JWSS - Journal of Water and Soil Science

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The calcification of soils and the effects of topography on this process were studied in semi-arid regions of Kermanshah. From a toposequence, based on the previous soil surveys of the region, five profiles were selected, and field studies and laboratory analyses were carried out on soils. Alluvial - colluvial fans, piedmont alluvial plains, and old plateaux were three main physiographies on the selected toposequence. Soil moisture and temperature regimes were Xeric and Thermic, respectively. The results indicate that redistribution of carbonates and soil formation processes may be categorized in four specific stages to be described in the text. Accumulation of calcium carbonates in soil profiles showed two basic forms: one in sandy layers of fine - textured soil profiles under the influence of abrupt textural changes and lower permeability, and the second in subsurface horizons of soils with calcareous parent material. The morphological evidences showed that in addition to translocation from upper horizons of carbonates by solution and suspension, physical movements to subsurface layers of fine calcareous materials have also affected the formation of calcic horizons. In other words, CaCO3 may have moved as fine particles through soil cracks and subsequently accumulated in the lower horizons. Soil mineralogy showed considerable amounts of illite, Chlorite, smectite and palygorskite clay minerals. Some pedogenic transformations of illite and chlorite may have caused formation of smectite and palygorskite.

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The main sources of cadmium in soil-plant continuum in amounts that might present a hazard are liquid and solid wastes of sewage sludge, farm manures and fertilizers. In the southwest of Iran (Khuzestan Province) over 50,000 ha of land is under sugarcane (Saccarum officinarum) cultivation and more than 80,000 ha will be under sugarcane by the end of the year 2000. In these sugarcane fields, about 400 kg ha^-1 diamonium phosphate (DAP) and 400 kg ha^-1 urea are applied annually. There is no data available to show the fertilizers impact on soil, water and plant contaminations in Iran with respect to cadmium. The objective of this research was to compare the extractable cadmium of virgin soils with that of soils under sugarcane.

 Four sugarcane growing stations viz. Haft-tapeh, Karoon, Shoeibieh and Ghazali with cultivation histories of 36, 20, 2 and 1 year, respectively, were selected. In each site, along a transect soil samples from 0-30 cm of both furrows and ridges of cultivated soils and of virgin soils were collected. Electrical conductivity (EC), pH, clay and organic carbon contents, CI and Cd of 101 soil samples were measured according to standard methods. Results showed that increasing either EC or CI increased Cd concentration with its maximum in virgin soils and its minimum in furrows.

 Results also indicated a slight decrease in the Cd content of cultivated soils.

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Potassium fixation and release by phillosilicate clay minerals in soils are very important processes influencing the availability of K to plants. This investigation was conducted to determine the potassium fixation capacity and charge characteristics of soil clays of 15 surface soils (0-30 cm) from central and northern Iran. After clay particle separation, both total and tetrahedral cation exchange capacity of soil clays were determined. Tetrahedral CEC was measured after saturation with Li and heating at 300 C to reduce octahedral charge to near zero. Potassium fixation was obtained in both wet (1:10 soil:solution, 16 h on a shaker) and dry conditions (after drying for 24 h at 70°C) using three different levels of added K

The total CEC in soil clays of Isfahan, Char-Mahal and Gilan provinces ranged from 22.1-36.0, 33.0-55.8 and 31.3-47.9 cmol kg^-1, respectively. Tetrahedral CEC in soil clays of Isfahan, Char-Mahal and Gilan provinces ranged from 17.9-4504, 26.2-32.5 and 8.3-23.8 cmol kg^-1, respectively, which consisted of 81.0-98.4, 58.5-95.8 and 24.7-72.5% of their total charge, respectively. The amount of K fixation increased with drying and the level of k added. Mean potassium fixation in soil clays of Isfahan, Char-Mahal and Gilan ranged from 5.42-9.13, 6.63-14.67 and 8.87-10.36, respectively. Mean potassium fixation by soil clays (except for soil clays of Gilan) best correlated with total CEC. In the soil clays of Isfahan, mean potassium fixation correlated with tetrahedral CEC, whereas no correlation was observed in soil clays from other places. The average amount of potassium fixation in clay fractions was in the order: Gilan clays > Char-Mahal clays > Isfahan clays.

