A. Abbaspour, M. Kalbasi, H. Shariatmadari,
Volume 8, Issue 1 (4-2004)
Abstract
The possibility of using a steel plant by-product (converter sludge) as an iron fertilizer was investigated. This compound consists of 64% Fe oxides. Considerable amounts of elements such as Ca, Si, Mn, P, and K are also present in the sludge. To study the converter sludge, an incubation experiment was carried out on three calcareous soils. Treatments were 0, 4, and 8 percent of converter sludge mixed with soils plus mixtures of 4% converter sludge with elemental sulfur, thiobacillus inoculum and sulfuric acid. Soil samples (400 g) were kept at field capacity and room temperature in capped, aerated plastic containers for two months. Sub-samples were taken at 1, 10, 30, and 60 days of incubation and analyzed for Fe, Mn, Zn, P, and K contents as well as EC and pH.
Results showed that converter sludge increased significantly extractable Fe proportional to the rate of sludge used. Sulfuric acid application increased Fe availability significantly, but the availability of this nutrient generally decreased with the incubation time. Application of the sludge also increased the pH slightly at the beginning of incubation. Elemental sulfur and sulfuric acid application increased Fe and Mn availability significantly. Application of the sludge without and with elemental sulfur and sulfuric acid slightly increased availability of P. The results of this study revealed that converter sludge might be used as an iron fertilizer. However, further investigation in greenhouse and field experiments is needed.
A. R. Melali, H. Shariatmadari,
Volume 11, Issue 42 (1-2008)
Abstract
Application of slag and converter sludge, major by-products of Esfahan Zob Ahan factory, to enrich two organic amendments for corn nutrition, was investigated. Farm manure and its vermicompost mixed with different rates of slag and sludge were incubated in 3 Kg pots at field capacity moisture and home temperature for three months. The applied rates of slag and sludge were 0, 5 and 10 percent (w/w) of pure iron from these compounds to the organic amendments. Iron sulfate with the above ratios was also examined for comparison. Sub-samples of the incubated materials were taken after 0, 10, 25, 45, 65 and 90 days of incubation and examined for DTPA extractable Fe, Mn, Zn and Cu. After the incubation, the enriched amendments were applied to a soil sample to grow corn. Three Kg soil samples, taken from Chah Anari experimental farm, Esfahan University of Technology, were mixed with 17 gr of the amendments (50 ton/ha) placed in 3 Kg pots. In each pot two corn seeds (single cross 704) were planted and after 70 days crop yield and concentration of Fe, Mn, Zn, Cu in the plant tissues were determined. Results showed that the use of iron sulfate strongly increased DTPA extractable Fe and Mn of the amendments. In enrichment by converter sludge, the best result was obtained in the mixture of 10 percent pure iron with the vermicompost on 60 days of incubation. Treatment of 5 percent pure iron from slag mixed with the manure increased DTPA extractable Fe and Mn with the time, but the 10 percent treatment was not much effective in this regard. The highest rates of iron uptake by the plants occurred in the iron sulfate and 10 percent converter sludge treatments, respectively however, the highest rate of the plant Mn uptake was observed in 5 percent iron from converter sludge mixed with vermicompost. In general, 10 percent pure iron from converter sludge was the most effective enrichment treatment, increasing the plant uptake of Fe, Mn, Zn and Cu micronutrients.
H Shariatmadari, Y Rezainejad, A Abdi, A Mahmoudabadi, M Karami,
Volume 12, Issue 46 (1-2009)
Abstract
Many researchers have reported positive effects of converter sludge and slag, two by-products in Isfahan iron melting factory. In this work, the optimum rate of application and the availability of some essential elements (for plant growth) in the converter sludge and slag for corn were investigated. The converter sludge contains about 64% Fe ІІ and ІІІ oxides and some other essential elements for plant growth. The slag also contains 17% iron oxides, 52.8% calcium oxide as well as considerable amounts of some other elements. Treatments included a control, Fe-EDTA foliar spray with 5 in 1000 concentration, application of sludge in 4 levels (L1, L2, L3 and L4 equal to 5.83, 13.33, 20.83 and 26.67 ton/ha, respectively) and application of slag in 4 levels (S1, S2, S3 and S4 equal to 3.20, 7.28, 11.36 and 15.44 ton/ha, respectively) which supply 1, 2, 3 and 4 times as much as soil test recommends, based on AB-DTPA extractable Fe in the soil. Corn (Zea mays) single cross 704 was planted for the experiment. Applications of the two compounds increased the soil extractable Fe and Mn, decreased Mg but the treatment did not change the soil-extractable Zn, Cu and Ca. The corn yield also increased due to the applications of the two compounds and the maximum yield was related to L3, L4, S3 and S4 treatments. The foliar application treated the leaf chlorosis and increased the silage, grain and leaf + stalk yields however, this was not as efficient as sludge and slag application. Also applications of the two compounds increased the Fe, Mn, Zn, Cu, Ca and Mg uptake by corn. The L3 and S3 treatments can be recommended as the proper levels of these compounds as iron fertilizer.
