Showing 6 results for Clay Mineralogy
M. Chorom, C. Jafari,
Volume 7, Issue 2 (7-2003)
Abstract
Environmental pollution is one of the major problems for humans and animals. Radioactive wastes and heavy metals are important sources of pollution. Recent studies suggest that soil and geomedia have a high potential for the disposal of radioactive wastes and heavy metals. The clay minerals in geomedia can act as a barrier against radioactive wastes and heavy metals. However, enough information and experimental evidence about the mechanisms involved in the fixation of metals by clays are not available. This study aimed to show the effect of clay type on the fixation of cobalt and cadmium as affected by thermal energy. Increasing the temperature from 25 to 400°C decreased the CEC of clays in Ahwaz and Darab soils saturated with cobalt from 35.6 and 50.1 cmolc+/kg to 28.8 and 4.5, respectively. In cadmium clays, however, reductions in CEC were minimal (from 34.3 and 51.2 at 25°C to 32.5 and 47.7 cmolc+/kg at 400°C, respectively) compared to cobalt saturated clays. Consequently, the bonding characteristics change according to the size of the cations upon thermal treatment. The small cation, cobalt with an ionic radius of 0.68 Å, apparently migrates to the octahedral vacant sites and forms covalent bonds after heating at 400°C to become non-exchangable (fixed). The larger cation, Cd with an ionic radius of 0.97Å, apparently does not migrate into lattice sites on thermal treatment and remains exchangeable.
A. Jafari, H. Shariatmadari, H. Khademi, Y. Rezainejad,
Volume 12, Issue 44 (7-2008)
Abstract
Mineralogy is one of the most influential soil properties that change from upper- to lower slope positions, depending on the climate differences. Such changes affect soil properties such as phosphorus sorption and desorption processes differently. Therefore, this study was carried out to investigate the clay mineralogy of soils in four toposequences from arid (Isfahan) and semiarid (Chaharmahal Bakhtiari) regions and its effect on soil P release. The soils of three points on each toposequence were sampled as the upper-slope mainly containing parent materials the mid-slope, non-arable lands and the lower-slope, arable lands. Some of soil properties such as clay minerals were determined. Also, trend of P release parameters was studied in four toposequences. Results showed that the amount of clay, cation exchange capacity (CEC), electrical conductivity (EC), and pH of the soils increase down the slope in all toposequences. X-ray diffractograms showed that kaolinite and illite in upper slope and smectite and chlorite in lower slope were the predominant clays. Among the kinetic models examined based on their determination coefficient and standard error, the Elovich equation was chosen to describe the P release kinetics in studied soils. The trend of P desorption rate along the arid toposequences was in the following order: upper-slope < mid-slope < lower-slope. Furthermore, the rate of P desorption in soils of the semiarid toposequences was higher than arid toposequences. Regarding the trend of P rate parameters along the toposequences, it could be concluded that P release rate and the soil capacity to supply P for plants increase toward lower slope.
S. Sanjari, M. H. Farpoor, I. Esfandiarpour Borujeni, M. K. Eghbal,
Volume 15, Issue 58 (3-2012)
Abstract
Paleosols provide invaluable data on paleoclimatic conditions of the area. These soils widely exist in central Iran. Micromorphology and clay mineralogy are among valuable techniques which are useful for interpretation and identification of these soils. The present research was performed to compare the micromorphology and clay mineralogy of paleosols and modern soils of Jiroft area. After field studies, 4 pedons (located on different geomorphic surfaces including stable mantled pediment, stable and unstable transitional surfaces of pediment and alluvial plain, and stable surface of alluvial plain) were sampled for physicochemical, micromorphological, and clay mineralogical analyses. Clay coatings in argillic horizons of paleosols were found during micromorphology observations. On the other hand, clay coatings in present soils were only found in natric horizons, which were attributed to high amounts of Na in these soils. Moreover, smectite, palygorskite, illite, chlorite, and kaolinite clay minerals were recognized in paleosols, but chlorite was not detected in modern soils. The presence of palygorskite in the soils under study was related to the stability of geomorphic surface. Results of the present research showed that a more humid climate was present at the time of paleosols formation.