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Soil organic matter and clay minerals adsorb and immobilize extracellular enzymes of microorganisms and increase soil enzymes stability. This study aims to clarify the relative importance of soil organic matter and clay minerals on the cellulolytic activities of soils. Fluca prepared cellulase was immobilized on some agricultural residues and clay minerals, avicel and a sample of soil. Immobilized exoglucanase and endoglucanase were assayed at different times. Activities of the immobilized enzymes were strikingly dependent on the kind of sorbent. After 20 days of storing in refrigerator at 4^oC, the deactivation of immobilized enzymes on the organic substances (as avicel) was very low but deactivation of immobilized enzymes on the soil and clay minerals was relatively high. On the other hand, the activities of immobilized enzymes on the agricultural residues and avicel were significantly higher than the soil and clay minerals. So it may be concluded that a large part of cellulolytic activity of soil is related to immobilized enzymes on agricultural residues. Coating of the clay minerals, soil and avicel with 4 mmol of Al (OH) x per mg of them significantly increased their immobilization capacity and activities of immobilized enzymes. Activities of immobilized exoglucanase and endoglucanase on the Ca- homoionized soil and clay minerals were significantly higher than the K- homoionized soil and clay minerals. However, these effects may be related to the specific effects of cations on the method of enzyme assay or enzymes activities. These homoionizing-cations effects on the activity of immobilized enzymes on avicel were not significant.

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Clay minerals have considerable effects on physico-chemical properties of soils. Using different techniques, mineralogy of silicate clays and their formation were investigated in selected soils from Chaharmahal and Bakhtiari Province. The study area is about 1300 ha and its soil moisture and temperature regimes are xeric and mesic, respectively. Geomorphologically, the area consists of different landforms including pediments, outwash, hills and piedmont plain. After field and laboratory studies, five representative pedons were selected in previously determined mapping units and samples were taken for the analyses required. Clay particles from two surrounding rock formations and selected soil samples were separated and examined by electron microscopy (SEM and TEM), X-ray diffraction and infrared techniques. Illite, smectite, chlorite, palygorskite and kaolinite were present in all the soils. Considering the fact that palygorskite was not observed in nearby rock formations, this mineral is probably formed by pedogenic processes. Smectite, on the other hand, has been inherited from parent materials and also transformed from palygorskite. Other minerals had been probably inherited from parent materials. Infrared spectra confirm the X-ray diffraction and submicroscopic results.

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Environmental pollution is one of the major problems for humans and animals. Radioactive wastes and heavy metals are important sources of pollution. Recent studies suggest that soil and geomedia have a high potential for the disposal of radioactive wastes and heavy metals. The clay minerals in geomedia can act as a barrier against radioactive wastes and heavy metals. However, enough information and experimental evidence about the mechanisms involved in the fixation of metals by clays are not available. This study aimed to show the effect of clay type on the fixation of cobalt and cadmium as affected by thermal energy. Increasing the temperature from 25 to 400°C decreased the CEC of clays in Ahwaz and Darab soils saturated with cobalt from 35.6 and 50.1 cmol_c+/kg to 28.8 and 4.5, respectively. In cadmium clays, however, reductions in CEC were minimal (from 34.3 and 51.2 at 25°C to 32.5 and 47.7 cmol_c+/kg at 400°C, respectively) compared to cobalt saturated clays. Consequently, the bonding characteristics change according to the size of the cations upon thermal treatment. The small cation, cobalt with an ionic radius of 0.68 Å, apparently migrates to the octahedral vacant sites and forms covalent bonds after heating at 400°C to become non-exchangable (fixed). The larger cation, Cd with an ionic radius of 0.97Å, apparently does not migrate into lattice sites on thermal treatment and remains exchangeable.

