Showing 5 results for Fluoride
N. Mirghaffari, H. Shariatmadari,
Volume 11, Issue 41 (10-2007)
Abstract
Concentration of soluble fluoride in groundwater, soil, and some crops in Isfahan region was determined by Ion Selective Electrode (ISE) method. The mean fluoride concentration of water samples in the study area was 0.3 and 0.05 mg L-1 in the spring and summer, respectively. These values are in an acceptable limit for irrigation, whereas for drinking water, they are in deficiency range. The average and maximum concentrations of soluble fluoride in soil samples were 1.0 and 3.2 mg kg-1, respectively. In general, the spatial distribution of fluoride in soils showed that fluoride content around major industrial centers such as Isfahan Steel Factory, Mobarakeh Steel Co., and Isfahan oil refinery was higher than other sites. The minimum and maximum fluoride contents of crops were observed in alfalfa as 0.2 and in corn as 4.2 mg kg-1, respectively. Tomato had the highest mean concentration of fluoride as 3.6 mg kg-1. The fluoride concentration in plants positively correlated with the fluoride concentration in irrigation water and soil (P < 0.01) and negatively correlated with cation exchange capacity of soil (P < 0.05).
E. Chavoshi, M. Afyuni, M. A. Hajabbasi,
Volume 19, Issue 72 (8-2015)
Abstract
Fluoride (F) is an essential element for humans and animals. The continuous ingestion of fluoride by humans and animals in excessive amounts has damaging effects. The objective of this study was to investigate the uptake of fluoride in spinach and alfalfa in an alkaline soil of Isfahan, Iran. Two plants were planted in lysimeters at Isfahan University of Technology research station site. The treatments consisted of two plants and three concentrations of F. Each treatment was performed in triplicate. All the plants were harvested after 125 days and the total plants' F concentrations were determined. The F concentration in both plants' roots were higher significantly (p<0.05) than the plants' shoots at both treatments. The F concentration in spinach root was 2.5 to 3 times greater than those values in alfalfa root. Totally, the RCFs and SCFs values of F were very low. This showed that these plants did not uptake much fluoride from the soil.
E. Chavoshi, M. Afyuni, M. A. Hajabbasi,
Volume 19, Issue 72 (8-2015)
Abstract
Transport of fluoride and consumption of groundwater with excess fluoride concentrations poses a health threat to millions of people around the world. The objective of this study was to simulate transport of fluoride (F) using HYDRUS-1D model. The study was conducted in lysimeters at Lavark research station site in Isfahan. The treatments consisted of two concentrations of F (157 and 315 mg kg-1). The duration of the study was 125 days. Some of soil physical and chemical properties, soluble F and total F concentration were determined during the study. The results showed the transport of F in calcareous soil profiles. This may be due to the high pH and desorption of F ion as a result of repulsion by the more negatively charged soil surfaces. The highest concentration of total F and water soluble F were observed in the 10 cm surface soil layer. The concentration of F decreased with increased soil depth. The correlation coefficient was significant between the water soluble fluoride and the total fluoride (1% level). Also, the difference between the observed t- value and a critical value on the t distribution is statistically insignificant. It showed that the model simulated successfully water soluble F concentration in the soil profile.
E. Chavoshi, M. Afyuni , M. Ali. Hajabbasi,
Volume 19, Issue 73 (11-2015)
Abstract
The sorption and desorption of fluoride by soil can play an important role in the transport of fluoride in soil. The study was conducted on the soil from Isfahan University of Technology research station site (two depths of 0-30 and 30- 60 cm). Fluoride sorption reactions were examined by equilibrating 0, 2.5, 5, 10, 25, 50 and 100 mg L-1 NaF solution with soils for 23 hr. The desorption experiments were performed using 0.03 mol L-1 NaCL solutions immediately following the completion of sorption experiments. The sorption isotherms of F were well described by the Langmuir and Freundlich models. The n values for Freundlich isotherm were 0.57 and 0.55 for two depths of the studied soil, respectively. The kF values for Freundlich isotherm were 0.026 and 0.025 mg (1-n) Ln g-1 for two depths, respectively. Maximum monolayer sorption capacities (q max) were obtained to be 0.4 and 0.35 mg g-1 for 1 and 2 layers of the studied soil, respectively. The desorption isotherms of F were well described by the Freundlich model. The fitted model parameters’ (kF and n) values for desorption branches were larger than these values for sorption branches. Also, the results showed a positive hysteresis (ndesrb sorb and kdesorb >Ksorb). It seems fluoride sorption to be reversible.
E. Chavoshi, M. Afyuni, M. A. Hajabbasi,
Volume 22, Issue 2 (9-2018)
Abstract
This study covers a large agricultural and industrial area of Isfahan province, including three types of land use, i.e., agricultural, uncultivated, industrial and urban types. A total of 275 samples from surface soil (0-20 cm) were collected and water soluble fluoride concentrations of them were measured. The spatial structure of water soluble fluoride in the soils was determined by omnidirectional variogram in the GS+ software. The spatial distribution of water soluble fluoride in the soil was mapped by employing the point kriging method in the SURFER software. The results showed that the mean of the water soluble fluoride concentration in Isfahan soils (0.85 mg L-1) was higher than the mean world soils (0.53 mg L-1). The water soluble fluoride showed moderate spatial dependence, indicating that the spatial variability of water soluble fluoride was mainly controlled by intrinsic and extrinsic factors. The mean water soluble fluoride concentration was significantly higher in agricultural and urban areas, as compared with the uncultivated land. This could be due to application of phosphate fertilizer in agricultural areas and the atmospheric fallout of fluoride from the industrial sources such as steel factories. According to the generated kriging map, the higher concentration of fluoride was mainly recorded around the Zayande Rood River and in the central and western parts of the study area.
