JWSS - Journal of Water and Soil Science

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Information about forms of zinc (Zn) is important for the evaluation of its status in soil and also understanding of the soil fertility and chemistry. To obtain such information, amounts and distribution of Zn in different fractions of 20 soil samples of Tehran province, Iran were determined by sequential extraction method and their relationships with each other and with soil characteristics were investigated. Total Zn of soils ranged from 70 to 169.9 mg/kg^-1. The amount of different Zn forms relative to the sum of forms was determined to be as follows: organic less than 0.1, soluble+exchangeable 0.1, manganese-oxide-associated 0.9, carbonate 1.6, crystalline iron-oxide-associated 3.8, amorphous iron-oxide-associated 4.2, and residual form 89.3%. Simple correlation coefficients showed that pH had a negative significant correlation with all forms of Zn except organic. Silt and clay contents had significant positive correlations with total, residual, and crystalline iron-oxide-asociated Zn but CEC had significant correlation only with total Zn. Calcium carbonate equivalent showed a significant correlation with soluble+exchangeable, manganese-oxide-associated and amorphous iron-oxide-associated Zn. DTPA-extractable Zn was significantly correlated with soluble+exchangeable, carbonate, and amorphous iron-oxide-associated Zn. A significant correlation was also observed between the Zn forms themselves, which is presumably a reflection of the existence of a dynamic relation between the chemical forms of an element in soil.

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Zn deficiency is one of the most important nutritional disorders after macro-nutrients in rice. There are considerable genotypic differences among rice genotypes in response to Zn deficiency. Determination of such differences and introduction of efficient genotypes could lead to significant reduction of fertilizer use for rice production. In this research, some of the most frequently cultivated rice genotypes in Northern Iran, were compared for their tolerance to Zn deficiency in a field (11 cultivars) and hydroponic (16 cultivars) experiment. Four levels of Zn fertilizer were used in field experiment including 0 (control), 25, 50 and 100 kg ha^-1 and three different activity of Zn in chelator-buffer experiment including 130 (control), 23 and 5 pM. Experiments were conducted using complete randomized block design and data was analyzed using two factorial analysis of variance including Zn level and genotypes. In addition to yield components in the field study and dry matter production in the hydroponic culture medium, concentration of Zn was also determined in shoot, root and seed. The comparison of all yield components showed that the cultivar Onda was the most Zn-inefficient (susceptible to Zn deficiency) and Khazar was the most Zn-efficient (tolerant to Zn deficiency) genotypes under field conditions. In hydroponic experiment, cultivars Fajr, Tarom Hashemi and Onda were determined as the most Zn-inefficient and Shafagh, Amol and Mianeh were recognized as the most Zn-efficient genotypes. The most significant response to Zn fertilizer, in terms of Zn accumulation in seeds, was observed in Nemat and Tarom Deilamani. In contrast, Cadoos accumulated Zn mostly in straw. Results of our experiments introduced not only the genotypes with the highest yield on soils low in available Zn, but also genotypes with the highest Zn accumulation in seeds in response to Zn fertilizers which are important for human nutrition.

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Deforestation has been recognized as one of the biggest environmental problems in the world. It is also one of the main elements of land productivity changes and one of the biggest factors which threaten world's environmental diversity. In this study, based on environmental Kuznets theory, factors which may affect deforestation have been investigated. Results obtained from 71 studied countries show that environmental Kuznets curve was not true for them. Population growth helps the speed of deforestation while higher rate of GDP growth decreases its rate. Institutions which help with the improvement of democracy, individual assets, civil right and political liberty can decrease the pressure on natural recourses and deforestation.

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The objective of this study was to evaluate the possibility of using treated industrial by-products as a zinc (Zn) source and compare their Zn availability and efficiency to ZnSO4. A greenhouse factorial experiment in a completely randomized block design was conducted with corn (Zea mays L.) in triplicates. Treatments included three Zn sources (ZnSO4, IUT-UT in size of < 1 mm and IUT-UT in size of 2-3 mm) at three rates (0, 20 and 40 kg ha-1). The results showed that Zn application both in the form of ZnSO4 and treated industrial by-products significantly (P < 0.05) increased the growth and shoot dry matter yield of corn. Shoot dry matter weight of corn in pots that had received IUTUT was higher compared to those that had received ZnSO4. The highest shoot dry matter weight was produced at the IUT-UT treatment in size of < 1 mm. Increased fertilizer rate significantly (P < 0.05) enhanced shoot and root Zn concentration. However, this increase was higher in ZnSO4 treatment as compared to the IUT-UT treatments. Application of the IUT-UT caused a significant increase in shoot Fe concentration of corn. Shoot and root Cd concentration in all experimental treatments was less than 0.02 mg kg-1. The results showed that IUT-UT can be used as a slow-release Zn fertilizer with low impurity.