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Clay minerals deserve special attention as they play a crucial role in many soils. The clay mineralogy of five gypsiferous soils from different landforms in eastern Isfahan was investigated using X-ray diffraction (XRD). In addition, soil aggregates and wind-deposited sediments were examined by scanning electron microscope (SEM) and analyzed by energy dispersive X-ray analyzer (EDX). The results indicate the presence of palygorskite, mica, kaolinite, chlorite, and quartz with a trace amount of vermiculite and randomly interstratified layers in all soils. Smectite occurs in soils of both the piedmont plain and old river terrace, but not in the alluvial fan soils. Mica, chlorite, quartz, and kaolinite were probably inherited from the parent material. Palygorskite seems to increase with depth in the alluvial fan, whereas, in the old terrace soils, this clay mineral decreases with depth. Palygorskite present in alluvial fan soil appears to have been formed authigenically when the basin was covered with shallow hyper-saline lagoons toward the end of the Tertiary. Palygorskite in the old terrace seems to be mostly detrital and an eolian origin of palygorskite is likely because a large amount of palygorskite is present in upper soil horizons. A higher proportion of smectite in deep soils of the old terrace, as compared with palygorskite, suggests the possibility of authigenic formation of smectite from palygorskite. .

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Aggregation is an important temporal property of soil structure that is affected by intrinsic soil properties and also soil use and management. Aggregate stability has a strong influence on many processes in soil such as infiltration, aeration, strength, erosion, and soil’s ability to transmit liquids, solutes, gases, and heat. In this study, undisturbed soil specimens from 0-10 and 10-20 cm depths were sampled during summer 1999 from some regions in Iran including Golestan, Kermanshah, West Azerbaijan, and Mazendaran. After drying the samples in lab, the different sizes of aggregates were separated and the wet aggregate stability (WAS) and dispersible clay (DC) were determined on 2-2.8 mm aggregates according to Pojasok & Kay procedure (1990). The variance analysis of data showed significant differences among soils in all regions. The averages were compared by Duncan test to find the following order: Mazendaran > Golestan > Kermanshah > West Azerbaijan. Regression analysis of data of whole regions showed that the variability of aggregate stability was mainly explained by organic carbon content (R²=0.723 in P > 0.0001). The clay content had the greatest effect on aggregate stability in samples from Golestan while sand content had the greatest effect in samples from West Azerbaijan. The resulting equations from stepwise regression can be used to estimate aggregate stability from other soil variables in the study regions.

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Stabilizng sand dunes has been one of the main challenges in the arid regions. So far, different kinds of mulches have been used extensively for sand dune stabilization. This study was carried out to determine the optimum composition, concentration and thickness of clay mulch for sand dune stabilization. For this purpose two soil samples from clay flats of a playa with different amount of salinity from Ardestan area were used to make clay mulches. A sand dune sample was selected as bed for applying the mulch. To select the right ingredient and treatments, clay samples were mixed with sand and different amount of water, and sprayed on sand dune bed. In addition, wheat straw was added to some mixture to test its effect on stability of the mulch. Treatments with lowest crack and highest penetration of mulch in sand bed were selected for the experiment in this study. Mulch treatments contained (1): 250g sand dune + 250g clay + 25g straw (2) 250g clay + 25g straw (3) 250g sand + 250g clay (4) 250g clay (5) 125g sand + 125g clay and (6) 125g clay. All treatments were mixed with 500ml water. The experimental design was a CRD with a 6(mulch) * 2(thickness)* 2 EC factorial method with 3 replications. The results showed that clay mulch were resistant to wind erosion, but erosion took place when they had been bombarded with sandblast. The mulches with straw showed the highest resistance to erosion as compared to other treatments. With increasing the number of mulch layers, resistant to erosion also increased. The added stability of mulch was due to the increase in mulch thickness and also increases in clay and silt content. The overall result of this study shows that the mulch with two layers and higher mixture of clay and sands was the best treatment for the stabilization of sand dunes.

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Sugarcane (Saccharum officinarum L.)‌ and rotational crops have been cultivated without potassium fertilizers for many years in southwestern Iran. Although potassium was removed from this soil, no response has been reported to K fertilizers by crops. This study was conducted to evaluate the effects of wetting and drying, and cultivation systems on potassium fixation in some Khouzestan soils. The results showed that expandable clay mineral was observed in cultivated soils but not in the non-cultivated soils. This may be related to irrigation, and cultivation practices in this soils. By adding K and sequential wetting and drying the amount of K-available increased in sugarcane, rotational cropping and uncultivated soils from 132.6, 226.2 and, 171.6 mgkg^-1 to 266, 447 and 628, respectively. These results showed that more K can be fixed after cultivating soils, especially by sugarcane, but available K increased by adding K. All surface soils had higher K fixation capacity than subsurface ones. Also, by application K to these soils, the amount of K fixation decreased with increasing wetting and drying times. The K fixation increased by the increase of cation exchangeable capacity. Significant difference was observed between cultivation system and depth of sampling in 1% levels. High K fixation can be attributed to illite minerals depleted from K. Mica-like minerals formed after adding K, and wetting and drying cycles. Amount of K fixation by clay particle samples was more than the same soil samples but in both the same trend was observed for K fixation. Also, drying and wetting decreased K fixation in the last periods. It may be due to trapping K in the interlayer positions.