S. M. A. Zomorodian, M. Khoshkoo,
Volume 16, Issue 61 (10-2012)
Abstract
Internal erosion is the second major reason for earth dam's failure after overtopping. One of the effective factors in internal erosion in earth dams is the clay minerals used in dams as well as the effects of compaction efforts on soil in sample preparation. In this research, internal erosion and the effect of clay minerals and compaction effort on internal erosion were investigated. For this purpose, Kaolin clay and Na Montmorillonite (Bentonite) separately and with different percentages of mixture were used to investigate the effect of different percentages of Bentonite on internal erosion. Two hammers of standard compaction and modified compaction test were also used to investigate different compaction efforts in internal erosion. The results showed that as compaction effort increased in constant water content, erodibility also increased to about 3%. In addition, it is found that erodibility of kaolin clay is more than bentonite, which reaches 65%. Finally, by adding 12% bentonite to kaolinite, erodibility decreased to a great extent.
M. Bahmani, M.h Salehi, I. Esfadiarpoor,
Volume 18, Issue 67 (6-2014)
Abstract
One of the main objectives of soil classification systems is to identify the differences of soil properties for management purposes. In this study, the efficiency of American and WRB soil classification systems were compared in order to describe some of soil physical, chemical and mineralogical properties in arid and semiarid regions of central Iran. Khatoon-Abad and Mobarekeh plains as arid regions and Koohrang and Shahrekord plains as semiarid regions were selected. Then, representative pedons of each plain were chosen from 16 excavated pedons and soil samples were taken from the genetic horizons to determine soil classification. Results showed that soil orders of both Koohrang and Khatoon-Abad plains are vertisols according to American soil classification system whereas based on WRB system, these soils are classified as cambisols and calcisols, respectively. On the other hand, both Mobarekeh and Shahrekord soils are classified as calcisols in WRB system whereas these soils are classified as aridisols and inceptisols, respectively, according to American soil taxonomy. None of soil classification systems could show the existence of gypsum in horizons lower than 100 cm of the soil surface for Mobarekeh soil. Clay mineralogy indicates that smectite is the dominant clay mineral in Koohrang soil as explains well at the family level of American soil classification system. Results suggest that WRB has somewhat higher efficiency rather than American soil classification system for the studied soils.
P. Khosravani, M. Baghernejad, A. Abtahi, R. Ghasemi,
Volume 25, Issue 3 (12-2021)
Abstract
Soil classification in a standard system is usually defined based on information obtained from properties and their variations in different map units. The aim of this study was to compare soil genesis and morphological characteristics in different landforms with WRB and Soil Taxonomy (ST) Systems. From nine studied profiles, six profiles were selected as representative profiles and dug in Colluvial fans, Piedmont plain, and Alluvial plain physiographic units, respectively. Then, the soils were classified according to the pattern of the two systems. Also, variation analysis of variance (ANOVA) and comparing means were used to quantify interested soil properties. The results of soil physio-chemical properties at different landform positions were significant based on analysis of variance of the effect of physiographic units and soil depth at the level of 1 %. Soil classification results based on WRB indicated that WRB were recognized four reference soil groups (RSG) included Regosols, Cambisols, Calcisols, and Gleysols at the first level of WRB classification in comparison of ST with recognizing two order Entisols and Inceptisols could separate more soils. The soils were located on the alluvial plain with a high groundwater level in the WRB due to the creation of restrictive conditions for root development in contrast to the ST called “Aquepts” in the suborder level but in a WRB is classified as the “Gleysols” RSG. On the other hand, ST, unlike WRB, used the Shallow criteria at the family level to describe the shallowness of soils and the limitations of root development. Generally, the efficiency of each system varies despite the differences in their structure and depending on the purpose of using them.