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Potato is one of the most important tuberous crops. To achieve optimum yield in potato, suitable brand and sufficient and balanced soil nutrients are necessary. In order to study the effects of Zinc, Manganese and Copper on potato yield and leaf and tuber concentrations of Phosphorus and Iron, a factorial pot experiment with 32 treatments was conducted in greenhouse of Soil Science Department, Zanjan University, using a completely randomized design and three replications. The study factors were four levels of Zinc(Zn0: 1.14, Zn1: 5, Zn2: 10 and Zn3: 15 mg/kg soil), four levels of Manganese(Mn0: 1.4, Mn1: 5, Mn3: 10 and Mn4: 20 mg/kg soil) and two levels of Copper (Cu0: 0.22 and Cu1: 2 mg/kg soil) which were applied to the soils of planting pots. The results showed that potato yield increased as the soil concentrations of Zinc, Manganese and copper increased to certain levels Soil application of zinc and manganese fertilizers significantly decreased leaf and tuber concentrations of Phosphorus and Iron. Soil application of copper decreased Iron concentration of leaf but not Phosphorus. The highest potato yield was obtained from the treatment of 15, 10 and 2 mg zinc, manganese and copper per kg of soil, respectively.

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The task of modern agriculture is to safeguard the production of high quality food, in a sustainable natural environment under the precondition of pollution not exceeding accepted norms. The sustainability of current land use in agro-ecosystems can be assessed with respect to heavy metal accumulation in soils by balancing the input/ output fluxes. The objectives of this study were to model accumulation rate and the associated uncertainty of Zn in the agro-ecosystems of 3 arid and semi-arid provinces (Fars, Isfahan and Qom). Zinc accumulation rates in the agro-ecosystems were computed using a stochastic mass flux assessment (MFA) model with using Latin Hypercube sampling in combination with Monte-Carlo simulation procedures. Agricultural information including crop types, crop area and yield, kind and number of livestock, application rates of mineral fertilizers, compost and sewage sludge and also metal concentration in plants and soil amendments were used to quantify Zn fluxes and Zn accumulation rates. The results indicated that Zn accumulates considerably in agricultural lands of the studied townships especially in Najafabad (3009 g ha-1yr-1). The major Zn input routes to the agricultural soils (and due to agricultural activities) were manure and mineral fertilizers and the major part of the uncertainty in the Zn accumulation rate resulted from manure source.

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Zinc (Zn) is an essential trace element for plants as well as for animals and humans. There is a significant relationship between soils, plants and humans Zn status in a certain agro-ecosystem. The objectives of this study were to assess Zn status of soils in 3 arid and semiarid provinces of Iran and to model the relationship between wheat grain Zn and agro-ecosystem parameters. About 137 soil and wheat samples were collected randomly from the agricultural soils of Fars, Isfahan and Qom and were analysed in laboratory. Modeling the relationship between wheat grain Zn and agro-ecosystem parameters was done using least square based and robust methods. The results indicated that total Zn concentration of soils (range, 21-149 mg kg-1 mean, 75.2 mg kg-1) was in normal ranges. The DTPA-extractable Zn concentrations were below the critical level (0.8 mg kg-1) in 16% of the surveyed fields. The Zn concentration in 80% of wheat grains was sufficient (more than 24 mg kg-1) with respect to plant nutrition (range, 11.7-64 mg kg-1 mean, 31.6 mg kg-1). However, Zn bioavailability for consumers was generally low in more than 75% of the samples. This is because of high phytic acid to Zn molar ratio (more than 15). Soil DTPA-extractable Zn and available P were entered in to most of regression models significantly. Regression analysis showed that most of models fitted to wheat grain Zn concentration and soil Zn and influenced by agro-ecosystem parameters had a weak prediction power, despite their high determination coefficient. This means that factors other than those considered here have a strong influence on the uptake of Zn by wheat in these soils.