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  This research was carried out to study the impacts of geomorphologic characteristics of claypan on land use and land degradation. Databank of the study area was constructed and digital terrain model of claypan was prepared. By using GIS techniques spatial distributions of the subsurface drainage network, sediment transportation index and wetness index were calculated. The results indicate that the depth to the claypan is between 0 (where the pan is exposed at the surface) to 605 cm. There are several depressions in the claypan which are filled by new sediments. Each depression has a catchment which is charged by the drainage water of its attributed lands. While a depression drains naturally or synthetically, the attributed soils over the depression are in non saline or moderate salinity condition otherwise, a marshland, a waterlogging area or a salt crust zone develops over there. The results also indicated that soil surface salinity is a function of depth to claypan and drainage condition of area. The trends of salinity extension are different for closed and open catchments and the depth to the claypan could be estimated using electrical conductivity. The results also show that analysis of microtopography of soil surface and soil stratification should be considered for designing irrigation and drainage networks.

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Mineralogy is one of the most influential soil properties that change from upper- to lower slope positions, depending on the climate differences. Such changes affect soil properties such as phosphorus sorption and desorption processes differently. Therefore, this study was carried out to investigate the clay mineralogy of soils in four toposequences from arid (Isfahan) and semiarid (Chaharmahal Bakhtiari) regions and its effect on soil P release. The soils of three points on each toposequence were sampled as the upper-slope mainly containing parent materials the mid-slope, non-arable lands and the lower-slope, arable lands. Some of soil properties such as clay minerals were determined. Also, trend of P release parameters was studied in four toposequences. Results showed that the amount of clay, cation exchange capacity (CEC), electrical conductivity (EC), and pH of the soils increase down the slope in all toposequences. X-ray diffractograms showed that kaolinite and illite in upper slope and smectite and chlorite in lower slope were the predominant clays. Among the kinetic models examined based on their determination coefficient and standard error, the Elovich equation was chosen to describe the P release kinetics in studied soils. The trend of P desorption rate along the arid toposequences was in the following order: upper-slope < mid-slope < lower-slope. Furthermore, the rate of P desorption in soils of the semiarid toposequences was higher than arid toposequences. Regarding the trend of P rate parameters along the toposequences, it could be concluded that P release rate and the soil capacity to supply P for plants increase toward lower slope.

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Fire is widely used to clear farms in Iran, while there is little information regarding the effects of fire on the characteristics, especially mineralogy of soils. The objectives of the present study were to 1) compare some physico-chemical properties of burned and unburned soils and 2) evaluate minerals transformation in top soil layer resulting from increasing temperature. Soil samples were taken from 0-5 and 5-15 cm depths of two burned places, an agricultural soil from Takht-e-Jamshid area and Bamoo forest, in four replications. Physico-chemical analyses were carried out on burned and unburned samples. X-ray diffraction technique was used to identify minerals of clay fraction in 0-5 cm depth burned and unburned soil, and also to compare transformation of minerals (if any) after heating at 300˚C and 600˚C for 2, 4, 8 and 12 h. Burning increased soil pH and sand sized fraction in 0-5 cm, and P and K in both depths of Bamoo forest. Changes in soil properties of agricultural filed were negligible. XRD analyses showed the reduction in the intensity peaks of chlorite and illite after burning. Lower relative quantity of chlorite and illite was observed in various times of 300˚C treatment in comparison to control, while they were not observed in 8 and 12 h of 600˚C. No change was observed in the peak of quartz in forest and field soils after burning and after various heat treatments.

