JWSS - Journal of Water and Soil Science

Fruits and citrus wastes are generated in the food industry in large quantities. Their management in Iran, as one of the major hubs of fruits and citrus production, is of great importance. In this study, the biochar samples were prepared from pomegranate, orange and lemon peel waste produced in a juice factory using the pyrolysis process in the range of 400-500 °C; then their efficiency for zinc adsorption from an aqueous solution was investigated. The kinetic and isotherm data of zinc adsorption were fitted by the linear and nonlinear forms of the Langmuir and Frendlich isotherm models and the first-order and second-order pseudo-kinetics models. The results showed that under the experimental conditions applied, the maximum amount of zinc absorption by biochars derived from pomegranate, orange and lemon peel was 2.42, 1.83 and 3.17 mg/g, respectively. The results of adsorption isotherm models also showed that the use of the linear form could lead to a completely different interpretation, as compared to the original form of the model. Based on the linear forms, the Langmuir isotherm was the best; meanwhile, according to the non-linear forms, the Freundlich isotherm was the best model to describe the adsorption data. In addition, the reaction kinetics indicated that both original and linear models had the same results, and the data were better fitted by the pseudo-second order model.

The reuse of treated wastewater in countries such as Iran that suffers from drought is considered an important challenge in water management programs. The application of modern wastewater treatment systems particularly attached growth systems, owing to the short time required for start-up, low land requirements, and the absence of problems associated with sludge handling may be a resolution. The objective of this study is to investigate the performance of the Moving Bed Biofilm Reactor (MBBR) in treating synthetic municipal wastewater and selecting an appropriate model. In this way, a bench-scale reactor possessing an effective volume of 15 liters, and synthetic wastewater with influent COD of 500 mg/l (similar to typical municipal wastewater) has been used and the experiments with media filling percentages of 30%, 50%, and 70% and hydraulic retention times (HRT) of 4, 8, and 12 hours have been carried out. The observed data show that the optimum bulk density and hydraulic retention time are 50% and 4 hours, respectively. Also, the kinetic study of reactor performance indicates that Grau second-order model has better conformation with Moving Bed Biofilm Reactor results. In addition, a regression model for predicting effluent COD based on the filling percentage and retention time is presented.