JWSS - Journal of Water and Soil Science

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Of all types of xenobiotics, pesticides such as herbicides play a significant role in soil and water pollution due to their widely usage all over the world. This study addresses the ability of organic amendments to enhance atrazine and metamitron degradation in two herbicide contaminated soils with contrasting textures under laboratory conditions. Soil samples were collected from surface soils with textures of sandy loam and silty clay, from northeastern part of Iran. Initial concentration of herbicides was 50 mgkg^-1 soil. Contaminated soil samples were treated by manure, compost and vermicompost at the rates of %0.5 and %2 (w/w). Residual concentrations of atrazine and metamitron were determined by HPLC at the end of incubation periods of 20,40 and 60 d. Residual concentrations of atrazine were 93, 77.8 and 72.4 % of the initial concentration after 20, 40 and 60d incubation, respectively. Residual metamitron concentrations were clearly lower than atrazine. After 20,40 and 60 d., the remaining concentrations of metamitron were 5.8, 2 and 1.2 %, respectively. Organic amendments at the rates of .5 and 2 % showed similar effects on the enhancement of herbicides degradation in soils. However, no significant effect was observed between types of organic amendments. Degradation was clearly affected by soil textures. Residual concentrations of herbicides were higher in sandy loam than in silty clay soil.

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The recent years' problems of herbicide use have led a growing number of researchers to seek alternative methods that are less reliant on herbicides. This research was conducted to determine the effect of long-term crop rotation, mineral fertilizer and herbicide on the weed infestation and grain yield of winter rye during 2004 and 2005 at the long-term experimental site of the University of Timiriazev, Moscow. Treatments were control (no weed control), herbicide, combined fertilizer (NPK) and NPK plus herbicide in field winter rye cultivated in continuous and crop rotation with other crops since 1912. Crop rotation significantly decreased weed density and dry mass. Long-term NPK application significantly decreased weed density, but had not any effect on weed dry mass. Crop rotation, NPK application and herbicide increased ground crop cover and decreased ground weed cover. In continuous crop, weed ground cover was 10 % in control plot and 3.33 % in plots where NPK was applied. Data showed that long-term crop rotation and NPK application can reduce weed infestation and increase grain yield of winter rye.

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To study the goosegrass (Eleusine indica (L.) Gaertn.) in tall fescue (Festuca arundinacea Schreb.), an experiment in 15-year old turf was conducted during 2006 in Tehran in Sheikh Fazlollah highway using randomized complete block design with 4 replications in 1*1 m2 plots. Treatments were diclofop methyl at 2.5 and 3 Lha-1, fenoxaprop-p-ethyl at 0.8 and 1 Lha-1, clodinafop propargyl at 0.6 and 0.8 Lha-1, tralkoxydim at 1 and 1.2 Lha-1, sulfosulfuron at 27 and 35 gha-1 and untreated control. All treatments were repeated 3 times during the growing period of goosegrass. The results showed that after the last spraying, diclofop methyl at 2.5 and 3 Lha-1, fenoxaprop-p-ethyl at 0.8 and 1 Lha-1, clodinafop propargyl at 0.6 and 0.8 Lha-1 decreased goosegrass's biomass up to 81, 83.64, 81.26, 78.58, 80.27 and 81.26 percent, respectively and goosegrass's density up to 82.5, 83.13, 79.38, 79.38, 78.75 and 80.63 percent, respectively, without significant differences. Treatment after 2 times of spraying controlled goosegrass more than 80 percent. Tralkoxydim and sulfosulfuron decreased goosegrass' biomas and density about 70 and 60 percent, respectively. One week after the last spraying, diclofop methyl, fenoxaprop-p-ethyl and clodinafop propargyl treatments did not decrease tall fescue's biomass without significant differences with untreated control. Turf biomass was decreased by tralkoxydim at 1 and 1.2 Lha-1 and sulfosulfuron at 27 and 35 gha-1, by 37.54, 36.79, 40.48 and 48.55 percent, respectively. Herbicide treatments made visual rating by 49.38, 48.75, 48.75 and 50.63 percent, respectively. Overall, diclofop methyl at 2.5 Lha-1, fenoxaprop-p-ethyl at 0.8 Lha-1 and clodinafop propargyl at 0.6 Lha-1 can be recommended for goosegrass control in tall fescue because of insignificant differences between both their doses, bio-environmental problems, costs, and no damage to tall fescue.

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This study was conducted to compare the impact of various organic amendments with different C/N ratios and chemical compositions on biological and chemical degradation of Atrazine in sterile and non-sterile soils. The experiment was carried out in a factorial arrangement (2×6×2) including two soil types (sterile and non sterile soils), six types of organic amendments (vermicompost, cow manure, glucose, starch and sawdust and without organic matter) and two levels of inorganic nitrogen fertilizer (0 and 250 mg kg-1), with three replications. Initial Atrazine concentration in soil samples (silty loam) was adjusted at 100 mg.kg-1. Soil samples were amended by organic materials at the rate of 5% by weight and treated with 250 mg inorganic nitrogen fertilizer( NH4NO3). Half of soil samples were sterilized by HgCl2. Residual Atrazine concentration in soil samples were determined by HPLC at the end of 20, 40 and 60 days incubation time. The results showed that all the applied organic amendments (except for cow manure) and inorganic nitrogen treatment reduced biological degradation of Atrazine in non- sterile soil samples. It was not possible to predict the biological degradation of Atrazine based on C/N ratio of organic amendments and microbial activity. The results also showed that chemical degradation of Atrazine after 60 days of incubation was not affected by organic amendment and inorganic nitrogen fertilizer.

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The application of herbicides as organic chemical compounds to control pest and weeds may affect the population and activity of microorganisms, and this may have an influence on biochemical processes that are important for soil fertility and plant growth. The primary objective of this study was to evaluate different loading rates of eradican (EPTC) on soil microbial biomass C and N, microbial biomass C/N ratio and the activities of urease and arylsulphatase under field conditions. In this experiment, loading rates of 6 and 9 L ha-1 eradican were applied to a calcareous soil cultivated with corn (Zea mays L.) and left uncultivated using split-plots arranged in a completely randomized block design with three replications. The experiment was conducted in the Kabootarabad’s Agricultural Research Center, Isfahan. Soil microbial biomass C and N were determined at 30th and 90th days after the onset of experiment and the activities of urease and arylsulphatase were assayed at 30th, 60th and 90th days. Results showed that in soils cultivated with corn microbial biomass C increased with increasing eradican levels and in both cultivated and uncultivated soils microbial biomass N and microbial biomass C/N ratios were increased over the control. At 30th day, urease activity at 6 L ha-1 level reduced, while at 9 L ha-1 level it increased compared with the control soils. At 60 day, there was no significant difference in the urease activity between the treatments. At 90th day, the activity of urease showed slight fluctuations. There was a reduction in arylsulphatase activity of the cultivated soils by increasing the loading rates of eradican during the experiment, and in uncultivated soils no trend was observed. Briefly, the use of eradican can cause either reduced or increased microbial biomass sizes and enzyme activities in calcareous soils These changes, however, depend largely upon the application rate of eradican, time elapsed since eradican application (i.e., sampling date) and the presence or absence of plant