During recent years, worldwide concern has been focused on the potential for contamination of surface waters and ground waters by agrochemicals in runoff and soil water from irrigated fields. Given this perspective, it is very important to correctly evaluate the levels of different agrochemicals in water, both from human toxicological and environmental viewpoints and to develop management strategies for reducing agrochemical loads to acceptable levels in the environment. The main objective of this study was to assess the qualitative changes of tailwater due to the use of agrochemicals and thereby to determine contamination loads. Four farms (A, B, C and D) were chosen in the Foumanat region in the F2 unit in 1996. The areas of these fields ranged from 0.22 to 0.6 ha having a number of unequal successive basins with variable inflow and outflow rates.
A quantitative analysis showed that the tailwater ratio in farms A, B, C and D ranged from 2 to 64% during the irrigation season. The outflow water was classified as C3S1. The changes in qualitative factors were not significant and did not follow any certain pattern during the irrigation season. The changes in SAR, EC, Cu, Zn, B, P, K and DO in the inflow and outflow waters were also insignificant. After fertilizer application, the increase in nitrogen concentration in the outflow was significant. The average pollution loads in the inflow and outflow were about 1618 and 1476 kg/day/ha, respectively. The remaining load in the rice fields was about 142 kg/day/ha, which was meaningful at 1% level. The fifth farm (E) located in Lahidjan was sprayed with diazinon. Water samples were analyzed each day for diazinon residues for 10 days after application. Sample analysis showed that the concentration of the insecticide was 93.08 mg/l immediately after application and gradually reduced to 0.98 mg/l ten days after spraying.
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