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Limited information is available about the effect of preceding crop residues on bioavailability of zinc (Zn) in calcareous soil and its accumulation in wheat grain. In this experiment, residues of five crops including safflower (Carthamus tinctorius L.), sunflower (Helianthus annuus L.), bean (Phaseolus vulgaris L.), clover (Trifolium pretense L.) and sorghum (Sorghum bicolor L.) were incorporated into a calcareous Zn-deficient (0.5 mg kg-1) soil. A treatment without crop residue was also used in the experiment. This experiment was conducted in research greenhouse of Isfahan university of technology in 2010. Two wheat cultivars (Triticum aestivum cvs. Backcross and Kavir) differing in Zn-efficiency were studied in the experiment. Incorporating crop residues into the soil resulted in an increase of grain Zn concentration in both wheat cultivars although this increase was dependent on the preceding crop type. The greatest increase of grain Zn concentration occurred in the sorghum residues treatments. Although application of crop residues significantly decreased grain phytic acid to Zn molar ratio (as Zn bioavailability criteria for consumers), this ratio was still higher than 15, the critical Zn bioavailability level for consumers in foods. According to the results, despite the increase in the total Zn content, the bioavailability of Zn in wheat grain was not affected by crop residue treatments.

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Heavy metals contamination of soil and plants has very important and vital role in relation to health and life of human and other organisms. The aim of this study was to assess the efficiency of sorghum (Sorghum bicolor) and sommon lambsquarter (Chenopodium album) in phytoremediation of Zn from soil. Efficiency of 0.01M CaCl2, 0.1M NaNO3, and 1M NH4NO3 for extraction of “bioavailable fraction of soil Zn was also compared. Correlation between the Zn concentrations extracted by these methods and plants response (relative yield and shoot Zn concentration) to soil Zn contamination was then evaluated. For this purpose, a calcareous soil sample was contaminated with different concentrations of Zn. Sorghum and common lambsquarter, were grown in pots containing the contaminated soil and were analysed for their Zn concentrations after harvest. Results of this study showed that, common lambsquarter was more tolerant to low and medium concentrations (≤900 mg/kg), but sorghum tolerated high concentration of Zn. Also sorghum was more capable in removal of Zn from soil in comparison to common lambsquarter, so that soils contaminated with low Zn levels (≤900 mg/kg) can be remediated by sorghum. In addition, there was a significant correlation between 1 M NH4NO3-extractable soil Zn and the plants response (relative yield and shoot Zn concentration) to soil Zn contamination.

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Shahrekord groundwater is the main source of water for drinking, and the agricultural and industrial activities of its inhabitants. Water quality measures of scaling and corrosion can deteriorate steel-based systems used for storage or supplying water for drinking and to industry and irrigation. The main aim of this study was to assess the spatial variability and mapping of scaling and corrosion using Langelier index (LI) and Ryznar index (RI) and that of the related parameters of pH, total dissolved solids (TDS), total hardness (TH), and total alkalinity (TA) in Shahrekord groundwater. For this purpose, water samples from 97 wells were analyzed for pH, TDS, TH, and TA and LI and RI indices were calculated. The Gaussian model best described the spatial variability of TDS while the Spherical model was best for all other parameters. Based on LI and RI averages of, -0.13 and 7.9 respectively, Shahrekord groundwater has a slight potential for corrosion. The values of all parameters, except RI, were lowest in the northwest and highest in the southeast of the aquifer. In most parts and in the center of the aquifer, the values of LI ranged from -0.5 to zero indicating negligible scaling potential. Spatial distribution of the RI index was almost inversely symmetrical to that of LI index. LI showed strong positive correlations with its components (varying from 0.61 to 0.90) while RI had strong negative correlations with its components (ranging from -0.66 to -0.98). LI and RI had the strongest correlations, respectively, with pH (r=0.90) and total alkalinity (r=-0.90).

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Zinc (Zn) is one of the essential micronutrients for plant growth and its deficiency frequently occurs in calcareous soils. But, a suitable extractant for estimation of plant-available Zn in calcareous soils, amended with sewage sludge, has not been presented yet. The aim of this research was to assess several chemical extractants (7 extractants) for estimation of available Zn in calcareous soils amended (1% w/w) and unamended with sewage sludge. Results showed that Mehlich 3 and Mehlich 1 extractants extracted the highest and the lowest concentrations of Zn in both amended and unamended soils, respectively. All wheat indices (wheat yield, Zn concentration and Zn uptake) increased by sewage sludge addition. Besides, the results indicated that in unamended soils, significant correlations were found (r=0.65^*- 0.91^**) between extracted Zn using AB-DTPA, DTPA-TEA and Mehlich 3 extractants and different wheat indices. On the contrary, in sewage sludge-amended soils, only the correlation between extracted Zn using Mehlich 2 and Zn concentration was significant (r=0.83^**). According to this study findings, the suitable extractant for extracting wheat-available Zn is thoroughly different in calcareous soils amended and unamended with sewage sludge.

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