Showing 9 results for Cd
E. Khadivi Borujeni, F. Nourbakhsh, M. Afyuni, H. Shariatmadari,
Volume 11, Issue 1 (4-2007)
Abstract
Application of sewage sludge on the farmland as a source of crop nutrient had recently received considerable attention. Some management practices may be required to control the accumulation of toxic elements including Pb, Ni and Cd. Sequential extraction gives useful information on plant bioavailability of the elements. The objective of this study was to investigate the cumulative and residual effects of sewage sludge application on the chemical forms and mobility factor of Pb, Ni and Cd. Zero, 25, 50 and 100 Mg ha-1 of sewage sludge were applied for 1, 2 and 3 consecutive years in a split plot design, with three replications. Soil samples were taken from 0-20 cm at the end of the third year of application. Different chemical forms of Pb, Ni and Cd were measured. Results revealed that the soluble form (SOL) of Ni and Cd increased whereas Pb soluble form decreased with increasing levels and years of application. Exchangeable (EXC), carbonate (CAR) and organic (ORG) forms of the three elements increased as levels and years of application increased. Occluded (OCC) form decreased for Pb, Ni and increased for Cd. Residual form (RES) of Pb increased while that of Ni and Cd decreased. A gereral increase was observed for available (DTPA-extractable) concentration of Pb, Ni and Cd. Relative distributions of different chemical forms were in the following order: Pb: OCC > RES> ORG> CAR> EXC> SOL, Ni: RES> ORG> OCC> CAR>EXC> SOL and Cd: OCC> CAR> RES> ORG> EXC> SOL. The comparison of different forms of the metals showed the following orders: soluble Ni>Pb>Cd, exchangeable, carbonate and occluded Pb>Ni> Cd, organic and residual Ni> Pb>cd. Increasing the available (DTPA-extractable) concentration of the elements in such a calcareous soil showed that consecutive application of sewage sludge may increase the available (DTPA-extractable) concentration beyond critical levels. A significant corretation was observed between organic form and available (DTPA-extractable) concentration of the elements.
H. Khodaverdiloo, M. Homaee,
Volume 11, Issue 42 (1-2008)
Abstract
Phytoremediation is a new technology that employs plants to remediate contaminated soils. This method compared to those that involve the use of large scale energy consuming equipments is an inexpensive method. Phytoremediation models are useful tools to further understanding the governing processes and also to manage the contaminated soils. A thorough literature review indicates that very few models have been developed for phytoremediation due to the complexity of the phenomena. The objective of this study was to develop a simple model for phytoremediation of lead and cadmium. A new formulation of phytoremediation was established based on soil and plant responses to heavy metal pollution. A large quantity of a sandy loam soil was thoroughly mixed to ensure homogeneous different concentration levels by lead and cadmium. These contaminated soils were transferred to some plastic pots. Land Cress (Barbarea verna) and Spinach (Spinacia oleracea L.) seeds were germinated in pots containing 8 kg of contaminated soil. Plants were harvested at five time intervals. The concentrations of Pb and Cd in the plant and soil samples were digested by wet oxidation and 4 M Nitric acid digestion methods, respectively, and were determined by flame and graphite furnace atomic absorption spectrometry methods. Proposed models then were calibrated using the collected data and validated quantitatively. The results indicated that the soil adsorption isotherms followed a linear form for both Pb and Cd concentrations. The results also indicated that the phytoremediation rate of Pb by Land Cress and Spinach are first-order function of Pb concentration in soil. In contrast, a zero-order function of soil Cd contaminations was obtained. Combining these two results of soil and plant responses to Pb and Cd pollution, a simple model with reasonable performance was derived to predict the time needed for remediation of soil Pb (R2 > 0.98). However, in the case of Cd, the derived models appeared to be useful to make only some overall estimations of the remediation (R2≈0.70).