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Application of compost and compost leachate as organic fertilizers can improve plant growth, nutrients uptake and increase phytoavailability of nutrients in soil. A factorial experiment (4×4×2) was conducted in a completely randomized design to evaluate the effect of compost and compost leachate on growth and chemical composition of barley and bioavailability of some nutrients in calcareous clay loam soil and sandy soil under greenhouse conditions. Treatments consisted of four levels of compost (0, 15, 30, and 60 g kg-1), four levels of compost leachate (0, 10, 20, and 40 g kg-1), and two culture mediums (clay loam soil and sandy soil) with three replicates. Results indicated that application of compost and compost leachate significantly increased barley shoot dry matter, the number of tillers, spikes and grain yield in clay loam soil and sandy soil. The maximum barley shoots dry matter and numbers of tillers in both culture mediums were obtained at the highest level of compost or compost leachate, and the maximum number of spikes and grain yield were obtained at the lowest level of compost or compost leachate. Application of compost in clay loam soil and sandy soil increased shoot and root concentrations of nitrogen (N), phosphorus (P), Iron (Fe), manganese (Mn), zinc (Zn) and copper (Cu). However, addition of compost leachate only increased shoot concentrations of Fe and P. Increasing compost levels increased post harvest concentrations of NO3- N, P, Fe, Mn, Zn, Cu and also electrical conductivity and organic matter content of clay loam soil and sandy soil. Addition of compost leachate significantly increased concentrations of Fe, Zn, Cu and also electrical conductivity and organic matter content of both culture mediums. In both culture mediums and both compost and compost leachate treatments, post harvest concentrations of micronutrients were above critical levels. Therefore, addition of these nutrients is not required for the next cultivation. Generally, compost and compost leachate are appropriate organic fertilizers for barley production however, high salinity level in compost leachate, the rate and frequency of leachate application, particularly in sand, needs intensive control and monitoring. Prior to any fertilizer recommendation, the results of this study need to be verified under field conditions, as well.

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Paleosols provide invaluable data on paleoclimatic conditions of the area. These soils widely exist in central Iran. Micromorphology and clay mineralogy are among valuable techniques which are useful for interpretation and identification of these soils. The present research was performed to compare the micromorphology and clay mineralogy of paleosols and modern soils of Jiroft area. After field studies, 4 pedons (located on different geomorphic surfaces including stable mantled pediment, stable and unstable transitional surfaces of pediment and alluvial plain, and stable surface of alluvial plain) were sampled for physicochemical, micromorphological, and clay mineralogical analyses. Clay coatings in argillic horizons of paleosols were found during micromorphology observations. On the other hand, clay coatings in present soils were only found in natric horizons, which were attributed to high amounts of Na in these soils. Moreover, smectite, palygorskite, illite, chlorite, and kaolinite clay minerals were recognized in paleosols, but chlorite was not detected in modern soils. The presence of palygorskite in the soils under study was related to the stability of geomorphic surface. Results of the present research showed that a more humid climate was present at the time of paleosols formation.

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Internal erosion is the second major reason for earth dam's failure after overtopping. One of the effective factors in internal erosion in earth dams is the clay minerals used in dams as well as the effects of compaction efforts on soil in sample preparation. In this research, internal erosion and the effect of clay minerals and compaction effort on internal erosion were investigated. For this purpose, Kaolin clay and Na Montmorillonite (Bentonite) separately and with different percentages of mixture were used to investigate the effect of different percentages of Bentonite on internal erosion. Two hammers of standard compaction and modified compaction test were also used to investigate different compaction efforts in internal erosion. The results showed that as compaction effort increased in constant water content, erodibility also increased to about 3%. In addition, it is found that erodibility of kaolin clay is more than bentonite, which reaches 65%. Finally, by adding 12% bentonite to kaolinite, erodibility decreased to a great extent.

