JWSS - Journal of Water and Soil Science

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Clay minerals deserve special attention as they play a crucial role in many soils. The clay mineralogy of five gypsiferous soils from different landforms in eastern Isfahan was investigated using X-ray diffraction (XRD). In addition, soil aggregates and wind-deposited sediments were examined by scanning electron microscope (SEM) and analyzed by energy dispersive X-ray analyzer (EDX). The results indicate the presence of palygorskite, mica, kaolinite, chlorite, and quartz with a trace amount of vermiculite and randomly interstratified layers in all soils. Smectite occurs in soils of both the piedmont plain and old river terrace, but not in the alluvial fan soils. Mica, chlorite, quartz, and kaolinite were probably inherited from the parent material. Palygorskite seems to increase with depth in the alluvial fan, whereas, in the old terrace soils, this clay mineral decreases with depth. Palygorskite present in alluvial fan soil appears to have been formed authigenically when the basin was covered with shallow hyper-saline lagoons toward the end of the Tertiary. Palygorskite in the old terrace seems to be mostly detrital and an eolian origin of palygorskite is likely because a large amount of palygorskite is present in upper soil horizons. A higher proportion of smectite in deep soils of the old terrace, as compared with palygorskite, suggests the possibility of authigenic formation of smectite from palygorskite. .

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  Gypsum affects many physical, chemical and mineralogical properties which in turn influences management, classification and sutability of the soils. This is the reason why accurate measurement of gypsum in soil is very important. In most of the soil science laboratories, the method of acetone ,in spite of its too much limitation, is being used as a standard method. The purpose of this research was to compare different gypsum determination methods and to find the most suitable one. The study areas include Jafarabad of Borkhar and Sepahanshahr.Soil samples were collected from different horizons of the studied profiles and seven samples with a wide range of gypsum content were selected. Gypsum content of the soil samples were determined by methods of acetone, sodium carbonate, resin, calcium and magnesium difference, diluted extracted sulfate, ammonium carbonate, sodium citrate and hydrochloric acid. To calculate the recovery percentage of the methods, after adding a certain amount of gypsum with known purity percentage to the soil samples, gypsum content was determined again by above mentioned eight methods. To evaluate the suitability of the methods, in addition to the recovery percentage of the methods, coefficient of variability and extent of proximity of the regression line to the 1:1 line were used. The results revealed that among the used methods, the method of sodium carbonate is the most accurate one. Resin method is ranked as the second best method and can be used in non-saline soils as another accurate method for determination of gypsum content. Sodium citrate and hydrochloric acid methods for different amounts of gypsum and ammonium carbonate method for gypsum content up to 30% are third in rank as far as their accuracy is concerned. Acetone, calcium magnesium difference and diluted extracted sulfate methods are not sufficiently accurate, because of low solubility of gypsum in water which is used as an extractant. In general, the most important determinant of accuracy of the methods is extractants of the gypsum among which the sodium carbonate has the highest efficiency.

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In order to evaluate the effects of sulphur fertilizer sources and amounts on growth indices and yield of peanut (Arachis hypogaea L. CV. NC2), a field experiment was conducted in Bandar Kiaashahr, Guilan province, Iran in 2004. The experiment was laid out in a factorial arrangement with two factors including sulphur sources (gypsum and single super phosphate) and sulphur rates (0, 30, 60 and 90 kg.h-1) in a completely randomized block design with three replications. Results showed that sulphur application greatly enhanced peanut growth and yield. The application of 90 kg.h-1 sulphur (in both forms) performed significantly better than the rest. The highest pod yield and grain yield were obtained in 90 kg.h-1 sulphur in gypsum form (6400 and 5200 kg.h-1, respectively). The highest LAI (6.6), CGR (20.2 g.m-2.12GDD-1) and PGR (16 g.m-2.12GDD-1) were obtained in 90 kg sulphur in the form of gypsum after 1142, 1142 and 1289 of accumulation, respectively. According to the results of the present experiment, it could be concluded that sulphur may considerably increase peanut grain yield and yield components. Thus, it could be expected that the application of 90 kg sulphur per hectare in the form of gypsum may result in better growth indices and higher grain yield of peanut.

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Gypsum is the most common sulfate mineral in soils of arid and semi-arid regions. Two hundred million hectares of the earth’s surface and about 28 million hectares of Iranian arid soils are covered by gypsiferous soils. The studied soils consist of alluvial plane and eolian plains in northern Iran. Soils were classified as Haplocambids, Aquisalids and Endoaquepts. In this study, genesis, formation and development of gypsum in soils were investigated. Study area includes different geomorphic surfaces from the upper watershed to alluvial plains. Gypsum crystals without considering their size, shape, arrangement are determined as pedogenic. In the weakly-developed horizons, in aridic moisture regimes, formation of euhedral pedogenic gypsum crystals and incomplete infilling of voids was dominant. In the well-developed soils, in xeric moisture regime, gypsum crystals are oriented and the perpendicular in arrangement of crystals along pores is dominants. Gypsum crystals occur in different shapes such as lenticular, tabular, and rosette-like and fan arrangement. Origin of gypsum in weakly-developed soils was weathered gypsiferous marls in upper Atrak basin. The source of gypsum in the soils with shallow ground water is high content of sulfate dissolved in soil solutions. In horizons affected by fluctuation of ground water contaning sulphur, euhedral tabular shape is dominant. In well-developed soils, based on Snowball morphology, gypsum is classified as stage II nodule. Results showed that there is no relationship between formation of the snowball morphology, b-fabric and kind of diagnostic horizons (A, B and C).