M Davari, M Homaee, H Khodaverdiloo ,
Volume 14, Issue 52 (7-2010)
Abstract
Phytoremediation is a new, in-situ and emerging remediation technology for contaminated soils. This technology, compared to other methods, is a sustainable, natural, relatively cheap and applicable to large scale area. Modeling phytoremediation provides quantitative insight for the governing process as well as for managers to assess the remediated sites. The objective of this study was to introduce a macroscopic phytoremediation model for Ni and Cd- polluted soils. The proposed model assumes that relative transpiration reduction function can resemble total soilNi and Cd concentrations. Combining the related functions of soil and plant responses to soil Ni and Cd concentrations, the phytoremediation rate of Ni and Cd was predicted. In order to test the proposed model, large quantities of soil were thoroughly polluted with Ni and Cd. Upland Cress (Lepidum sativum) and Ornamental Kale (Brassica olerace var. Viridis) seeds were then germinated in the contaminated soils. The experimental pots were irrigated with fresh water to reach field capacity. Upland Cress and Ornamental Kale were harvested three and four times, respectively. At each harvest, relative transpiration, Ni and Cd contents of soil samples and plants were measured. Comparison of the maximum error, root mean square error, coefficient of determination, modeling efficiency and coefficient of residual mass indicated that the non-threshold non-linear model provide high efficiency to predict relative transpiration for Upland Cress and Ornamental Kale, respectively. The results also indicated that the proposed macroscopic model can well predict the phytoemediation rate of the Ni and Cd by Upland Cress (R2>0.83) and Ni by Ornamental Kale (R2=0.78).
R. Hamzenejad Taghlidabad, H. Khodaverdiloo, S. Rezapour, Sh. Manafi,
Volume 16, Issue 60 (7-2012)
Abstract
Soil contamination with heavy metals, including Cd and Pb, is of serious concern. The aim of this study was to investigate the efficiency of Atriplex verucifera, Salicornia europaea and Chenopodium album for simultaneous remediation of soil exchangeable sodium percentage and Cd and Pb contamination in two soils with different properties. Two soils, including a saline-sodic-calcareous (S1) and calcareous (S2) soil, were selected. Different concentrations of Pb and Cd were then added to the soils. The contaminated soils were incubated under a wetting-drying cycle for nearly seven months. The plants, seeds were grown in pots containing different treatments of polluted soils and in control treatment (no Cd and Pb contaminations). The plant yields and concentrations of Pb, Cd and Na in the soil and plant samples were measured. A considerable accumulation of soil Cd by Salicornia and Pb accumulation by Atriplex and Salicornia was observed under unsuitable conditions of the saline-sodic soil, whereas Atriplex and Chenopodium had high capability for Cd in the soil S2. Also these plants caused the reduction of ESP in soil S1. The results revealed that these plants could be used for remediation of Pb and Cd contaminated soils. In this study, Salicornia with lower rate of yield reduction had the highest tolerance to Cd-stress. Understanding the complex plant and soil (salinity-sodicity and soil metal concentration) factors controlling the metals concentrations in the plants will help to design phytoextraction technology for arid, salt-affected regions.
S. Farahi, M. Hamidpour, H. Shirani, H. Dashti, M. Heshmati,
Volume 17, Issue 66 (2-2014)
Abstract
This research was conducted to study the effect of natural and polyacrylamide-modified montmorillonite on the sorption of Cd from aqueous solutions. The sorption of Cd on the sorbents was studied as a function of pH (Cd concentration: 10 mg L-1) in the range of 4-8.5, and as a function of metal concentration (Cd concentration in the range of 1-10 mgL-1) using a 24h batch equilibration. Experimental and modeling data from equilibrium investigations revealed that the Koble–Corrigan sorption model describes the interaction between Cd and the two sorbents better than the Freundlich and Langmuir models. The values of KF constant of Freundlich and KL constant of Langmuir models were higher for sorption of Cd onto the modified montmorillonite than for those of natural montmorillonite. Maximum sorption capacity calculated from the Langmuir model was 0.6 and 0.7 mg g-1 for natural and modified montmorillonite, respectively. These values are indications of high sorption affinity of Cd to montmorillonite in the presence of polyacrylamide. The amount of Cd sorbed by modified montmorillonite decreased by increasing solution pH while Cd sorption by natural montmorillonite increased by increasing the solution pH.
M. Fathi, R. Jafari, S. Soltani,
Volume 19, Issue 71 (6-2015)
Abstract
Desertification is known as a major crisis in arid regions of Isfahan province. This study aimed to assess the performance of three main desertification models including MEDALUS, MICD and FAO-UNEP for mapping desertification severity in the hotspot of Jarghuyeh region, eastern Isfahan. Different desertification indicators and their related indices were chosen based on the characteristics of the region and fieldwork, and spatially mapped in 27 geomorphologic facies. The desertification severity maps were classified based on the classification scheme for each model in ArcGIS 10 environment, and then comparison of the models and selection of the best one were achieved using IDRISI Tiga 16.03 software. The results of all three models showed that more than 95% of the region can be classified as severe desertification but due to the differences in the number of desertification classes and also indicators and indices only 45% of desertification severity was observed to be similar across the models. Results indicated that the MEDALUS model due to its flexibility to accept new indicators and indices, GIS-based characteristics, and use of geometric mean of indicators in desertification mapping seems to be a suitable model for studying desertification severity in the region. According to this model, 85% and 15% of the area are classified as very severe and severe class of desertification, respectively, which indicates that the rate of desertification is very high and immediate management programs are needed to slow down the desertification process in the region.