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Studies on the soils of western Golestan province show that regardless of increased rain and presence of clay minerals with high cation exchange capacity, potassium extractable with ammonium acetate is low. In order to find the reason for this low amount of available K, clay minerals and micromorphology of the soil porosity were studied. Twenty disturbed and undisturbed samples from each horizon were taken for physicochemical properties, mineralogy and micromorphological studies. Four selected profiles included Gypsic Aquisalids, Typic Endoaquepts, Typic Calcixerolls and Typic Hapludalfs. The results showed that in addition to the clay content and type of clay minerals in soils that can affect soil available K (Kava.), it seems soil porosity can also affect Kava. mainly through their effects on extension of roots, water and nutrients transmission. Favorable content of clay and dominance of smectites in Mollisols and also higher porosity and dominance of channel porosities caused the presence of higher Kava, in these soils. presence of HIS. poor soil drainage, reduction of Fe3+ in smectite crystal lattice in Inceptisols, and also less amount of porosities caused the presence of higher potassium fixation and reduction of Kava. in these soils.

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Urease is one of the most important enzymes in nitrogen cycle. The clay particles (with high surface area) play an important role in the stability of these protein compounds (enzymes) against various environmental factors. In order to examine the interactions between urease with sepiolite and vermiculite, three in vitro experiments were conducted separately in a completely randomized design. Two experiments were carried out with two replications. Treatments included six incubation times (0, 1, 2, 5, 10 and 20 days) and five levels of temperature (10, 20, 30, 40 and 50 ˚C). The third experiment was carried out in a factorial arrangement with two replications. Factors included three levels of pH (5, 7 and 9), and six-levels of enzyme concentrations (0.05, 0.25, 1, 5, 15 and 30 units). The results showed that the activity of adsorbed enzyme was more than free enzyme during the incubation time. The optimum temperatures for activity of free and adsorbed enzymes were 30 and 50 ˚C, respectively. It was concluded that enzyme adsorption on clay surfaces increases enzyme stability against environmental changes. Also, the results showed that the highest levels of urease adsorption on sepiolite and vermiculite occurred at pH 9 and 7, respectively. Adsorption isotherms of Enzyme showed that Vermiculite adsorbed urease with higher affinity compared to Sepiolite.

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Paddy soils provide the staple diet for nearly half of the world's population. The formation of the Anthrosols is induced by tilling the wet soil (puddling), flooding and drainage regimes associated with the development of a plow pan and specific redoximorphic features. The aim of this study was to evaluate the effects of long-term rice cultivation on physico-chemical properties and clay mineralogy of soils of three rice farms and compare the results with adjacent virgin lands in Yasouj region. Paddy soils exhibited larger contents of clay, organic carbon, saturation percentage, cation exchangeable capacity, cation exchange activity classes, electrical conductivity and lower content of calcium carbonate equivalent compared to non-paddy soils. This land use showed higher proportions of Feo, Fet and lower content of Fed. No such differences were noticed with the type of clay minerals in both land uses. Paddy soils contained greater amount of smectite, particularly in the surface horizons. Smectite in paddy soils exhibited lower layer charge and higher degree of crystallinity compared to non-paddy soils. Transformation of illite and chlorite to expandable minerals is a possible mechanism for lower amounts of these minerals in paddy soils.

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Stabilizing heavy metals in polluted soils is a method to prevent them from entering plants. Clay minerals are considered good sorbents for heavy metals due to their low cost, high abundance, easy manipulation and harmlessness to the environment. The objective of this study was to investigate the potential of clay deposits containing smectites and palygorskite to sorb cadmium and to reduce its movement into canola. Two selected deposits are located in the Isfahan Province. Physical and chemical characteristics of clay deposits were determined. The clay fraction was then separated from each deposit sample. This study showed that palygorskite was the dominant clay mineral in deposit sample 1 and smectites in deposit sample 2. These clays were then used as an amendment to plant growth medium. Pot experiment was carried out with canola (Brassica napus) as a test plant with 3 replicates. Treatments included three growth media: smectite + quartz sand, palygorskite + quartz sand and pure quartz sand (control treatment) under 3 Cd concentrations: 0, 2.5 and 7.5 ppm. Results obtained from the pot experiment indicated that deposits containing smectite and palygorskite were very useful in stabilizing cadmium in polluted soils and could prevent Cd from entering plant. Smectite clay mineral could retain a higher quantity of cadmium as compared to palygorskite. Plants in pots amended with smectite had a higher growth rate as compared to those in control and palygorskite amended pots. Cadmium accumulation in plant roots was much higher than that in shoot. Furthermore, the higher Cd concentration in growth media resulted in the higher amount of Cd uptake by the plant.