JWSS - Journal of Water and Soil Science

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Lintz-Donawitz (LD) converter slag, a by-product of the iron and steel-making industry is produced in large quantities in Isfahan, Iran. The slag contains 52.8 and 2.2% (w/w) CaO and MgO, respectively. To determine the influence of LD slag on the chemical characteristics of three acid soils from Gilan, an incubation study was conducted. The soil samples were collected from 0-30 cm of rice and tobacco fields and a tea garden. Treatments were 0, 0.5, 1, 2, 4, 8 and 16 % (w/w) of converter slag/kg soil. The slag was thoroughly mixed with 500g soil in plastic pots. Soil moisture content was adjusted to near field capacity and changes in pH, EC and AB-DTPA-extractable Fe, Mn, Zn, P and K were determined at 1, 10, 30 and 60 days. Results showed that soil pH increased with increasing slag rates. Slag increased AB-DTPA-extractable P and Mn, the magnitude increase depend on the amount of slag applied. However, the effect of slag on AB-DTPA-extractable Fe depended on initial pH, initially decreasing at the pH range of 7.4 - 8.5 and then increasing at higher pH levels. Slag decreased AB-DTPA-extractable K especially in highly acid soil. In the present study, soil pH and AB-DTPA-extractable Fe decreased with time, though the effect of incubation time on pH was not significant. The effect of incubation time on AB-DTPA extractable Mn and P was different. Time effect on EC and AB-DTPA-extractable K was not significant. In general, soil chemical characteristics were more affected by slag rates than by incubation time. In conclusion, it seems that converter slag is a suitable amendment for acid soils. It is suggested that the effect of LD converter slag on plant growth and chemical characteristics of acid soils be studied under field conditions.

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  Application of slag and converter sludge, major by-products of Esfahan Zob Ahan factory, to enrich two organic amendments for corn nutrition, was investigated. Farm manure and its vermicompost mixed with different rates of slag and sludge were incubated in 3 Kg pots at field capacity moisture and home temperature for three months. The applied rates of slag and sludge were 0, 5 and 10 percent (w/w) of pure iron from these compounds to the organic amendments. Iron sulfate with the above ratios was also examined for comparison. Sub-samples of the incubated materials were taken after 0, 10, 25, 45, 65 and 90 days of incubation and examined for DTPA extractable Fe, Mn, Zn and Cu. After the incubation, the enriched amendments were applied to a soil sample to grow corn. Three Kg soil samples, taken from Chah Anari experimental farm, Esfahan University of Technology, were mixed with 17 gr of the amendments (50 ton/ha) placed in 3 Kg pots. In each pot two corn seeds (single cross 704) were planted and after 70 days crop yield and concentration of Fe, Mn, Zn, Cu in the plant tissues were determined. Results showed that the use of iron sulfate strongly increased DTPA extractable Fe and Mn of the amendments. In enrichment by converter sludge, the best result was obtained in the mixture of 10 percent pure iron with the vermicompost on 60 days of incubation. Treatment of 5 percent pure iron from slag mixed with the manure increased DTPA extractable Fe and Mn with the time, but the 10 percent treatment was not much effective in this regard. The highest rates of iron uptake by the plants occurred in the iron sulfate and 10 percent converter sludge treatments, respectively however, the highest rate of the plant Mn uptake was observed in 5 percent iron from converter sludge mixed with vermicompost. In general, 10 percent pure iron from converter sludge was the most effective enrichment treatment, increasing the plant uptake of Fe, Mn, Zn and Cu micronutrients.

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Many researchers have reported positive effects of converter sludge and slag, two by-products in Isfahan iron melting factory. In this work, the optimum rate of application and the availability of some essential elements (for plant growth) in the converter sludge and slag for corn were investigated. The converter sludge contains about 64% Fe ІІ and ІІІ oxides and some other essential elements for plant growth. The slag also contains 17% iron oxides, 52.8% calcium oxide as well as considerable amounts of some other elements. Treatments included a control, Fe-EDTA foliar spray with 5 in 1000 concentration, application of sludge in 4 levels (L1, L2, L3 and L4 equal to 5.83, 13.33, 20.83 and 26.67 ton/ha, respectively) and application of slag in 4 levels (S1, S2, S3 and S4 equal to 3.20, 7.28, 11.36 and 15.44 ton/ha, respectively) which supply 1, 2, 3 and 4 times as much as soil test recommends, based on AB-DTPA extractable Fe in the soil. Corn (Zea mays) single cross 704 was planted for the experiment. Applications of the two compounds increased the soil extractable Fe and Mn, decreased Mg but the treatment did not change the soil-extractable Zn, Cu and Ca. The corn yield also increased due to the applications of the two compounds and the maximum yield was related to L3, L4, S3 and S4 treatments. The foliar application treated the leaf chlorosis and increased the silage, grain and leaf + stalk yields however, this was not as efficient as sludge and slag application. Also applications of the two compounds increased the Fe, Mn, Zn, Cu, Ca and Mg uptake by corn. The L3 and S3 treatments can be recommended as the proper levels of these compounds as iron fertilizer.

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Iron deficiency is most widespread among plant nutrients. Nowadays, different materials such as inorganic salts, organic chelates, soil acidifying materials and industrial wastes are used to correct iron deficiency. Slag and convertor sludge of steel factories are among the industrials wastes for this purpose. These materials contain considerable amount of iron produced in large quantities every year. Application of slag and convertor sludge to soil may affect bioavailability and chemical forms of iron in soil. Sequential chemical extraction technique has been widely used to examine these chemical forms, and thus to better understand the processes that influence element availability. It was, therefore, the objective of this study to investigate the application effect of slag and convertor sludge of Esfahan Steel Mill on the chemical forms of iron, distribution of these forms and bioavailability of iron in surface (0-20cm) and subsurface (20-45cm) soil of three research fields. The results showed that more than 99% of the applied Fe occurred in residual, Fe oxide and hydroxide and free forms. Application of slag and convertor sludge for three consecutive years increased chemical forms and DTPA extractable iron in surface and subsurface soil of three fields.

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