-DTPA methods, respectively. Regarding to higher determination coefficient and lower standard error, Elovich and power function equations were suitable to describe P sorption kinetics. Rate constants of the Elovich and power function equations ranged from 0.036 to 0.49 and 0.157 to 0.304 mg kg^-1h^-1 for Olsen and from 0.074 to 0.76 and 0.184 to 0.382 mg kg^-1h^-1 for AB-DTPA. The trend of the data implied a discontinuity in slope at 336 h, as two region models might better satisfy the trend of the data in to two range ( 0 to 336 and 336 to 2500 hr). At the first section, the P sorption could be describe by simplified Elovich, power function and parabolic diffusion law kinetics equations. Rate constants in these equations varied among the soils. At the second section, kinetics equations could not describe the P sorption. The results of this study indicated that P sorption rates varied among the soils and Fe , Al and CaCo₃ affected on P sorption kinetics.

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  Gypsum affects many physical, chemical and mineralogical properties which in turn influences management, classification and sutability of the soils. This is the reason why accurate measurement of gypsum in soil is very important. In most of the soil science laboratories, the method of acetone ,in spite of its too much limitation, is being used as a standard method. The purpose of this research was to compare different gypsum determination methods and to find the most suitable one. The study areas include Jafarabad of Borkhar and Sepahanshahr.Soil samples were collected from different horizons of the studied profiles and seven samples with a wide range of gypsum content were selected. Gypsum content of the soil samples were determined by methods of acetone, sodium carbonate, resin, calcium and magnesium difference, diluted extracted sulfate, ammonium carbonate, sodium citrate and hydrochloric acid. To calculate the recovery percentage of the methods, after adding a certain amount of gypsum with known purity percentage to the soil samples, gypsum content was determined again by above mentioned eight methods. To evaluate the suitability of the methods, in addition to the recovery percentage of the methods, coefficient of variability and extent of proximity of the regression line to the 1:1 line were used. The results revealed that among the used methods, the method of sodium carbonate is the most accurate one. Resin method is ranked as the second best method and can be used in non-saline soils as another accurate method for determination of gypsum content. Sodium citrate and hydrochloric acid methods for different amounts of gypsum and ammonium carbonate method for gypsum content up to 30% are third in rank as far as their accuracy is concerned. Acetone, calcium magnesium difference and diluted extracted sulfate methods are not sufficiently accurate, because of low solubility of gypsum in water which is used as an extractant. In general, the most important determinant of accuracy of the methods is extractants of the gypsum among which the sodium carbonate has the highest efficiency.

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Transport and filtering of pathogenic bacteria through porous media and groundwater resources are important and، therefore the effect of various factors on bacteria transport and filtering has been given a great attention nowadays. In this study، effects of calcium sulfate and carbonate on Psedomonas fluorescens filtration and filtering parameters were investigated in saturated sand columns under steady-state flow. The calcium carbonate levels included 0، 5، 10 and 20 %w/w and calcium sulfate levels consisted of 0، 5 and 10 % w/w which were thoroughly mixed with sand (0.15-0.25 mm). The experiment was considered factorial in completely randomized design with three replicates. The treated sands were poured into pyrex cylinders with length of 20 cm and diameter of 7 cm. Then، steady-state saturated flow with constant flux was applied to the columns. When the steady-state flow was established، the bacteria suspension with concentration of 10⁶ CFU cm^-3 (C0) was injected as step input into the columns. The leaching then was continued up to 5 times of pore volume (PV). The effluent concentration of the bacteria (C) was measured at 0.25 PV intervals. Then، the sand columns were divided into 0-5، 5-10، 10-15 and 15-20 cm layers in order to measure the filtered bacteria in each layer. The results showed that the effects of calcium carbonate on retaining of the bacteria in the 5-10 and 10-15 cm layers were significant at 1% level. It was significant at 5% for the 15-20 cm layer. The effect of calcium sulfate was also significant at 5% for the 10-15 cm and 15-20 cm layers. The interactive effects of treatments on bacteria adsorption was significant for the 5-10، 10-15 and 15-20 cm layers. The retained concentration profile and the filtration coefficient were significantly affected by the treatments، showing higher bacteria adsorption at lower depths and predominance of physical filtering. The results showed the high filtering capacity of carbonate and sulfate minerals which could ultimately reduce bacteria transport in saturated porous media towards groundwater resources.

