JWSS - Journal of Water and Soil Science

This study was done to evaluate the effect of topography, water table, and irrigation on gypsc soil development and clay mineral diversity in Ram-Hormuz Plain, Khuzestan Province. To localize, 10 profiles in this region that covered all purpose irrigation and topography situation were described. The results showed that the soils could be classified in Entisols, Inceptisols and Aridisols orders. All soil epipedons were ochric and subsurface horizons were cambic, gypsic, and salic. The salic horizons were formed under a low water table. The XRD results showed that smectite, kaolinite, illite, chlorite, palygorskite, vermiculite and sepiolite were the dominant minerals, respectively. Kaolinite and illite were inherited from the parent material, but chlorite was the result of both inheritance and transformation of other clay minerals except uncultivated or non-irrigated soils. Sepiolite was decreased in gypsic horizons, but palygorskite was increased in these horizons. Sepiolite was raised with increasing the depth under the good drainage class; this could be related to neoformation, but it was decreased with depth under the weak drainage class. These results could be due to the instability of this mineral in high moisture and its low Mg activity. There was also a negative correlation correlation between Palygorskite and smectite; this was such that most palygorskite was observed in the surface horizons, but smectite was in the subsurface. Smectite was the dominant clay mineral in the studied soils; it was formed from the weathering of other minerals as well as from neoformed ones in the lowlands. Vermiculite was formed in these soils due to k depletion by leaching or plant absorption. This happened in the illite to smectite transformation process. Therefore, topography and irrigation could be regarded as the main factors putting these soils in high category; also, clay mineral assemblage was different under this situation in these soils.

Understanding the abundance of clay minerals in soil and also, their spatial variability can provide more comprehensive information about soil properties, behavior and functions. The objectives of this research were: (i) to map the spatial distribution of  the dominant clay minerals in the soils of Isfahan Province and its relationship with climate and parent materials, and (ii) to determine the quantity of  the dominant clay minerals in different climatic classes of Isfahan Province. The amount of palygorskite, illite, expanded minerals and chlorite were semi-quantitatively determined for 100 soil samples collected from Isfahan Province. Maps of the dominant clay minerals were prepared by the Inverse Distance Weighting method. The results showed that palygorskite mostly occurred in the soils of dry areas with higher temperature throughout the province. This mineral was not present in the more humid areas of the province. Besides, palygoskite was found to be dominant in the soils derived from the Qom Formation, as well as Lower and Upper Red Formations belonging to Miocene and Pliocene. It seems, therefore, that the parent material plays a major role in entering palygoskite to the soil system, while the dry climate mostly guarantees the stability of this clay minerals and, to some extent, its limited neoformation in such soils. Both illite and chlorite occur in all soils throughout the province, regardless of their climate, following no particular trend. This may indicate that parent materials play a major role in the occurrence of these minerals. Both climate and parent material appear to have affected the distribution of expandable clays in the soils. In more humid areas of the province (west and southwest), climate plays a larger role in the distribution of this mineral. In other areas of the study region, especially in the eastern parts of the province with a much drier climate, the role of the parent material on the dominant soil clay minerals is more pronounced.