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Soil structure and aggregate stability affect soil erodibility. There is a necessity for increasing aggregate stability against erosive factors such as wind and water. This study was conducted on surface soil samples (0-20cm) collected from agricultural land susceptible to erosion located in Chahoo, southeast of Fars province. The experimental design was CRD with 10 treatments and was replicated 3 times as follows: control plot (without addition of soil amendments), pure gypsum, chopped wheat straw, farm yard manure, gypsum+wheat straw, gypsum+ farm yard manure (1% w/w), cement at levels (0.3% w/w), (0.6% w/w), (0.9% w/w), gypsum +cement (0.9% w/w). After one, four and seven months, the amounts of soil aggregates in 53-4000 µm sizes were determined by wet sieving and MWD was calculated. The results of aggregate size distribution in every stage of the experiment showed that application of farm yard manure and wheat straw separately or in combination with gypsum through reduction in aggregates with diameters of <106 µm has caused an increase in aggregates with diameter of >106 µm. Based on the results of this research, the effect of these treatments, which increased MWD of the aggregate, results from the amount of aggregates with diameters larger than 1000 µm. According to the results of this study, it is suggested that these treatments be considered suitable to increase the stability of sensitive silt loam soils.

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Calcareous and gypsiferous soils are restricting factors for uptake of some plant nutrient elements and plant production. Most soils in Iran are calcareous and gypsiferous. Therefore, the aim of this study was the evaluation of calcium carbonate (Caco3) and gypsum effect on availability of some nutrients and corn growth. This study was conducted in a greenhouse at Vli-e-Asr University of Rafsanjan. Treatments were arranged in a factorial manner as a completely randomized design with three replications. Treatments were three levels of Caco3 (0, 20 and 40 g/100g soil), gypsum at three levels (0, 15 and 30 g/100g soil) and two soil textures (Sand and Silt clay loam). Results indicate that irrespective of soil texture, Caco3 application significantly decreased leaf area (by 80% and 15% for sand and silty clay loam texture, respectively), dry weight (by 80% and 15% respectively), plant height (regressed on Caco3 percentage by slopes -0.7 and -0.15 for sand and silty clay loam respectively), and shoot Fe (-9.67 and -11.3) and Zn (-0.24 and -1) uptake, but had no significant effect on shoot Cu uptake. In sandy soil, application of gypsum, significantly decreased leaf area (80%), dry weight (62%), and shoot Cu uptake (slope= -1.93), but had no significant effect on plant height and shoot Zn uptake. Gypsum application significantly reduced shoot Fe uptake (slope= -24.86) in fine textured soil, but it had no significant effect in coarse textured soil.

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Magnetic susceptibility measurement is a simple and quick technique for characterizing soils and sediments and describing soil-forming processes. The interpretation of soil magnetic susceptibility data needs sufficient knowledge about the factors affecting this parameter. To identify the effects of parent material, gypsum and calcium carbonate equivalent, 42 samples were taken from horizons of soils developed on loessial, alluvial, granitic and marly materials in southern Mashhad. Gypsum and carbonates of soil samples were removed by successive washing with distilled water and diluted HCl, respectively. Magnetic susceptibility of bulk samples (lfbulk), gypsum free samples (lfGf), gypsum and carbonates free samples (lfGCf) and gypsum, carbonates and sand free samples (lfGCSf) was measured. The results revealed a strong 1:1 correlation between the measured and calculated lfGf and lfGCf. Despite the high amounts of gypsum and carbonates in soils developed on marls, their lfbulk was much more than that of the other soils and reached up to 121.8×10-8m3 kg-1. In contrast, the lfbulk values of saprolitic granite were less than 10.4×10-8m3 kg-1. The lfbulk values of loessial and alluvial soils were less than those of marly soils but higher than those of soils developed on saprolitic granite. lfbulk values were negatively correlated with the amount of sand. However, reduction in magnetic susceptibility values of marly soils after removing sand reflects the different nature of this soil. The correlation between lfbulk and amount of silt and clay is positive, but the magnetic susceptibility values are more sensitive to clay percentage, indicating the more important contribution of clay to magnetic susceptibility values. The results of this study highlight the role of parent materials, gypsum and carbonates in the soil magnetic susceptibility values that should be considered.

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Vis-NIR spectroscopy has been introduced as a non-destructive, fast, and cheap technique, with minimal sample preparation and no loss or damage to the environment. No investigation has yet been carried out to examine the ability of this method to estimate soil properties in Iran. The objective of this research was to investigate the capability of Vis-NIR spectroscopy to predict the amount of organic matter, carbonate and gypsum in surface soils of Isfahan province. A total of 248 surface soil samples were collected from the study area. Soil organic matter content, gypsum and carbonates percentages were measured by standard laboratory methods. Soil spectral analyses were performed by a field spectrometer using 350-2500 nm wavelength range. Different pre-processing methods were evaluated after recording the spectra. Partial least squares regression was used to predict soil parameters. R2 values for organic matter, carbonates and gypsum were 0.61, 0.45 and 0.8, respectively. Based on RPD (Ratio of Prediction to Deviation) values, the precision of prediction model for gypsum was quite good, and acceptable for organic matter, whereas the prediction of the model for soil carbonates was poor. Consequently, vis-NIR spectroscopy is capable of predicting some soil properties simultaneously and the model accuracy is acceptable.