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Soil physical and chemical properties, and test conditions might affect soil structural stability. In this study, the effects of test conditions as well as intrinsic soil properties on structural stability were investigated for selected soils from Hamedan Province. Mean weight diameter (MWD) and tensile strength (Y) of aggregates were determined by wet sieving method and indirect Brazilian test, respectively. The soil samples were pre-wetted slowly to matric suction of 200 kPa before the wet sieving. The pre-wetted samples were wet-sieved for 5, 10 and 15 min in order to simulate different hydro-mechanical stresses imposed on soil structure. Tensile strength of soil aggregates were also measured at air-dry and 500 kPa matric suction conditions. Short duration shaking (i.e. 5 min) could effectively discriminate the Hamedan soils in terms of structural stability due to their fairly low aggregate stabilities. The soil organic matter content had the highest impact on MWD followed by both clay and CaCO₃ content. The same was true for the Y values i.e. OM played the highest role in mechanical strength of soil aggregates. The highest coefficient of determination (R²) was obtained between Y and the intrinsic soil properties for matric suction of 500 kPa. The organic matter content had an important role in water and mechanically stable soil aggregates. The results indicated that short-duration wet sieving (i.e. 5 min) and measurements of tensile strength at matric suction of 500 kPa could be recommended for aggregate stability assessment in Hamedan soils

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Calcareous and gypsiferous soils are restricting factors for uptake of some plant nutrient elements and plant production. Most soils in Iran are calcareous and gypsiferous. Therefore, the aim of this study was the evaluation of calcium carbonate (Caco3) and gypsum effect on availability of some nutrients and corn growth. This study was conducted in a greenhouse at Vli-e-Asr University of Rafsanjan. Treatments were arranged in a factorial manner as a completely randomized design with three replications. Treatments were three levels of Caco3 (0, 20 and 40 g/100g soil), gypsum at three levels (0, 15 and 30 g/100g soil) and two soil textures (Sand and Silt clay loam). Results indicate that irrespective of soil texture, Caco3 application significantly decreased leaf area (by 80% and 15% for sand and silty clay loam texture, respectively), dry weight (by 80% and 15% respectively), plant height (regressed on Caco3 percentage by slopes -0.7 and -0.15 for sand and silty clay loam respectively), and shoot Fe (-9.67 and -11.3) and Zn (-0.24 and -1) uptake, but had no significant effect on shoot Cu uptake. In sandy soil, application of gypsum, significantly decreased leaf area (80%), dry weight (62%), and shoot Cu uptake (slope= -1.93), but had no significant effect on plant height and shoot Zn uptake. Gypsum application significantly reduced shoot Fe uptake (slope= -24.86) in fine textured soil, but it had no significant effect in coarse textured soil.

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Magnetic susceptibility measurement is a simple and quick technique for characterizing soils and sediments and describing soil-forming processes. The interpretation of soil magnetic susceptibility data needs sufficient knowledge about the factors affecting this parameter. To identify the effects of parent material, gypsum and calcium carbonate equivalent, 42 samples were taken from horizons of soils developed on loessial, alluvial, granitic and marly materials in southern Mashhad. Gypsum and carbonates of soil samples were removed by successive washing with distilled water and diluted HCl, respectively. Magnetic susceptibility of bulk samples (lfbulk), gypsum free samples (lfGf), gypsum and carbonates free samples (lfGCf) and gypsum, carbonates and sand free samples (lfGCSf) was measured. The results revealed a strong 1:1 correlation between the measured and calculated lfGf and lfGCf. Despite the high amounts of gypsum and carbonates in soils developed on marls, their lfbulk was much more than that of the other soils and reached up to 121.8×10-8m3 kg-1. In contrast, the lfbulk values of saprolitic granite were less than 10.4×10-8m3 kg-1. The lfbulk values of loessial and alluvial soils were less than those of marly soils but higher than those of soils developed on saprolitic granite. lfbulk values were negatively correlated with the amount of sand. However, reduction in magnetic susceptibility values of marly soils after removing sand reflects the different nature of this soil. The correlation between lfbulk and amount of silt and clay is positive, but the magnetic susceptibility values are more sensitive to clay percentage, indicating the more important contribution of clay to magnetic susceptibility values. The results of this study highlight the role of parent materials, gypsum and carbonates in the soil magnetic susceptibility values that should be considered.

