S. Vaseghi, M. Afyuni, H. Shariatmadari, M. Mobli,
Volume 7, Issue 3 (10-2003)
Abstract
Excessive application of sewage sludge leads to the accumulation of potentially toxic elements in soils. The objective of this greenhouse study was to examine the DTPA–extractability of Fe, Zn, Cu, Mn, Pb, Cd, Ni, and Co in relation to soil pH and to investigate the concentrations of these metals in corn (Zea mayz). The study was conducted using a factorial experiment in a completely randomized design with three replications. Sewage sludge was applied at 0, 50, 100, and 200 t/ha on four soils [Langaroud (pH= 4.8), Lahijan (pH= 5.7), Rasht (pH= 6.8), and Isfahan (pH= 7.9)]. Application of sewage sludge significantly increased DTPA-extractable Fe, Zn, Cu, Pb, Cd, and Ni in all soils. The increasing effect was in accordance with sludge level. Langaroud soil had the highest and Isfahan soil the lowest levels of DTPA-extractable metals. Application of sewage sludge increased plant growth and metals in the foliage of corn plants. The metal concentration in corn tissues also increased with decreasing soil pH. Overall, the application of sewage sludge as an organic material, particularly in acid soils, may increase availability of heavy metals, which may, in turn, result in soil pollution. Therefore, addition of sewage sludge to soils should be managed on the basis of the changes in soil heavy metal concentration.
H. Kheirabad, A. H. Khoshgoftarmanesh, Z. Khanmohamadi,
Volume 16, Issue 62 (3-2013)
Abstract
Due to soil and plant zinc (Zn) deficiency and its effect on reducing yield and quality of agricultural products, application of Zn fertilizers has been intensified in recent years. To achieve optimum fertilizer management, knowledge of factors affecting Zn availability in soil and its uptake by plant is required. Therefore, this study was carried out to investigate the effect of certain soil physiochemical properties on Zn availability in soil and its uptake by corn. The experiment was laid out in a completely randomized design with factorial combination and three replicates in the research greenhouse of Isfahan University of Technology, in winter 2009. In this greenhouse experiment, 11 soil series were exposed to two Zn levels (0 and 15 mg Zn kg−1 in the form of zinc sulfate). The results indicated that Zn application significantly increased the dry matter weight and shoot and root Zn concentration of corn, although the magnitude of this increase varied depending on the soil type. There was no significant correlation between the DTPA-extractable Zn and the uptake of this nutrient element by corn. There was a negative significant correlation (P < 0.05) between the equivalent calcium carbonate content and available P with the DTPA-extractable Zn. A significant linear relationship (R2 = 0.31) was found between the buffer capacity of soil for Zn and clay content. According to the results obtained from the stepwise regression analysis, the DTPA-extractable Zn and buffer capacity of soil for Zn were not correlated with other measured soil properties.
A. Abdollahi, M. Norouzi Masir, M. Taghavi, A. Moezzi,
Volume 24, Issue 2 (7-2020)
Abstract
Nowadays, one of the ways to confront with the micronutrients deficiency is application of Nano materials to increase the availability of elements such as zinc for plants. Therefore, this study was conducted to investigate the effect of functionalized iron oxide nanoparticles and zinc sulfate chemical fertilizer on the zinc chemical forms in soil solution phase and its correlation with zinc concentrations and uptake in wheat. This study was carried out in a completely randomized design with three replications. Treatment consisted of functionalized iron oxide nanoparticles of Hydroxyl (OH), Carboxyl (COOH) and Amine (NH2), each at three levels (100, 200 and 300 mg.kg-1), ZnSO4 (40 kg.ha-1) and Control (without using iron oxide nanoparticles). At the end of the cultivation period, soil chemical properties such as pH, soil available zinc and dissolved organic carbon and concentrations and the uptake of zinc in plant were measured. The results showed that pH, available zinc and dissolved organic carbon content of soil solution were significantly affected by the treatments. The results obtained from the Visual MINTEQ Geochemical model showed that the highest amount of the free form of zinc (Zn2+) was obtained at the level of 300 mg.kg-1 of carboxyl iron oxide nanoparticles. Also, the experimental treatments significantly influenced the concentration of Zn-DOM species. The positive and significant correlation between Zn+2 and Zn- DOC species with the concentration and total Zn uptake of wheat indicated that these pools of Zn could be liable species in soil. The results of this study, therefore, showed that the application of functionalized iron oxide nanoparticles could help to improve soil conditions in order to increase the zinc availability for plants.
S. Shakeri, A. Azadi, M. Saffari,
Volume 24, Issue 4 (2-2021)
Abstract
Determining the relative distribution of each chemical form of the elements and their relationship with the physical, chemical, and clay mineralogical properties of soils can help researchers to achieve the sustainable agricultural management. The present study was conducted to evaluate the chemical forms of four micronutrients (Zn, Cu, Fe and Mn) in some surface and subsurface soils of Kohgiluyeh and Boyer Ahmad province and their relationship with the physical, chemical and mineralogical properties of the soils. The results showed that the exchangeable and sorbed chemical forms of the studied elements were very low and negligible, but the residual, carbonate, and organic forms had the highest to lowest values of the chemical forms of these elements, respectively. Examination of the correlation of the chemical forms of these elements with soil properties showed the effective correlation of organic carbon values with the Zn chemical forms; also, there was a correlation between clay, silt, cation exchange capacity and calcium carbonate and the chemical forms of Cu, Fe and Mn. The correlation between the quantities of clay minerals and the chemical forms of these elements showed that the amounts of different forms of the studied elements were directly related to 2:1 clay silicate minerals (especially vermiculite). Evaluation of Fe and Mn chemical forms also showed that the amounts of these elements were higher in the soils with developed profiles (Alfisol and Mollisol), the wetter climate and zeric moisture regime rather than in soils with non-developed profiles (Entisols and Inceptisols) and a drier climate and a ustic moisture regime. In general, the results showed that variations of soil forming factors such as climate (as well as the total amount of each micronutrients), could be effective on the chemical forms of micronutrients (especially on Mn and Fe); these can be effective in the management of weakly to highly-developed soils orders.
