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Showing 2 results for Kinetic Models

S. Soodaee Mashaee, N. Aliasgharzade, S.h. Ostan,
Volume 11, Issue 42 (1-2008)
Abstract

  Understanding nitrogen mineralization from different organic sources should be a key factor in developing efficient prediction of the need for nitrogen fertilization with minimal negative environmental impact. In order to investigate nitrogen mineralization rate in soils amended with compost, vermicompost and cattle manure, an experiment was done as factorial in a randomized complete block design in three replications. Four treatments (compost, vermicompost, cattle manure and soil alone), two temperature levels (8 and 25 0C) and two moisture levels (50% and 85% FC) were used for the 90 - day incubation study. Ammonium and nitrate were measured by spectrophotometer method. Results indicated that the mixed first-and zero-order kinetics model is the best model for our data. Cattle manure treatment had the highest Nmin at 25 0C (87.78 mgN/kg equal to 14.54% Ntotal) and the least value (23.62 mgN/kg equal to 4.62% Ntotal) was obtained for the compost treatment at 8 0C. N0k (nitrogen availability index) for treatments was in the following order: Cattle manure>Vermicompost >Compost. With increasing the temperature and moisture, N mineralization increased. Also Nmin positively correlated with N0 (r =0.583*), and N0k (r =0.834**).


R. Torki Harchegani, N. Mirghaffari, M. Soleimani Aminabadi,
Volume 23, Issue 2 (9-2019)
Abstract

Fruits and citrus wastes are generated in the food industry in large quantities. Their management in Iran, as one of the major hubs of fruits and citrus production, is of great importance. In this study, the biochar samples were prepared from pomegranate, orange and lemon peel waste produced in a juice factory using the pyrolysis process in the range of 400-500 °C; then their efficiency for zinc adsorption from an aqueous solution was investigated. The kinetic and isotherm data of zinc adsorption were fitted by the linear and nonlinear forms of the Langmuir and Frendlich isotherm models and the first-order and second-order pseudo-kinetics models. The results showed that under the experimental conditions applied, the maximum amount of zinc absorption by biochars derived from pomegranate, orange and lemon peel was 2.42, 1.83 and 3.17 mg/g, respectively. The results of adsorption isotherm models also showed that the use of the linear form could lead to a completely different interpretation, as compared to the original form of the model. Based on the linear forms, the Langmuir isotherm was the best; meanwhile, according to the non-linear forms, the Freundlich isotherm was the best model to describe the adsorption data. In addition, the reaction kinetics indicated that both original and linear models had the same results, and the data were better fitted by the pseudo-second order model.


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