A. Khosravi-Dehkordi, M. Afyuni, A. Soffianian,
Volume 20, Issue 77 (11-2016)
Abstract
Pollutants are considered the disturbing factors of environment, and among them the heavy metals are more important considering their non-degradability and physiological effects on organisms in low concentrations. The goal of this research was to investigate the effect of industrial landuse on Cd and Pb concentrations in surface soils of the southwest Isfahan. According to satellite images and topographic maps (1:50000) of the study area, soil samples (depth: 0–20 cm) were collected using random sampling. A total of 38 surface soil samples were obtained from industrial areas (lowest distance = 1480 m) in the area of 73481 ha. Total concentrations of Cd and Pb in the digested solution were measured by Atomic Absorption Spectrophotometry (AAS). Using Arc GIS, the spatial distribution patterns and Cd and Pb variography of samples were analysed and finally the best models of spatial distribution of heavy metals were achieved. The primary results showed that the mean concentrations of Cd, and Pb of surface soil samples in industrial areas were 1.8 to 31.5 mg Kg-1 higher than the world’s mean values, respectively. Although the mean concentrations of Cd and Pb were respectively 8 to 700 mg Kg-1 lower than the standard of Iranian Department of Environment for industrial landuse.
M. H. Rasouli0-Sadaghiani, H. Khodaverdiloo, M. Barin, S. Kazemalilou,
Volume 22, Issue 1 (6-2018)
Abstract
The use of plants and soil microorganisms is a promising technique for the phytoremediation of heavy metal-contaminated soils. This study was carried out in order to evaluate the soil microbial potential with four Cd concentration levels (0, 10, 30 and 100 mg kg-1); the study also addressed the inoculation of arbuscular mycorrhizal fungi (AMF) species (a mixture of Glomus species including G. intraradices, G. mosseae and G. fasciculatum) as well as plant growth promoting rhizobacteria (PGPR) (a mixture of Pseudomonas species including P. putida, P. fluorescens, and P. aeruginosa) with the Centaurea cyanus plant. The soil sample was spiked uniformly with Cd nitrate salt to create different Cd concentrations. The contaminated soils were then sterilized and subsequently inoculated with AMF and PGPR. The results indicated that with increasing the soil Cd concentration, colonization percent, abundance of rhizobateria, shoot biomass, and shoot relative biomass were significantly decreased, while the proline content and the shoot Cd concentration were significantly increased (P≤0.05). The mean of Cd extracted in AMF and PGPR treatments was 1.8 and 2.8 and the translocation factor was 1.2 and 1.5 times higher, as compared to the corresponding control treatments, respectively. It could be concluded that microbial inoculation, in addition to improving plant growth, plays an important role in the Cd phytoremediation efficiency by plant.
R. Dabiri, H. Abghari, A. Ghorbani,
Volume 27, Issue 4 (12-2023)
Abstract
Management of watersheds and sustainable development today requires the most suitable and fastest method of obtaining and integrating information for optimal management and planning. One of the challenges of watershed management in the stage of planning and implementation of remedial and rehabilitation operations is choosing the appropriate and correct location; to have the necessary maximum efficiency and effectiveness, due to the high cost of mechanical operations and the lack of financial resources, select the right place to construct mechanical corrective dams has particular importance. Therefore, the objective of this research was to locate mechanical watershed management operations with a multi-criteria approach using AHP and ANP decision methods and compare the two methods in the geographic information system environment at the Saqezchi-Chay watershed. The research criteria and sub-criteria of 14 variables included soil (depth and texture), climate (type and precipitation amount), land use and Normalized Difference Vegetation Index (NDVI), hydrological factors and soil protection (flow accumulation, sedimentation rate, and curve number), topography (elevation and slope) and economic and social (distance from the village, from loan sources and the road). Expert judgments for weighting were collected through a questionnaire and in a field method with a statistical population of 29 experts and university professors. The results of this research showed that the ANP method had a significant correlation with the AHP method at the level of 95% and with an intensity of 0.839 and by comparing the prioritization of the two methods with Masonry Check Dams structures implemented in the Saqezchi-Chay watershed, it was determined that the ANP method prioritizes with more accuracy and resolution due to its network nature and increasing the range of changes.
