Showing 2 results for Nonexchangeable K
A. R. Hosseinpur,
Volume 8, Issue 3 (10-2004)
Abstract
Information about nonexchangeable potassium (NEK) release rate in Hamadan soils is limited. The objective of this study included an investigation of the dynamics of NEK in some soils from Hamadan Province by successive extraction with dilute citric acid over a period of 2500 h and determination of the correlation between the rate constants in this kinetic equation with soil properties. The results of this experiment showed that the initial NEK release rate was rapid which slowed down later on. The amount of NEK released after 2500 h ranged from 0.87 to 2.89 cmol kg-1. The amount of NEK released after 2500 h was significantly correlated with CEC, NEK, and soil separates. First order, parabolic diffusion law and power function equations described well the NEK release kinetics based on their highest determination coefficient and their lowest value of the standard error of the estimate. Release rate constant in the first order, parabolic diffusion law and power function equations ranged from 1.0×10-4 to 3.0×10-4, 1.7×10-4 to 10.6×10-4 and 2.75×10-1 to 4.6×10-1, respectively. In the correlation study the rate constants in the kinetic equations were correlated with some chemical properties and particle size distribution. The results of this experiment also showed that dilute citric acid can be used in the study of NEK release.
S.j Hosseinifard, H Khademi, M Kalbasi,
Volume 13, Issue 50 (1-2010)
Abstract
This study was conducted to determine the effect of 3 extractants on K release from biotite, phlogopite and muscovite. The minerals were grouped to <60 and 60-100 µm size classes. Particles CEC were saturated with calcium. Sequential extraction up to 30 times was carried out using 0.01M HCl, 1M NH4OAc and 0.05M BaCl2 solutions and cumulative concentration of K was calculated for each extractant. There was a difference among the 3 extractants in cumulative K release values from the three minerals. The highest values of cumulative K release were obtained by 0.01M HCl and 1M NH4OAc for less than 60 and 60-100 µm particle sizes, respectively. The amount of K release from muscovite was even higher when 1M NH4OAc and 0.05M BaCl2 solutions were used as extractants. This might indicate that muscovite cannot be considered as an ineffective source of available K in soils. Furthermore, particle size had a great impact on nonexchangeable K release from micaceous minerals. Coarser particles released higher quantity of K as compared to that of finer particles. Therefore, particle size distribution of different micaceous minerals in soils may be a factor that causes a difference in the amount of K release from soils.
