JWSS - Journal of Water and Soil Science

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The calcification of soils and the effects of topography on this process were studied in semi-arid regions of Kermanshah. From a toposequence, based on the previous soil surveys of the region, five profiles were selected, and field studies and laboratory analyses were carried out on soils. Alluvial - colluvial fans, piedmont alluvial plains, and old plateaux were three main physiographies on the selected toposequence. Soil moisture and temperature regimes were Xeric and Thermic, respectively. The results indicate that redistribution of carbonates and soil formation processes may be categorized in four specific stages to be described in the text. Accumulation of calcium carbonates in soil profiles showed two basic forms: one in sandy layers of fine - textured soil profiles under the influence of abrupt textural changes and lower permeability, and the second in subsurface horizons of soils with calcareous parent material. The morphological evidences showed that in addition to translocation from upper horizons of carbonates by solution and suspension, physical movements to subsurface layers of fine calcareous materials have also affected the formation of calcic horizons. In other words, CaCO3 may have moved as fine particles through soil cracks and subsequently accumulated in the lower horizons. Soil mineralogy showed considerable amounts of illite, Chlorite, smectite and palygorskite clay minerals. Some pedogenic transformations of illite and chlorite may have caused formation of smectite and palygorskite.

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  Studying soil phosphorus fractions is useful in understanding soil pedogenesis as well as soil fertility. In this reseach, 20 soil samples were taken from different depths of 0-30 and 30-60 cm of upper-slope, mid-slope and lower-slope positions of four toposequences in arid (Jei and Ziar in Isfahan) and semiarid (Farokhshahr and Shahrekord) regions. In each toposequence, the soil depth was relatively low at the upper-slope position and increased toward the lower-slope. The soils in upper-slope and mid-slope were under scarce native vegetation where the soil in lower-slope was under farming activities. Soil phosphorus (P) fractionation was carried out using sequential extraction. The total soil phosphorus was in the range of 302-1135 with an average of 715 mg/kg. About 65-89% of total phosphorus were inorganic, and 11-35% organic. The amount of inorganic and organic P in the soil samples was in the range of 204-897 with an average of 571, and 70-238 with an average of 114 mg/kg, respectively. The amount of total, inorganic and organic P increased from upper-slope toward the arable lands and decreased from topsoil to subsoil in all toposequences. In the studied soils, apatite ( Ca₁₀-P ), aluminum phosphates(Al-P), octacalcium phosphates( Ca₈-P ), iron phosphates (Fe-P), iron oxides occluded phosphates( OC-P ) and dicalcium phosphates( Ca₂-P ) were the major constituents of the soil inorganic phosphates, respectively.

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Mineralogy is one of the most influential soil properties that change from upper- to lower slope positions, depending on the climate differences. Such changes affect soil properties such as phosphorus sorption and desorption processes differently. Therefore, this study was carried out to investigate the clay mineralogy of soils in four toposequences from arid (Isfahan) and semiarid (Chaharmahal Bakhtiari) regions and its effect on soil P release. The soils of three points on each toposequence were sampled as the upper-slope mainly containing parent materials the mid-slope, non-arable lands and the lower-slope, arable lands. Some of soil properties such as clay minerals were determined. Also, trend of P release parameters was studied in four toposequences. Results showed that the amount of clay, cation exchange capacity (CEC), electrical conductivity (EC), and pH of the soils increase down the slope in all toposequences. X-ray diffractograms showed that kaolinite and illite in upper slope and smectite and chlorite in lower slope were the predominant clays. Among the kinetic models examined based on their determination coefficient and standard error, the Elovich equation was chosen to describe the P release kinetics in studied soils. The trend of P desorption rate along the arid toposequences was in the following order: upper-slope < mid-slope < lower-slope. Furthermore, the rate of P desorption in soils of the semiarid toposequences was higher than arid toposequences. Regarding the trend of P rate parameters along the toposequences, it could be concluded that P release rate and the soil capacity to supply P for plants increase toward lower slope.