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Due to soil and plant zinc (Zn) deficiency and its effect on reducing yield and quality of agricultural products, application of Zn fertilizers has been intensified in recent years. To achieve optimum fertilizer management, knowledge of factors affecting Zn availability in soil and its uptake by plant is required. Therefore, this study was carried out to investigate the effect of certain soil physiochemical properties on Zn availability in soil and its uptake by corn. The experiment was laid out in a completely randomized design with factorial combination and three replicates in the research greenhouse of Isfahan University of Technology, in winter 2009. In this greenhouse experiment, 11 soil series were exposed to two Zn levels (0 and 15 mg Zn kg−1 in the form of zinc sulfate). The results indicated that Zn application significantly increased the dry matter weight and shoot and root Zn concentration of corn, although the magnitude of this increase varied depending on the soil type. There was no significant correlation between the DTPA-extractable Zn and the uptake of this nutrient element by corn. There was a negative significant correlation (P < 0.05) between the equivalent calcium carbonate content and available P with the DTPA-extractable Zn. A significant linear relationship (R2 = 0.31) was found between the buffer capacity of soil for Zn and clay content. According to the results obtained from the stepwise regression analysis, the DTPA-extractable Zn and buffer capacity of soil for Zn were not correlated with other measured soil properties.

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Vis-NIR spectroscopy has been introduced as a non-destructive, fast, and cheap technique, with minimal sample preparation and no loss or damage to the environment. No investigation has yet been carried out to examine the ability of this method to estimate soil properties in Iran. The objective of this research was to investigate the capability of Vis-NIR spectroscopy to predict the amount of organic matter, carbonate and gypsum in surface soils of Isfahan province. A total of 248 surface soil samples were collected from the study area. Soil organic matter content, gypsum and carbonates percentages were measured by standard laboratory methods. Soil spectral analyses were performed by a field spectrometer using 350-2500 nm wavelength range. Different pre-processing methods were evaluated after recording the spectra. Partial least squares regression was used to predict soil parameters. R2 values for organic matter, carbonates and gypsum were 0.61, 0.45 and 0.8, respectively. Based on RPD (Ratio of Prediction to Deviation) values, the precision of prediction model for gypsum was quite good, and acceptable for organic matter, whereas the prediction of the model for soil carbonates was poor. Consequently, vis-NIR spectroscopy is capable of predicting some soil properties simultaneously and the model accuracy is acceptable.

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Improvement of soils is among the major concerns in civil engineering, therefore a variety of approaches have been employed for different soil types. The annual budget of implementing the projects of this kind in countries clearly implies the importance of the subject. The loose granular soils and sediments have always imposed challenges due to their low strength and bearing capacity. Bio-mediated soil improvement has recently been introduced as a novel link of biotechnology (biotech) and civil engineering for improving the problematic soils, i.e. utilizing some bacteria to precipitate calcite on the soil particles. Bio-grouting is a branch of Bio-mediated soil improvement which is a method based on microbial calcium carbonate precipitation. In this regard, the soil samples were stabilized by injecting the bacterium Sporosarcina pasteurii in the first phase of the process and Urea and Calcium Chloride in the second phase of the process (two-phase injection) as the nutrients into the sandy soil columns and subjected to unconfined compressive strength test. In this research, Taguchi method was utilized for design of experience (DOE). Based on results obtained, the activity of the bacteria caused the precipitation of calcium carbonate in soil samples so that after 21 days, the unconfined compressive strength of the soil increased from 85 kPa in the control sample to 930 kPa at optimum condition.

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