JWSS - Journal of Water and Soil Science

In this research, the nitrate removal by beech leaves was investigated in batch and column systems. The batch experiment was performed to address the effect of pH, contact time, adsorbent dosage and initial nitrate ion concentration on the nitrate removal. The results showed that with an increase in pH, the removal efficiency and adsorption capacity were decreased and nitrate removal by millimeter and nano adsorbent beech leaves reached equilibrium 120 and 90 minutes after experiment, respectively. With an increase in the nitrate concentration, the removal efficiency was decreased from 59.2% to 39.7% and 82.1% to 69.9% for millimeter and the nanoparticles of Beech leaves, respectively. In fixed-bed column adsorption experiments, the flow rates of 5, 8 and 11 ml/min and the nitrate concentration of 15, 50 and 120 mg/L were studied. The results showed with an increase in the nitrate concentration from 15 to 120 mg/L, the saturation time was decreased from 240 to 150 and 360 to 270 minutes for millimeter and nanoparticles of Beech leaves, respectively. Thomas, Dose-response and Yoon-Nelson models were fitted to the results of the continuous experiments. The Thomas model fitted the experimental data with high accuracy. Compared to the adsorbents, nano-adsorbent had more adsorption capacity in the batch and column systems. 

The scarcity of freshwater resources increases the importance of seawater and brackish water desalination processes. However, a large amount of specific energy requirements, and high operational costs, present a big challenge in adopting desalination technologies. Due to high expenses of energy, desalination of saline waters by low-cost methods is important. The objective of this research was to investigate the ability of two adsorbents (zeolite and graphene oxide) to remove salinity ions from aqueous solutions in Caspian Sea water and water of the well of the Dark zone in Isfahan. At first, some graphene oxide was made according to Homer's method. Then, the characteristics of graphene oxide were known by Fourier transform infrared spectroscopy and using an electron microscope. After that, the ability of adsorbents to remove salinity agent cations and anions was evaluated. To investigate a fixed-bed zeolite column with graphene oxide (GO) layer was used to remove Na⁺, K⁺, Ca²⁺, Mg²⁺, and Cl^– from 50 cc of saline water. Also, Hexadecyl trimethylamine (HDTMA) was used to modify natural zeolites. The results showed that among the adsorbents for the water of the well in the Dark zone, 30 mg graphene oxide with 13 gr zeolite had the highest adsorption rate (23.84 percent of salinity reduction), and for Caspian Sea water, 13 gr zeolite modified by surfactants had the highest adsorption rate (23.43 percent of salinity reduction). Also, the removal of cations and anion followed the sequence: K⁺ >Ca²⁺ >Mg²⁺ >Cl^– >Na⁺.